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US4994074A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymers of ε-caprolactone, glycolide and glycolic acid for suture coatings

Assignee: Ethicon Inc
•
Filing: 1990-02-01
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Granted: 1991-02-19
•
Expires: 2010-02-01
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Abstract

Abstract Copolymer of a predominant amount of ε-caprolactone, the balance being glycolide and glycolic acid. Coating for an absorbable, multifilament surgical suture prepared by dissolving the copolymer in an organic solvent.

Inventors

  • 👤 Rao S. Bezwada
  • 👤 Alastair W. Hunter
  • 👤 Shalaby W. Shalaby

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 12:28
CPC Classifications
A; A61; A61L; A61L17/00; A61L17/06; A61L17/10; A61L17/12; A61B; A61B17/00; A61B17/04; A61B17/06; A61B17/06166; C; C08; C08G; C08G63/00; C08G63/02; C08G63/06; C08G63/08; A61B2017/00004

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 40 words
A copolymer of a predominant amount of ε-caprolactone and the balance glycolide and glycolic acid, at a concentration of glycolic acid such that the intrinsic viscosity of the copolymer in hexafluoroisopropyl alcohol is between about 0.15 to about 0.60 dl/g.
Claim 2
Dependent Claim 40 words
A copolymer of a predominant amount of ε-caprolactone and the balance glycolide and glycolic acid, at a concentration of glycolic acid such that the intrinsic viscosity of the copolymer in hexafluoroisopropyl alcohol is between about 0.15 to about 0.60 dl/g.
Claim 3
Dependent Claim 19 words
The copolymer of claim 1 wherein the amount of ε-caprolactone is between about 80 to about 95 mole percent.
Claim 4
Dependent Claim 19 words
The copolymer of claim 2 wherein the amount of ε-caprolactone is between about 90 to about 95 mole percent.
Claim 5
Dependent Claim 20 words
The copolymer of claim 3 wherein the intrinsic viscosity of the copolymer is between about 0.20 to about 0.50 dl/g.
Claim 6
Dependent Claim 20 words
The copolymer of claim 4 wherein the melting temperature of the copolymer is between about 35° to about 50° C.
Claim 7
Dependent Claim 20 words
The copolymer of claim 5 wherein the amount of glycolic acid is between about 1 to about 15 mole percent.
Claim 8
Dependent Claim 19 words
The copolymer of claim 6 wherein the amount of glycolide is between about 2 to about 10 mole percent.
Claim 9
Dependent Claim 21 words
A coating for a surgical suture comprising a solution of the copolymer of claim 1 or 7 in an organic solvent.
Claim 10
Dependent Claim 21 words
The coating of claim 8 wherein the amount of copolymer in solution is between about 1 to about 20 weight percent.
Claim 11
Dependent Claim 21 words
The coating of claim 9 wherein the suture is an absorbable monofilament or multifilament suture with or without an attached needle.
Claim 12
Dependent Claim 13 words
The coating of claim 10 wherein the suture is an absorbable multifilament suture.
Claim 13
Dependent Claim 17 words
The coating of claim 11 wherein the absorbable multifilament suture is in the form of a braid.
Claim 14
Dependent Claim 21 words
The coating of claim 12 wherein the suture is prepared from a polymer of a lactone or one or more lactones.
Claim 15
Dependent Claim 15 words
The coating of claim 13 wherein the multifilament suture is a poly(lactide-co-glycolide) braided multifilament suture.
Claim 16
Dependent Claim 11 words
An absorbable multifilament suture coated with the copolymer of claim 1.
Claim 17
Dependent Claim 11 words
An absorbable multifilament suture coated with the copolymer of claim 7.

References Cited (Backward Citations)

US4045418A Cited
US4057537A Cited
US4300565A Cited
US4243775A Cited
US4605730A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-02-18 1994-08-20 1995-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-02-18 1998-08-20 1999-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-02-18 2002-08-20 2003-02-19 $7700.00 Window Closed / Lapsed

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