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US5229526A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal alkoxides

Assignee: Florida State University
•
Filing: 1992-04-03
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Granted: 1993-07-20
•
Expires: 2012-04-03
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Abstract

Abstract A metal alkoxide having the following formula: ##STR1## wherein T 1 is hydrogen or a hydroxy protecting group, Z is --OT 2 , or --OCOCH 3 , T 2 is hydrogen or a hydroxy protecting group, and M is selected from the group comprising Group IA, IIA and transition metals are useful in the preparation of biologically active derivatives of baccatin III and 10-deacetyl baccatin III.

Inventors

  • 👤 Robert A. Holton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:48
CPC Classifications
C; C07; C07D; C07D407/00; C07D407/02; C07D407/12; C07D305/00; C07D305/14; C07D409/00; C07D409/02; C07D409/12; C07F; C07F7/00; C07F7/003; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/55

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 53 words
A metal alkoxide having the following formula: ##STR32## wherein T 1 is hydrogen or a hydroxy protecting group, Z is --OT 2 , wherein T 2 is hydrogen or a hydroxy protecting group, M is a Group IA, IIA, IIIA, IVA, VA, VIA or transition metal, Ac is acetyl and Ph is phenyl.
Claim 2
Dependent Claim 53 words
A metal alkoxide having the following formula: ##STR32## wherein T 1 is hydrogen or a hydroxy protecting group, Z is --OT 2 , wherein T 2 is hydrogen or a hydroxy protecting group, M is a Group IA, IIA, IIIA, IVA, VA, VIA or transition metal, Ac is acetyl and Ph is phenyl.
Claim 3
Dependent Claim 15 words
The metal alkoxide of claim 1 wherein M is Li, Mg, Na, K or Ti.
Claim 4
Dependent Claim 10 words
The metal alkoxide of claim 1 wherein M is lithium.
Claim 5
Dependent Claim 23 words
The metal alkoxide of claim 1 wherein M is lithium, Z is --OT 2 , and T 2 is a hydroxy protecting group.
Claim 6
Dependent Claim 27 words
The metal alkoxide of claim 4 wherein T 1 and T 2 are independently selected from the group consisting of 1-ethoxyethyl, 2,2,2-trichloroethoxymethyl, trialkyl silyl and triaryl silyl.
Claim 7
Dependent Claim 23 words
The metal alkoxide of claim 1 wherein M is Li, Mg, Na, K or Ti and T 1 is a hydroxy protecting group.
Claim 8
Dependent Claim 13 words
The metal alkoxide of claim 1 wherein M is a Group IIA metal.
Claim 9
Dependent Claim 13 words
The metal alkoxide of claim 1 wherein M is a Group IIIA metal.
Claim 10
Dependent Claim 13 words
The metal alkoxide of claim 1 wherein M is a Group IVA metal.
Claim 11
Dependent Claim 13 words
The metal alkoxide of claim 1 wherein M is a Group VA metal.
Claim 12
Dependent Claim 13 words
The metal alkoxide of claim 1 wherein M is a Group VIA metal.
Claim 13
Dependent Claim 12 words
The metal alkoxide of claim 1 wherein M is a transition metal.
Claim 14
Dependent Claim 17 words
The metal alkoxide of claim 1 wherein M is a transition metal selected from the lanthanide series.
Claim 15
Dependent Claim 17 words
The metal alkoxide of claim 1 wherein M is a transition metal selected from the actinide series.
Claim 16
Dependent Claim 51 words
A metal alkoxide having the following formula: ##STR33## wherein T 1 is hydrogen or a hydroxy protecting group, Z is --OT 2 , wherein, T 2 is hydrogen or a hydroxy protecting group, M is a Group IA, IIA, IIIA, IVA, or transition metal, Ac is acetyl and Ph is phenyl.
Claim 17
Dependent Claim 51 words
A metal alkoxide having the following formula: ##STR33## wherein T 1 is hydrogen or a hydroxy protecting group, Z is --OT 2 , wherein, T 2 is hydrogen or a hydroxy protecting group, M is a Group IA, IIA, IIIA, IVA, or transition metal, Ac is acetyl and Ph is phenyl.

References Cited (Backward Citations)

EP0253739A1 Cited
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EP0253738B1 Cited
US4942184A Cited
EP0336841A1 Cited
EP0336840A1 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-07-19 1997-01-18 1997-07-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-07-19 2001-01-18 2001-07-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-07-19 2005-01-18 2005-07-20 $7700.00 Window Closed / Lapsed

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