Method of purifying exhaust gases

Claim 1

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-fuel ratio of at least 18:1 and having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxiding atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support, and, wherein said porous support is formed from zeolite.

Claim 2

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-fuel ratio of at least 18:1 and having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxiding atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support, and, wherein said porous support is formed from zeolite.

Claim 3

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-fuel ratio of at least 18:1 and having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from at least one material selected from the group consisting of alumina, silica, silica-alumina and zeolite, wherein said copper has a weight of 0.1 to 50 g per liter of said porous support, and, wherein said porous support comprises a monolithic body having a first portion loaded with said copper and a second portion loaded with an oxidizing catalyst for reducing substances from the exhaust gases leaving said first portion.

Claim 4

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-fuel ratio of at least 18:1 and having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from at least one material selected from the group consisting of alumina, silica, silica-alumina and zeolite, wherein said copper has a weight of 0.1 to 50 g per liter of said porous support, and, wherein said porous support comprises a monolithic body having a first portion loaded with said copper and a second portion loaded with an oxidizing catalyst for reducing substances from the exhaust gases leaving said first portion.

Claim 6

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-face ratio of at least 18:1 and having a higher ratio of air to fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases characterized by possessing an oxidizing atmosphere and containing nitrogen oxides but not containing a sufficient amount of reducing compounds capable of reducing nitrogen oxides to N 2 , comprising adding hydrocarbons to the exhaust gases in amount stoichiometrically sufficient to reduce the nitrogen oxides to N and thereafter contacting the exhaust gases with copper containing catalyst in the presence of hydrocarbons in an oxidizing atmosphere at a temperature of 300° to 600° C., thereby reducing the quantity of the nitrogen oxides in the exhaust gases, the oxidizing atmosphere being one produced solely by the lean fuel-air mixture and the added hydrocarbon and being an atmosphere containing a greater amount of oxygen than is required for oxidizing the reducing compounds including the added hydrocarbons, to H 2 O and CO 2 , the amount of oxygen present being solely that of the exhaust gases as they are produced.

Claim 7

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having an air-face ratio of at least 18:1 and having a higher ratio of air to fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases characterized by possessing an oxidizing atmosphere and containing nitrogen oxides but not containing a sufficient amount of reducing compounds capable of reducing nitrogen oxides to N 2 , comprising adding hydrocarbons to the exhaust gases in amount stoichiometrically sufficient to reduce the nitrogen oxides to N and thereafter contacting the exhaust gases with copper containing catalyst in the presence of hydrocarbons in an oxidizing atmosphere at a temperature of 300° to 600° C., thereby reducing the quantity of the nitrogen oxides in the exhaust gases, the oxidizing atmosphere being one produced solely by the lean fuel-air mixture and the added hydrocarbon and being an atmosphere containing a greater amount of oxygen than is required for oxidizing the reducing compounds including the added hydrocarbons, to H 2 O and CO 2 , the amount of oxygen present being solely that of the exhaust gases as they are produced.

Claim 8

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from zeolite, and wherein said copper has a weight of 0.1 to 50 g per liter of said porous support.

Claim 9

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having a higher ratio of air to the fuel and containing a greater amount of oxygen than is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from zeolite, and wherein said copper has a weight of 0.1 to 50 g per liter of said porous support.

Claim 10

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having a higher ratio of air to the fuel and containing a greater amount of oxygen that is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from at least one material selected from the group consisting of alumina, silica, silica-alumina and zeolite and wherein said copper has a weight of 0.1 to 50 g per liter of said porous support, and further wherein said porous support comprises a monolithic body having a first portion loaded with said copper and a second portion loaded with an oxidizing catalyst for reducing substances from the exhaust gases leaving said first portion.

Claim 11

A method of purifying exhaust gases from an automobile engine supplied with a lean fuel-air mixture having a higher ratio of air to the fuel and containing a greater amount of oxygen that is required for the complete combustion of any unburned fuel, said exhaust gases containing nitrogen oxides in an oxygen containing oxidizing atmosphere containing also hydrocarbons and CO, comprising the catalytic step of contacting the exhaust gases with a catalyst containing copper in the presence of hydrocarbons in an amount sufficient to satisfy the stoichiometric requirement for converting the nitrogen oxides to N 2 in the oxidizing atmosphere, thereby reducing the nitrogen oxides from the exhaust gases to N 2 , while retaining residual hydrocarbons and CO, the oxidizing atmosphere being one produced solely by the lean fuel air mixture and in which oxidizing atmosphere the amount of oxygen present in the exhaust gases as they are produced is greater than that required for oxidizing the existing reducing substances to H 2 O and CO 2 , wherein said copper is loaded on a porous support formed from at least one material selected from the group consisting of alumina, silica, silica-alumina and zeolite and wherein said copper has a weight of 0.1 to 50 g per liter of said porous support, and further wherein said porous support comprises a monolithic body having a first portion loaded with said copper and a second portion loaded with an oxidizing catalyst for reducing substances from the exhaust gases leaving said first portion.