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US5138029A Expired / Lapsed US ⏱️ 0.0 years remaining

Biodegradable or biocompatible copolymer and process for producing same

Assignee: Resonac Holdings Corp
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Filing: 1991-07-03
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Granted: 1992-08-11
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Expires: 2011-07-03
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Abstract

Abstract A random copolymer comprising, as repeating units, (i) 20 to 90 mol % of 3-hydroxybutyrate unit (3HB) having the formula (I): ##STR1## (ii) 5 to 70 mol % of 3-hydroxyvalerate unit (3HV) having the formula (II): ##STR2## and (iii) 1 to 15 mol % of 4-hydroxyvalerate unit (4HV) having the formula (III): ##STR3## wherein the total of the units 3HB, 3HV, and 4HV is 100 mol %, and having a weight average molecular weight within the range of from 10,000 to 2,500,000 and a production process thereof.

Inventors

  • 👤 Masaaki Nishioka
  • 👤 Hidemitsu Takinishi
  • 👤 Shiro Fukuyama
  • 👤 Atsuo Nishimura
  • 👤 Hiromi Niitsu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:27
CPC Classifications
C; C12; C12P; C12P7/00; C12P7/62; C12P7/625; C08; C08G; C08G63/00; C08G63/02; C08G63/06; Y; Y10; Y10S; Y10S435/00; Y10S435/8215; Y10S435/822; Y10S435/829

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 82 words
A random copolymer comprising, as repeating units, (i) 20 to 90 mol % of 3-hydroxybutyrate unit (3HB) having the formula (I): ##STR8## and (ii) 5 to 70 mol % of 3-hydroxyvalerate unit (3HV) having the formula (II): ##STR9## (iii) 1 to 15 mol % of 4-hydroxyvalerate unit (4HV) having the formula (III): ##STR10## wherein the total of the units 3HB, 3HV, and 4HV is 100 mol %, and having a weight average molecular weight within the range of from 10,000 to 2,500,000.
Claim 2
Dependent Claim 82 words
A random copolymer comprising, as repeating units, (i) 20 to 90 mol % of 3-hydroxybutyrate unit (3HB) having the formula (I): ##STR8## and (ii) 5 to 70 mol % of 3-hydroxyvalerate unit (3HV) having the formula (II): ##STR9## (iii) 1 to 15 mol % of 4-hydroxyvalerate unit (4HV) having the formula (III): ##STR10## wherein the total of the units 3HB, 3HV, and 4HV is 100 mol %, and having a weight average molecular weight within the range of from 10,000 to 2,500,000.
Claim 3
Dependent Claim 37 words
A random copolymer as claimed in claim 1, wherein the copolymer comprises (i) 20 to 85 mol % of 3HB, (ii) 13 to 65 mol % of 3HV, and (iii) 2 to 15 mol % of 4HV.
Claim 4
Dependent Claim 22 words
A random copolymer as claimed in claim 1, wherein the weight average molecular weight of the random copolymer is 100,000 to 1,500,000.
Claim 5
Dependent Claim 56 words
A process for producing a random copolymer according to claim 1, comprising culturing a microorganism in the presence of at τ-valerolactone to form and accumulate a random copolymer comprising 3-hydroxybutyrate units (3HB), 3-hydroxyvalerate units (3HV), and 4-hydroxyvalerate units (4HV) within the microorgani cells, followed by recovering the same wherein said microorganism belongs to the genus Alcaligenes.
Claim 6
Dependent Claim 35 words
A process as claimed in claim 4, wherein said microorganism is at least one member selected from the group consisting of those belonging to Alcaligenes facecalis, Alcaligenes ruhlandii, Alcaligenes latus, Alcaligenes aguamarinus and Alcaligenes eutrophus.
Claim 7
Dependent Claim 31 words
A process as claimed in claim 4, wherein said culturing is aerobically effected under the conditions of a temperature of 20° to 40° C. and a pH of 6 to 10.

References Cited (Backward Citations)

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US4393167A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-11 1996-02-10 1996-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-11 2000-02-10 2000-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-11 2004-02-10 2004-08-11 $7700.00 Window Closed / Lapsed

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