US4921731A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Deposition of ceramic coatings using sol-gel processing with application of a thermal gradient
Assignee: University of Florida
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Filing: 1987-04-28
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Granted: 1990-05-01
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Expires: 2007-04-28
Abstract
Abstract A method of ceramic coating a substrate by thermodeposition from a sol made by hydrolyzing and peptizing organometallic compounds in water. The sol contains colloidal particles having a size between about 0.0005 micron and about 10 microns and the deposited coatings have good packing characteristics as well as smoothness. Composite coatings are also deposited which contain reinforcing materials such as SiC embedded in the coated matrix. These coatings afford the substrate onto which they are coated excellent wear, anti-corrosion and insulating characteristics.
Inventors
- 👤 David E. Clark
- 👤 William J. Dalzell, Jr.
- 👤 Brenda L. Adams
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 19:25
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/80; C04B41/81; C04B41/85; C04B41/87; C03; C03C; C03C17/00; C03C17/22; C03C17/23; C03C25/00; C03C25/10; C03C25/104; C03C25/106; C03C25/1061; C04B41/009; C04B41/45; C04B41/50; C04B41/5025; C23; C23C; C23C18/00; C23C18/02; C23C18/12; C23C18/1204; C23C18/1208; C23C18/1225; C23C18/125; C23C18/1254; C23C18/1291; C03C2217/00; C03C2217/20; C03C2217/21; C03C2218/00; C03C2218/10; C03C2218/11; C03C2218/113
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
201 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of between about 0.01 and about 7 comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between 10,000:1 and 2:1, and said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium, and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between 10 weight % and about 90 weight %; (c) depositing particles from said partially dewatered sol onto the surface of a substrate, said substrate and said so being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (d) drying said coated substrate.
Claim 2
Independent Claim
201 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of between about 0.01 and about 7 comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between 10,000:1 and 2:1, and said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium, and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between 10 weight % and about 90 weight %; (c) depositing particles from said partially dewatered sol onto the surface of a substrate, said substrate and said so being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (d) drying said coated substrate.
Claim 3
Dependent Claim
26 words
A method of claim 1, wherein said substrate and said sol are maintained at a temperature differential of between about 100° C. and about 300° C.
Claim 4
Dependent Claim
48 words
A method of claim 1, wherein particles from said partially dewatered sol are deposited onto the surface of a substrate by immersing said substrate into said sol for a period of time effective to deposit a desired coating thickness and then removing the coated substrate from the sol.
Claim 5
Dependent Claim
32 words
A method of claim 1, wherein particles from said partially dewatered sol are deposited onto the surface of said substrate by spraying the partially dewatered sol onto the surface of said substrate.
Claim 6
Dependent Claim
30 words
The method of claim 1, wherein a reinforcement material is present in the sol in the form of a powder, shavings, fibers, colloids, platelets, whiskers, fines, ultrafines or mixtures thereof.
Claim 7
Dependent Claim
31 words
The method of claim 5, wherein the reinforcement material is selected from the group consisting of metal oxides, metal carbides, metal nitrides, silicon nitride, glass, carbons, metal powders and mixtures thereof.
Claim 8
Independent Claim
201 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of between about 4 and about 5 comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between 10,000:1 and 2:1, and said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium, and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between 10 weight % and about 90 weight %; (c) depositing particles from said partially dewatered sol onto the surface of a substrate, said substrate and said sol being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (d) drying said coated substrate.
Claim 9
Independent Claim
201 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of between about 4 and about 5 comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between 10,000:1 and 2:1, and said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium, and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between 10 weight % and about 90 weight %; (c) depositing particles from said partially dewatered sol onto the surface of a substrate, said substrate and said sol being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (d) drying said coated substrate.
Claim 10
Independent Claim
216 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of about between 0.01 and about 7 and comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between about 10,000:1 and 2:1, said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between about 10 weight % and about 90 weight %; (c) establishing a temperature differential between a substrate and said partially dewatered sol; (d) depositing particles from said partially dewatered sol onto the surface of said substrate, said substrate and said sol being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (e) drying said coated substrate.
Claim 11
Independent Claim
216 words
A method of thermophoretically depositing a ceramic coating onto a substrate, comprising the steps of: (a) hydrolyzing and peptizing a metal oxide precursor in an aqueous medium in the presence of an acidic peptizing agent at a temperature and for a time effective to produce a sol having a colloid particle size of between about 0.0005 and about 10 microns, said aqueous medium having a pH of about between 0.01 and about 7 and comprising a member selected from the group consisting of water and a mixture of water and an organic solvent having a water:solvent ratio of between about 10,000:1 and 2:1, said metal oxide precursor being selected from the group consisting of aluminum, silicon, hafnium, lanthanum, titanium, magnesium, thorium, uranium, tantalum, germanium and zirconium alkoxides, organo orthosilicates and mixtures thereof; (b) partially dewatering said sol by reducing the volume of water in said sol to between about 10 weight % and about 90 weight %; (c) establishing a temperature differential between a substrate and said partially dewatered sol; (d) depositing particles from said partially dewatered sol onto the surface of said substrate, said substrate and said sol being maintained at a temperature differential of between about 10° C. and about 1500° C., thereby producing a coated substrate; and then (e) drying said coated substrate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-04-30 | 1993-10-30 | 1994-05-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-30 | 1997-10-30 | 1998-05-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-30 | 2001-10-30 | 2002-05-01 | $7700.00 | Window Closed / Lapsed |