US5209849A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hydrophilic microporous polyolefin membrane
Assignee: Pall Corp
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Filing: 1992-04-24
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Granted: 1993-05-11
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Expires: 2012-04-24
Abstract
Abstract A hydrophilic microporous membrane, is provided comprising a hydrophobic membrane substrate exemplified by a polyolefin or partially fluorinated polyolefin membrane. A process is also provided for preparing a hydrophilic membrane by grafting a water soluble polymer to the hydrophobic membrane substrate surface by irradiation means, e.g., ultraviolet irradiation. The invention further concerns a method for making the membrane and process means for filtering a fluid through such membrane.
Inventors
- 👤 Hopin Hu
- 👤 Zhihua Cai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 17:36
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0093; B01D67/00931; C; C08; C08J; C08J9/00; C08J9/36; C08J9/40; C08J9/405; B01D2323/00; B01D2323/38; B01D2323/385; C08J2323/00; C08J2323/02; C08J2327/00; C08J2327/02; C08J2327/12
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
83 words
A composite microporous membrane structure comprising: a hydrophobic polyolefin microporous precursor membrane having external surfaces and having pores with internal pore surfaces; and a water soluble hydrophilic polymer comprising polyethylene glycol diacrylate co-extensively applied to said surfaces in a thin liquid coating that is permanently photografted in solid state form onto the internal pore surfaces of the precursor membrane so that the thus grafted membrane structure is hydrophilic, essentially retains the same microporosity as the precursor membrane and is water wettable, and non-leachable.
Claim 2
Dependent Claim
83 words
A composite microporous membrane structure comprising: a hydrophobic polyolefin microporous precursor membrane having external surfaces and having pores with internal pore surfaces; and a water soluble hydrophilic polymer comprising polyethylene glycol diacrylate co-extensively applied to said surfaces in a thin liquid coating that is permanently photografted in solid state form onto the internal pore surfaces of the precursor membrane so that the thus grafted membrane structure is hydrophilic, essentially retains the same microporosity as the precursor membrane and is water wettable, and non-leachable.
Claim 3
Dependent Claim
14 words
The membrane structure of claim 1 wherein the hydrophilic polymer comprises polyethylene glycol dimethacrylate.
Claim 4
Dependent Claim
15 words
The membrane structure of claim 1 wherein the hydrophilic polymer comprises polyethylene glycol di(lower alkyl)acrylate.
Claim 5
Dependent Claim
15 words
The membrane structure of claim 1 wherein the polyolefin precursor membrane is a polypropylene membrane.
Claim 6
Dependent Claim
17 words
The membrane structure of claim 1 wherein the polyolefin precursor membrane is a partially fluorinated polyolefin membrane.
Claim 7
Dependent Claim
16 words
The membrane structure of claim 1 wherein the polyolefin precursor membrane is a polyvinylidene difluoride membrane.
Claim 8
Independent Claim
142 words
A method of making a hydrophilic microporous membrane comprising: forming a composite porous membrane formed from a microporous hydrophobic membrane substrate having external surfaces and pores with internal pore surfaces formed of a first polymer comprising polyolefin, said substrate being directly coated over its entire surfaces with a second polymer comprising polyethylene glycol-dialkylacrylate, said composite porous membrane having essentially the same porous configuration as said porous membrane substrate; by contacting said porous membrane substrate with a photografting solution of said second polymer and a photoinitiator in ethylene glycol, and exposing said second polymer to radiation ray treatment to graft said second polymer in situ over the entire surfaces of said substrate under conditions such that the thus grafted membrane is hydrophilic, essentially retains the same microporosity as the membrane substrate and is water wettable and non-leachable, while avoiding plugging of said pores.
Claim 9
Independent Claim
142 words
A method of making a hydrophilic microporous membrane comprising: forming a composite porous membrane formed from a microporous hydrophobic membrane substrate having external surfaces and pores with internal pore surfaces formed of a first polymer comprising polyolefin, said substrate being directly coated over its entire surfaces with a second polymer comprising polyethylene glycol-dialkylacrylate, said composite porous membrane having essentially the same porous configuration as said porous membrane substrate; by contacting said porous membrane substrate with a photografting solution of said second polymer and a photoinitiator in ethylene glycol, and exposing said second polymer to radiation ray treatment to graft said second polymer in situ over the entire surfaces of said substrate under conditions such that the thus grafted membrane is hydrophilic, essentially retains the same microporosity as the membrane substrate and is water wettable and non-leachable, while avoiding plugging of said pores.
Claim 10
Dependent Claim
15 words
A method according to claim 7 where the precursor membrane substrate is formed of polypropylene.
Claim 11
Dependent Claim
14 words
A method according to claim 7 where the second polymer comprises polyethylene glycol dimethacrylate.
Claim 12
Dependent Claim
24 words
A method according to claim 7 where said photografting solution comprises polyethylene glycol dimethacrylate, a photoinitiator, a low surface tension liquid, and ethylene glycol.
Claim 13
Dependent Claim
45 words
A method according to claim 10 where the photoinitiator comprises a hydroxyalkylphenone having the formula ##STR4## where R 1 represents hydrogen, or a C 1-4 alkyl or alkoxy group or halogen, and R 2 and R 3 independently represent C 1-4 alkyl or alkoxy groups.
Claim 14
Dependent Claim
36 words
A method according to claim 7 wherein the amount of water soluble polymer concentration in the solution is such that the resulting grafted membrane structure retains microporosity and is readily wettable in water and is non-leachable.
Claim 15
Dependent Claim
71 words
A method according to claim 7 wherein the radiation ray treatment comprises: wetting the hydrophobic membrane substrate completely in the photografting solution; removing excess solution from the thus wetted membrane substrate, and exposing the resulting residually wet membrane in a UV chamber under inert gas for about 10 to about 50 seconds at a UV intensity of about 140 mW/cm 2 to graft the polyethylene glycol dialkylacrylate to the membrane substrate.
Claim 16
Dependent Claim
44 words
A method according to claim 13 comprising: soaking the thus grafted membrane substrate in a water soluble solvent for a time sufficient to remove photografting contaminants from the membrane substrate; and washing the thus soaked membrane substrate with water and drying the washed substrate.
References Cited (Backward Citations)
US4256782A
Cited
US4288467A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-05-10 | 1996-11-09 | 1997-05-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-05-10 | 2000-11-09 | 2001-05-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-05-10 | 2004-11-09 | 2005-05-11 | $7700.00 | Window Closed / Lapsed |