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US4987575A Expired / Lapsed US ⏱️ 0.0 years remaining

Tetravalent chromium (Cr4+) as a laser-active ion for tunabale solid-state lasers

Assignee: Individual
•
Filing: 1989-12-14
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Granted: 1991-01-22
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Expires: 2009-12-14
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Abstract

Abstract A laser-medium in the form of a dielectric crystal or glass doped with tetravalent chromium. The dielectric crystals are of olivine-like structure such as germanates of formula (A) (RE)GeO 4 where (A=Na or Li, RE=Y, Lu or Gd), crystals of willemite structure Zn 2 (Si or Ge)O 4 tetrahedral sites, or any other single-crystal or polycrystalline compound containing the (Si.Ge)O 4 tetrahedra in its crystal lattice, such as Ca 3 La 2 (SiO 4 ) 6 and crystals such as YAG (Y 3 Al 5 O 12 ).

Inventors

  • 👤 Robert R. Alfano
  • 👤 Vladimir Petricevic

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:47
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/14; H01S3/16; H01S3/1601; H01S3/162; H01S3/1623; H01S3/163; H01S3/1655; H01S3/1658

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 124 words
A laser comprising: a. a laser medium comprising a single crystal of dielectric material doped with chromium ions in the tetravalent state, the single crystal being a crystal of olivine-like structure such as germanates of formula (A) (RE)GeO 4 where (A=NA or Li, RE=Y, Lu or Gd), crystals of willemite structure Zn 2 (Si or Ge)O 4 or any other single-crystal or polycrystalline compound containing tetrahedral sites in its crystal lattice, such as Ca 3 La 2 (SiO 4 ) 6 and YAG, b. optical means for exciting said laser medium with wavelengths in the absorption region of said crystal to emit coherent optical radiation, and c. an optical resonant cavity for supporting coherent radiation emitted by the laser medium in the fluorescence region.
Claim 2
Dependent Claim 124 words
A laser comprising: a. a laser medium comprising a single crystal of dielectric material doped with chromium ions in the tetravalent state, the single crystal being a crystal of olivine-like structure such as germanates of formula (A) (RE)GeO 4 where (A=NA or Li, RE=Y, Lu or Gd), crystals of willemite structure Zn 2 (Si or Ge)O 4 or any other single-crystal or polycrystalline compound containing tetrahedral sites in its crystal lattice, such as Ca 3 La 2 (SiO 4 ) 6 and YAG, b. optical means for exciting said laser medium with wavelengths in the absorption region of said crystal to emit coherent optical radiation, and c. an optical resonant cavity for supporting coherent radiation emitted by the laser medium in the fluorescence region.
Claim 3
Dependent Claim 82 words
A laser medium comprising a single crystal of dielectric material doped with chromium ions in the tetravelent state (Cr 4+ ), the single crystal being a crystal of olivine-like structure such as germanates of formula (A) (RE) GeO 4 where (A=NA or Li, RE=Y, Lu or Gd), crystals of willemite structure Zn(Si or Ge)O 4 or any other single-crystal or polycrystalline compound containing tetrahedral sites in its crystal lattice, such as YAG and Ca 3 La 2 (SiO 4 ) 6 .
Claim 4
Dependent Claim 82 words
A laser medium comprising a single crystal of dielectric material doped with chromium ions in the tetravelent state (Cr 4+ ), the single crystal being a crystal of olivine-like structure such as germanates of formula (A) (RE) GeO 4 where (A=NA or Li, RE=Y, Lu or Gd), crystals of willemite structure Zn(Si or Ge)O 4 or any other single-crystal or polycrystalline compound containing tetrahedral sites in its crystal lattice, such as YAG and Ca 3 La 2 (SiO 4 ) 6 .

References Cited (Backward Citations)

US4648094A Cited
US4841530A Cited
US4679198A Cited
US4802180A Cited
US4797889A Cited
US4811349A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-21 1994-07-23 1995-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-21 1998-07-23 1999-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-21 2002-07-23 2003-01-22 $7700.00 Window Closed / Lapsed

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