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US5082925A Expired / Lapsed US ⏱️ 0.0 years remaining

Homopolymers and copolymers of salicylate lactones

Assignee: Ethicon Inc
•
Filing: 1990-08-16
•
Granted: 1992-01-21
•
Expires: 2010-08-16
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Abstract

Abstract Poly(1,4-benzodioxepin-2,5-(3-H)dione), poly(1,4-benzodioxepin-2,5-(3-H, 3-methyl)dione), and copolymers of 1,4-benzodioxepin-2,5-(3-H)dione or 1,4-benzodioxepin-2,5-(3-H, 3-methyl)dione and at least one of: a) glycolide, b) (L-)lactide, c) an alkylene carbonate, d) p-dioxanone, e) e-caprolactone, f) 1,4-dioxepan-2-one, or g) 1,5-dioxepan-2-one. Surgical devices prepared from the polymers and copolymers.

Inventors

  • 👤 Shalaby W. Shalaby
  • 👤 Donald F. Koelmel
  • 👤 Steven Arnold

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:35
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/64; A; A61; A61L; A61L31/00; A61L31/04; A61L31/06; C08G63/02; C08G63/06; C08G63/08

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 17 words
A homopolymer of a monomer represented by the following formula: ##STR4## wherein R is hydrogen or methyl.
Claim 2
Dependent Claim 17 words
A homopolymer of a monomer represented by the following formula: ##STR4## wherein R is hydrogen or methyl.
Claim 3
Dependent Claim 9 words
The homopolymer of claim 1 wherein R is hydrogen.
Claim 4
Dependent Claim 20 words
The homopolymer of claim 2 wherein the inherent viscosity of the homopolymer ranges from about 0.1 to about 1.7 dL/g.
Claim 5
Dependent Claim 20 words
The homopolymer of claim 3 wherein the inherent viscosity of the homopolymer ranges from about 0.3 to about 1.4 dL/g.
Claim 6
Dependent Claim 21 words
The homopolymer of claim 4 wherein the glass transition temperature of the homopolymer ranges from about 65° to about 80° C.
Claim 7
Dependent Claim 17 words
The homopolymer of claim 5 wherein the melting temperature of the homopolymer is greater than 160° C.
Claim 8
Dependent Claim 17 words
The homopolymer of claim 6 wherein the percent crystallinity of the homopolymer is greater than 5 percent.
Claim 9
Dependent Claim 17 words
The homopolymer of claim 7 wherein the percent crystallinity of the homopolymer is greater than 25 percent.
Claim 10
Dependent Claim 17 words
The homopolymer of claim 8 wherein the percent crystallinity of the homopolymer is greater than 30 percent.
Claim 11
Dependent Claim 37 words
A copolymer of the monomer represented by the formula of claim 1 and at least one of the following comonomers: a) glycolide, b) (L)-lactide, c) an alkylene carbonate, d) p-dioxanone, e) ε-caprolactone, f) 1,4-dioxepan-2-one, or g) 1,5-dioxepan-2-one.
Claim 12
Dependent Claim 12 words
The copolymer of claim 10 wherein the comonomer is glycolide or L-lactide.
Claim 13
Dependent Claim 10 words
The copolymer of claim 11 wherein the comonomer is glycolide.
Claim 14
Dependent Claim 27 words
The copolymer of claim 12 wherein the amount of the monomer represented by the formula of claim 1 ranges from about 1 to about 35 weight percent.
Claim 15
Dependent Claim 27 words
The copolymer of claim 13 wherein the amount of the monomer represented by the formula of claim 1 ranges from about 5 to about 15 weight percent.
Claim 16
Dependent Claim 10 words
A surgical device prepared from the homopolymer of claim 1.
Claim 17
Dependent Claim 10 words
A surgical device prepared from the homopolymer of claim 9.
Claim 18
Dependent Claim 10 words
A surgical device prepared from the copolymer of claim 10.
Claim 19
Dependent Claim 10 words
A surgical device prepared from the copolymer of claim 14.

References Cited (Backward Citations)

US2956064A Cited
US4190720A Cited
US4441496A Cited
US4470416A Cited
US4810775A Cited
US4891263A Cited
US4920203A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-01-20 1995-07-22 1996-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-01-20 1999-07-22 2000-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-01-20 2003-07-22 2004-01-21 $7700.00 Window Closed / Lapsed

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