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US5032565A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for reducing a refining catalyst before use

Assignee: Eurecat SA
•
Filing: 1990-02-14
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Granted: 1991-07-16
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Expires: 2010-02-14
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Abstract

Abstract This invention concerns a process for reducing a refining catalyst before it is put into use, the catalyst containing a support and an active phase based on at least one noble or non-noble metal of group VIII or of group Ib of the periodic classification of elements, consisting of: (a) impregnating the catalyst with an aqueous or organic solution of a reducing agent, (b) decomposing the reducing agent by heating with a catalyst, and (c) drying the catalyst thus obtained.

Inventors

  • 👤 Georges Berrebi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:45
CPC Classifications
C; C10; C10G; C10G49/00; C10G49/02; B; B01; B01J; B01J37/00; B01J37/02; B01J37/0201; B01J37/0203; B01J23/00; B01J23/38; B01J23/40; B01J23/48; B01J23/50; B01J23/70; B01J23/74; B01J37/16; B01J38/00; B01J38/48; B01J38/50; B01J38/52; C10G45/00; C10G45/32; C10G45/34; C10G45/40

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 208 words
A process for the reduction of a refining catalyst containing a support and an active phase based on at least one metal of group VIII of the periodic classification of elements, wherein before the catalyst is used in a refining reaction zone, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms polyalcohols having 1 to 14 carbon atoms organic acids having 1 to 14 carbon atoms polyacids having 1 to 14 carbon atoms, and mixtures thereof in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 2
Dependent Claim 208 words
A process for the reduction of a refining catalyst containing a support and an active phase based on at least one metal of group VIII of the periodic classification of elements, wherein before the catalyst is used in a refining reaction zone, a treatment of said catalyst is carried out comprising in the absence of hydrogen and carbon monoxide: (a) impregnating the catalyst at between 0° and 50° C. with an aqueous or organic solution of a compound that is a reducing agent selected from the group consisting of aldehydes having 2 to 14 carbon atoms, ketones having 3-18 carbon atoms polyketones having 3 to 18 carbon atoms, ethers having 2 to 14 carbon atoms, alcohols having 1 to 14 carbon atoms polyalcohols having 1 to 14 carbon atoms organic acids having 1 to 14 carbon atoms polyacids having 1 to 14 carbon atoms, and mixtures thereof in a manner so as to introduce from 10 ppm to 100% (by weight) of said compound onto the catalyst; (b) raising the temperature of the thus impregnated catalyst to a temperature between 100° and 150° C. and under a pressure of 1 to 10 bars, thereby reducing the catalyst; and (c) drying the catalyst to eliminate aqueous or organic solution.
Claim 3
Dependent Claim 24 words
A process according to claim 1 in which, in step (a), the impregnation temperature of the reducing compound is between 10° and 30° C.
Claim 4
Dependent Claim 27 words
A process according to claim 1 in which, in step (a), 10 ppm to 50% by weight of the said reducing compound is introduced onto the catalyst.
Claim 5
Dependent Claim 24 words
A process according to claim 1 in which the metal of group VIII is chosen from the group consisting or iron, cobalt and nickel.
Claim 6
Dependent Claim 27 words
A process according to claim 1 in which the metal of group VIII is selected from the group consisting of platinum, palladium, iridium, ruthenium, rhodium and osmium.
Claim 7
Dependent Claim 17 words
A process according to claim 1 in which the treatment takes place outside the refining reaction zone.
Claim 8
Dependent Claim 14 words
A process according to claim 1 in which the reducing agent is an aldehyde.
Claim 9
Dependent Claim 17 words
A process according to claim 1 in which the reducing agent is a ketone or a polyketone.
Claim 10
Dependent Claim 14 words
A process according to claim 1 in which the reducing agent is an ether.
Claim 11
Dependent Claim 17 words
A process according to claim 1 in which the reducing agent is an alcohol or a polyalcohol.
Claim 12
Dependent Claim 19 words
A process according to claim 1 in which the reducing agent is an organic acid or an organic polyacid.
Claim 13
Dependent Claim 50 words
A process according to claim 1, in which the catalyst is located in an enclosure and is at a temperature sufficient to crack or decompose the reducing agent in step (a), wherein said temperature is maintained by circulation in said enclosure of a current of at least one inert fluid.
Claim 14
Dependent Claim 39 words
A process according to any one of claims 12 to 11 in which the said enclosure containing the bed of the catalyst is equipped with hollow tubes through which a fluid passes to regulate the temperature of said process.
Claim 15
Dependent Claim 32 words
A process according to claim 13 in which said enclosure is a rotary furnace arranged in such a manner that during rotation the catalyst is brought regularly into contact with the tubes.
Claim 16
Dependent Claim 26 words
A process according to claim 1 in which the catalyst contains a metal of group Ib selected from the group consisting of silver, gold and copper.
Claim 17
Dependent Claim 13 words
A process according to claim 12, wherein the inert fluid is dry steam.

References Cited (Backward Citations)

DE232594C Cited
US2833725A Cited
US4234462A Cited
US4210605A Cited
JPS59150540A Cited
US4758346A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-07-15 1995-01-14 1995-07-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-07-15 1999-01-14 1999-07-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-07-15 2003-01-14 2003-07-16 $7700.00 Window Closed / Lapsed

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