US5244948A
Expired / Lapsed
US
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Process for the stabilization of polyolefins
Assignee: BASF Corp
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Filing: 1992-05-07
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Granted: 1993-09-14
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Expires: 2012-05-07
Abstract
Abstract Polyolefins and olefin copolymers which are prepared by polymerization on a catalyst made from a magnesium halide, a titanium compound and an aluminium alkyl can be stabilized by the addition of certain sterically hindered triazinylpiperidines, which are substituted in the 1-position, to the polymerization.
Inventors
- 👤 Rolf Mulhaupt
- 👤 Jean Rody
- 👤 Mario Slongo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 04:57
CPC Classifications
C; C08; C08F; C08F10/00; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
225 words
A process for the stabilization of a polyolefin and olefin copolymer, which is prepared by low pressure polymerization on a solid catalyst, which is prepared by the reaction of an aluminium alkyl with a solid product of a magnesium dihalide in active form and a titanium compound, the stabilization being carried out by the addition of a sterically hindered piperidine derivative to the polymerization, wherein a piperidine derivative of formula I is used, ##STR12## in which n is 1-4, R 1 is methyl, R 2 is C 1 -C 18 alkyl, or is a group of formula II ##STR13## R 3 is a group ##STR14## R 4 has one of the meanings given for R 3 when n=1, or is one of the groups --X--R 8 --Y--, ##STR15## in which q is 2-6, when n=2, or is the group ##STR16## when n=3, or is a group ##STR17## when n=4, R 6 and R 7 are independently of one another hydrogen, C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl or a group of the formula II, or R 6 and R 7 are together C 4 -C 10 alkylene or C 5 -C 7 oxaalkylene, R 8 is C 2 -C 12 alkylene, X and Y are --N(R 6 )--, m is 2 or 3, and p is 2-10.
Claim 2
Dependent Claim
225 words
A process for the stabilization of a polyolefin and olefin copolymer, which is prepared by low pressure polymerization on a solid catalyst, which is prepared by the reaction of an aluminium alkyl with a solid product of a magnesium dihalide in active form and a titanium compound, the stabilization being carried out by the addition of a sterically hindered piperidine derivative to the polymerization, wherein a piperidine derivative of formula I is used, ##STR12## in which n is 1-4, R 1 is methyl, R 2 is C 1 -C 18 alkyl, or is a group of formula II ##STR13## R 3 is a group ##STR14## R 4 has one of the meanings given for R 3 when n=1, or is one of the groups --X--R 8 --Y--, ##STR15## in which q is 2-6, when n=2, or is the group ##STR16## when n=3, or is a group ##STR17## when n=4, R 6 and R 7 are independently of one another hydrogen, C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl or a group of the formula II, or R 6 and R 7 are together C 4 -C 10 alkylene or C 5 -C 7 oxaalkylene, R 8 is C 2 -C 12 alkylene, X and Y are --N(R 6 )--, m is 2 or 3, and p is 2-10.
Claim 3
Dependent Claim
25 words
A process according to claim 1 wherein in formula I, R 2 is C 1 -C 8 alkyl or a group of the formula II.
Claim 4
Dependent Claim
20 words
A process according to claim 1 wherein in formula I, R 3 is a group N(R 6 )(R 7 ).
Claim 5
Dependent Claim
22 words
A process according to claim 1 wherein in formula I, n=1 and R 4 is a group N(R 6 )(R 7 ).
Claim 6
Dependent Claim
29 words
A process according to claim 1 wherein in formula I, n=2, X and Y are a group N(R 6 )- and R 8 is C 2 -C 6 alkylene.
Claim 7
Dependent Claim
18 words
A process according to claim 1 wherein in formula I, n=2 and R 4 is a group ##STR18##
Claim 8
Dependent Claim
24 words
A process according to claim 1 wherein in formula I, n=3 or 4 and R 6 is hydrogen or C 1 -C 4 alkyl.
Claim 9
Dependent Claim
15 words
A process according to claim 1 wherein the catalyst is prepared from spherical magnesium chloride.
Claim 10
Dependent Claim
20 words
A process according to claim 1 wherein titanium tetrachloride is used as titanium compound in the preparation of the catalyst.
Claim 11
Dependent Claim
18 words
A process according to claim 1 wherein the catalyst is activated by the addition of an electron donor.
Claim 12
Dependent Claim
21 words
A process according to claim 10 wherein an organosilicon compound having at least one Si--O--C bond is used as electron donor.
Claim 13
Dependent Claim
22 words
A process according to claim 1 wherein, apart from the sterically hindered piperidine compound, a phosphorus(III) ester is added to the polymerization.
Claim 14
Dependent Claim
11 words
A process according to claim 12 wherein a triorganophosphite is added.
Claim 15
Dependent Claim
16 words
A process according to claim 1 wherein the process is used for the polymerization of propylene.
Claim 16
Dependent Claim
9 words
A polymer stabilized by the process of claim 1.
Claim 17
Dependent Claim
9 words
A polypropylene stabilized by the process of claim 1.
Claim 18
Dependent Claim
21 words
A process according to claim 1 wherein an antioxidant of the sterically hindered phenol type is additionally added to the polymerization.
Claim 19
Dependent Claim
21 words
A process according to claim 12 wherein an antioxidant of the sterically hindered phenol type is additionally added to the polymerization.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-09-13 | 1997-03-15 | 1997-09-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-09-13 | 2001-03-15 | 2001-09-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-09-13 | 2005-03-15 | 2005-09-14 | $7700.00 | Window Closed / Lapsed |