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US5244948A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the stabilization of polyolefins

Assignee: BASF Corp
•
Filing: 1992-05-07
•
Granted: 1993-09-14
•
Expires: 2012-05-07
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Abstract

Abstract Polyolefins and olefin copolymers which are prepared by polymerization on a catalyst made from a magnesium halide, a titanium compound and an aluminium alkyl can be stabilized by the addition of certain sterically hindered triazinylpiperidines, which are substituted in the 1-position, to the polymerization.

Inventors

  • 👤 Rolf Mulhaupt
  • 👤 Jean Rody
  • 👤 Mario Slongo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:57
CPC Classifications
C; C08; C08F; C08F10/00; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/34926

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 225 words
A process for the stabilization of a polyolefin and olefin copolymer, which is prepared by low pressure polymerization on a solid catalyst, which is prepared by the reaction of an aluminium alkyl with a solid product of a magnesium dihalide in active form and a titanium compound, the stabilization being carried out by the addition of a sterically hindered piperidine derivative to the polymerization, wherein a piperidine derivative of formula I is used, ##STR12## in which n is 1-4, R 1 is methyl, R 2 is C 1 -C 18 alkyl, or is a group of formula II ##STR13## R 3 is a group ##STR14## R 4 has one of the meanings given for R 3 when n=1, or is one of the groups --X--R 8 --Y--, ##STR15## in which q is 2-6, when n=2, or is the group ##STR16## when n=3, or is a group ##STR17## when n=4, R 6 and R 7 are independently of one another hydrogen, C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl or a group of the formula II, or R 6 and R 7 are together C 4 -C 10 alkylene or C 5 -C 7 oxaalkylene, R 8 is C 2 -C 12 alkylene, X and Y are --N(R 6 )--, m is 2 or 3, and p is 2-10.
Claim 2
Dependent Claim 225 words
A process for the stabilization of a polyolefin and olefin copolymer, which is prepared by low pressure polymerization on a solid catalyst, which is prepared by the reaction of an aluminium alkyl with a solid product of a magnesium dihalide in active form and a titanium compound, the stabilization being carried out by the addition of a sterically hindered piperidine derivative to the polymerization, wherein a piperidine derivative of formula I is used, ##STR12## in which n is 1-4, R 1 is methyl, R 2 is C 1 -C 18 alkyl, or is a group of formula II ##STR13## R 3 is a group ##STR14## R 4 has one of the meanings given for R 3 when n=1, or is one of the groups --X--R 8 --Y--, ##STR15## in which q is 2-6, when n=2, or is the group ##STR16## when n=3, or is a group ##STR17## when n=4, R 6 and R 7 are independently of one another hydrogen, C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, C 7 -C 12 phenylalkyl or a group of the formula II, or R 6 and R 7 are together C 4 -C 10 alkylene or C 5 -C 7 oxaalkylene, R 8 is C 2 -C 12 alkylene, X and Y are --N(R 6 )--, m is 2 or 3, and p is 2-10.
Claim 3
Dependent Claim 25 words
A process according to claim 1 wherein in formula I, R 2 is C 1 -C 8 alkyl or a group of the formula II.
Claim 4
Dependent Claim 20 words
A process according to claim 1 wherein in formula I, R 3 is a group N(R 6 )(R 7 ).
Claim 5
Dependent Claim 22 words
A process according to claim 1 wherein in formula I, n=1 and R 4 is a group N(R 6 )(R 7 ).
Claim 6
Dependent Claim 29 words
A process according to claim 1 wherein in formula I, n=2, X and Y are a group N(R 6 )- and R 8 is C 2 -C 6 alkylene.
Claim 7
Dependent Claim 18 words
A process according to claim 1 wherein in formula I, n=2 and R 4 is a group ##STR18##
Claim 8
Dependent Claim 24 words
A process according to claim 1 wherein in formula I, n=3 or 4 and R 6 is hydrogen or C 1 -C 4 alkyl.
Claim 9
Dependent Claim 15 words
A process according to claim 1 wherein the catalyst is prepared from spherical magnesium chloride.
Claim 10
Dependent Claim 20 words
A process according to claim 1 wherein titanium tetrachloride is used as titanium compound in the preparation of the catalyst.
Claim 11
Dependent Claim 18 words
A process according to claim 1 wherein the catalyst is activated by the addition of an electron donor.
Claim 12
Dependent Claim 21 words
A process according to claim 10 wherein an organosilicon compound having at least one Si--O--C bond is used as electron donor.
Claim 13
Dependent Claim 22 words
A process according to claim 1 wherein, apart from the sterically hindered piperidine compound, a phosphorus(III) ester is added to the polymerization.
Claim 14
Dependent Claim 11 words
A process according to claim 12 wherein a triorganophosphite is added.
Claim 15
Dependent Claim 16 words
A process according to claim 1 wherein the process is used for the polymerization of propylene.
Claim 16
Dependent Claim 9 words
A polymer stabilized by the process of claim 1.
Claim 17
Dependent Claim 9 words
A polypropylene stabilized by the process of claim 1.
Claim 18
Dependent Claim 21 words
A process according to claim 1 wherein an antioxidant of the sterically hindered phenol type is additionally added to the polymerization.
Claim 19
Dependent Claim 21 words
A process according to claim 12 wherein an antioxidant of the sterically hindered phenol type is additionally added to the polymerization.

References Cited (Backward Citations)

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EP0045977B1 Cited
EP0107615A1 Cited
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EP0254348A2 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-09-13 1997-03-15 1997-09-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-09-13 2001-03-15 2001-09-14 $3760.00 Window Closed / Lapsed
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