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Process for coating polymer surfaces and coated products produced using such process

Assignee: Snyder Laboratories Inc
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Filing: 1989-02-15
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Granted: 1990-07-24
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Expires: 2009-02-15
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Abstract

Abstract Processes for treating polymeric surfaces to produce smooth, durable, slippery coatings which are able to withstand the rigors of sterilization and, long term exposure to human blood and other bodily fluids without substantial loss of their slipperiness.

Inventors

  • 👤 Richard A. Markle
  • 👤 Phyllis L. Brusky
  • 👤 John H. Baker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:38
CPC Classifications
B; B05; B05D; B05D5/00; B05D5/08; A; A61; A61L; A61L2/00; A61L2/16; A61L2/20; A61L2/206; A61L29/00; A61L29/04; A61L29/041; A61L33/00; A61L33/06; A61L33/064; B05D7/00; B05D7/50; B05D7/56; B05D7/58; B05D7/584; C; C08; C08J; C08J7/00; C08J7/04; C08J7/042; C08J7/043; C08J7/046; B05D3/00; B05D3/10; B05D3/105; C08J2383/00; C08J2383/04; C08J2433/00; C08J2433/04; C08J2433/06; C08J2433/10; C08J2433/12; C08J2439/00; C08J2439/04; C08J2439/06; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/139; Y10T428/28; Y10T428/2843; Y10T428/31504; Y10T428/31652; Y10T428/31667; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 110 words
A process for treating a medical article or device having a polymeric surface to produce a smooth, durable, slippery coating comprising: applying to the polymeric surface of the said article or device a primer coat; applying to said surface a tie coat comprising a solution selected from aqueous solutions of polyacrylic acid, dimethyl formamide solutions of poly(methyl vinyl ether/maleic anhydride), 1:1 methanol/isopropanol solutions of poly(methyl vinyl ether/maleic anhydride) and solutions of poly(methyl vinyl ether/maleic anhydride) in one or more alcohols selected from the group comprising the lower alcohols of methanol through pentanol or mixtures thereof in water; and applying to said surface a slippery coating comprising a solution of polyvinylpyrrolidone.
Claim 2
Dependent Claim 110 words
A process for treating a medical article or device having a polymeric surface to produce a smooth, durable, slippery coating comprising: applying to the polymeric surface of the said article or device a primer coat; applying to said surface a tie coat comprising a solution selected from aqueous solutions of polyacrylic acid, dimethyl formamide solutions of poly(methyl vinyl ether/maleic anhydride), 1:1 methanol/isopropanol solutions of poly(methyl vinyl ether/maleic anhydride) and solutions of poly(methyl vinyl ether/maleic anhydride) in one or more alcohols selected from the group comprising the lower alcohols of methanol through pentanol or mixtures thereof in water; and applying to said surface a slippery coating comprising a solution of polyvinylpyrrolidone.
Claim 3
Dependent Claim 26 words
The process of claim 1 wherein the article has a polymeric surface selected from the group comprising silicone, polyvinyl chloride, latex, polyester, polyurethane and thermoplastic elastomers.
Claim 4
Dependent Claim 27 words
The process of claim 2 wherein the surface of the article or device is first pretreated with a quaternary organic base prior to applying the tie coat.
Claim 5
Dependent Claim 19 words
The process of claim 2 wherein the primer coat applied comprises a solution of N-trimethoxypropylsilyl polyethyleneimine in methylene chloride
Claim 6
Dependent Claim 37 words
The process of claim 2 wherein the tie coat applied comprises a solution selected from aqueous solutions of polyacrylic acids, dimethyl formamide solutions of poly(methyl vinyl ether/maleic anhydride), and 1:1 methanol/isopropanol solutions of poly(methyl vinyl ether/maleic anhydride).
Claim 7
Dependent Claim 23 words
The process of claim 2 wherein the primer coat applied comprises a solution of N-trimethoxypropylsilyl polyethyleneimine in isopropanol or in an isopropanol/methanol mixture.
Claim 8
Dependent Claim 20 words
The process of claim 2 wherein the tie coat applied comprises a 1:1 methanol/isopropanol solution of poly(methyl vinyl ether/maleic anhydride).
Claim 9
Dependent Claim 61 words
The process of claim 1 wherein the polymeric surface is silicone, latex, polyester, polyurethane and thermoplastic, the primer coat to be applied is a solution of N-trimethoxypropylsilyl polyethyleneimine in trichloroethane, the tie coat to be applied is a solution of poly(methyl vinyl ether/maleic anhydride) in 1:1 methanol/isopropanol, and the slippery coating to be applied is a solution of polyvinylpyrrolidone in water.
Claim 10
Dependent Claim 79 words
A medical article or device having a polymeric surface which has been treated to produce a smooth, durable, slippery coating, said coating being formed by applying to the polymeric surface of the said article or device a primer coat comprising a solution selected from aqueous solutions of polyacrylic acid, dimethyl formamide solutions of poly(methyl vinyl ether/maleic anhydride) and 1:1 methanol/isopropanol solutions of poly(methyl vinyl ether/maleic anhydride); and applying to said surface a slippery coating comprising a solution of polyvinylpyrrolidone.
Claim 11
Dependent Claim 79 words
A medical article or device having a polymeric surface which has been treated to produce a smooth, durable, slippery coating, said coating being formed by applying to the polymeric surface of the said article or device a primer coat comprising a solution selected from aqueous solutions of polyacrylic acid, dimethyl formamide solutions of poly(methyl vinyl ether/maleic anhydride) and 1:1 methanol/isopropanol solutions of poly(methyl vinyl ether/maleic anhydride); and applying to said surface a slippery coating comprising a solution of polyvinylpyrrolidone.
Claim 12
Dependent Claim 21 words
An article or device having a silicone, latex, polyester, polyurethane and thermoplastic surface treated in accordance with claims 5 and 6.
Claim 13
Dependent Claim 14 words
An article or device having a polymeric surface treated in accordance with claim 8.
Claim 14
Dependent Claim 19 words
An article or device having a polymeric surface treated in accordance with claim 1 which is tubular in shape.
Claim 15
Dependent Claim 19 words
An article or device having a polymeric surface treated in accordance with claim 1 which is flat in shape.
Claim 16
Dependent Claim 22 words
An article or device having a polymeric surface treated in accordance with claim 1 which is suitable for use in surgical procedures.
Claim 17
Dependent Claim 23 words
An article or device having a polymeric surface treated in accordance with claim 1 which is suitable for use as a drainage device.
Claim 18
Dependent Claim 27 words
An article or device having a polymeric surface treated in accordance with claim 1 which treated surface is suitable to withstand the rigors of sterilization by steam.

References Cited (Backward Citations)

US4119094A Cited
US4439479A Cited
US4666437A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-23 1994-01-22 1994-07-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-23 1998-01-22 1998-07-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-23 2002-01-22 2002-07-24 $7700.00 Window Closed / Lapsed

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