US5068477A
Expired / Lapsed
US
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Process for reducing a refining catalyst and use of the catalyst in hydrogenation
Assignee: Eurecat SA
•
Filing: 1991-04-29
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Granted: 1991-11-26
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Expires: 2011-04-29
Abstract
Abstract Process for reducing a refining catalyst before its use, the catalyst containing a support and an active phase based on at least one noble or non-noble metal of group VIII or of group 1b of the periodic classification of the elements. <??>The process consists: a) in impregnating the catalyst with an aqueous or organic solution of a reducing agent compound, b) in decomposing the reducing agent compound by heating the catalyst, c) in drying the catalyst thus obtained.
Inventors
- 👤 Georges Berrebi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 13:59
CPC Classifications
C; C10; C10G; C10G49/00; C10G49/02; B; B01; B01J; B01J37/00; B01J37/02; B01J37/0201; B01J37/0203; B01J23/00; B01J23/38; B01J23/40; B01J23/48; B01J23/50; B01J23/70; B01J23/74; B01J37/16; B01J38/00; B01J38/48; B01J38/50; B01J38/52; C10G45/00; C10G45/32; C10G45/34; C10G45/40
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
218 words
A process for selective hydrogenation of a feed, comprising subjecting said feed to hydrogenation conditions in the presence of a catalyst, wherein said catalyst contains a support and an active phase based on at least one metal of group VIII of the periodic classification elements, and wherein before the catalyst is used, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms, polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms, polyalcohols having 1 to 14 carbon atoms, organic acids having 1 to 14 carbon atoms, polyacids having 1 to 14 carbon atoms and mixtures thereof, in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 2
Dependent Claim
218 words
A process for selective hydrogenation of a feed, comprising subjecting said feed to hydrogenation conditions in the presence of a catalyst, wherein said catalyst contains a support and an active phase based on at least one metal of group VIII of the periodic classification elements, and wherein before the catalyst is used, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms, polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms, polyalcohols having 1 to 14 carbon atoms, organic acids having 1 to 14 carbon atoms, polyacids having 1 to 14 carbon atoms and mixtures thereof, in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 3
Dependent Claim
24 words
A process according to claim 1 in which, in step (a), the impregnation temperature of the reducing compound is between 10° and 30° C.
Claim 4
Dependent Claim
27 words
A process according to claim 1 in which, in step (a), 10 ppm to 50% by weight of the said reducing compound is introduced onto the catalyst.
Claim 5
Dependent Claim
24 words
A process according to claim 1 in which the metal of group VIII is chosen from the group consisting of iron, cobalt and nickel.
Claim 6
Dependent Claim
27 words
A process according to claim 1 in which the metal of group VIII is selected from the group consisting of platinum, palladium, iridium, ruthenium, rhodium and osmium.
Claim 7
Dependent Claim
19 words
A process according to claim 1 in which the operation is ex situ, i.e. outside the refining reaction zone.
Claim 8
Dependent Claim
14 words
A process according to claim 1 in which the reducing agent is an aldehyde.
Claim 9
Dependent Claim
17 words
A process according to claim 1 in which the reducing agent is a ketone or a polyketone.
Claim 10
Dependent Claim
14 words
A process according to claim 1 in which the reducing agent is an ether.
Claim 11
Dependent Claim
17 words
A process according to claim 1 in which the reducing agent is an alcohol or a polyalcohol.
Claim 12
Dependent Claim
19 words
A process according to claim 1 in which the reducing agent is an organic acid or an organic polyacid.
Claim 13
Dependent Claim
53 words
A process according to claim 1, in which in the treatment of the catalyst, the catalyst is situated in an enclosure and the temperature sufficient to crack or decompose the reducing compound is obtained by circulation in the said enclosure of a current of dry steam or at least one other inert fluid.
Claim 14
Dependent Claim
41 words
A process according to any one of claim 12 in which the said enclosure containing the bed of the catalyst is equipped with hollow tubes through which a fluid passes whereby the necessary temperature regulation of the said process is obtained.
Claim 15
Dependent Claim
35 words
A process according to claim 13 in which the said enclosure is a rotary furnace arranged in such a manner that during rotation the catalyst particles are brought regularly into contact with the heating tubes.
Claim 16
Dependent Claim
28 words
A process according to claim 1 in which the catalyst contains inter alia a metal of group Ib selected from the group consisting of silver, gold and copper.
Claim 17
Dependent Claim
19 words
A process in accordance with the process of claim 1, comprising a selective hydrogenation reaction of an unsaturated hydrocarbon.
Claim 18
Dependent Claim
17 words
A process according to claim 1, wherein the feed comprises at least one acetylenic and/or diolefinic hydrocarbon.
Claim 19
Dependent Claim
14 words
A process according to claim 1, wherein the feed comprises at least one oil.
Claim 20
Dependent Claim
18 words
A process according to claim 1, wherein the feed comprises at least one oil containing a gum-forming compound.
Claim 21
Dependent Claim
15 words
A process according to claim 1, wherein the feed comprises at least one pyrolysis effluent.
Claim 22
Dependent Claim
218 words
A process for selective cracking of a feed, comprising subjecting said feed to cracking conditions in the presence of a catalyst, wherein said catalyst contains a support and an active phase based on at least one metal of group VIII of the periodic classification elements, and wherein before the catalyst is used, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms, polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms, polyalcohols having 1 to 14 carbon atoms, organic acids having 1 to 14 carbon atoms, polyacids having 1 to 14 carbon atoms and mixtures thereof, in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 23
Dependent Claim
218 words
A process for selective cracking of a feed, comprising subjecting said feed to cracking conditions in the presence of a catalyst, wherein said catalyst contains a support and an active phase based on at least one metal of group VIII of the periodic classification elements, and wherein before the catalyst is used, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms, polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms, polyalcohols having 1 to 14 carbon atoms, organic acids having 1 to 14 carbon atoms, polyacids having 1 to 14 carbon atoms and mixtures thereof, in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 24
Dependent Claim
14 words
A process according to claim 21, wherein the cracking reaction is a steam-cracking process.
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