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US4883769A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making a multidimensional quantum-well array

Assignee: United States Department of the Army
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Filing: 1988-08-18
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Granted: 1989-11-28
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Expires: 2008-08-18
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Abstract

Abstract Multidimensional quantum-well arrays are made by electron-beam lithographicatterning, followed by solid-state diffusion.

Inventors

  • 👤 Thomas R. Au Coin
  • 👤 Walter D. Braddock IV
  • 👤 Gerald J. Iafrate

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:19
CPC Classifications
H; H10; H10P; H10P76/00; H10P76/20; H10P76/204; B; B82; B82Y; B82Y10/00; H10D; H10D62/00; H10D62/80; H10D62/81; H10D62/812; H10D62/814; H10D84/00; H10D84/01; H10D84/02; H10D84/05; Y; Y10; Y10S; Y10S148/00; Y10S148/003; Y10S148/015; Y10S148/157; Y10S438/00; Y10S438/914; Y10S438/916

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 221 words
Method of making a multidimensional quantum-well array from a single crystal wafer of gallium arsenide as the substrate including the steps of: (A) epitaxially depositing a film of about 5000 Å of gallium arsenide onto the top surface of the substrate, (B) depositing thereover a superlattice buffer of ten periods of approximately 100 Å of gallium arsenide and 15 Å of gallium aluminum arsenide, (C) epitaxially depositing about 5000 Å of gallium arsenide onto the superlattice buffer, (D) epitaxially depositing about 1000 Å of gallium aluminum arsenide thereover, (E) epitaxially depositing about 500 Å of gallium arsenide thereover, (F) depositing about 500 Å of silicon dioxide thereover, (G) spinning an electron-beam sensitive resist onto the silicon dioxide film to a thickness of about 1000 to 2000 Å and exposing the resist to an electron beam focused properly and of sufficient flux to produce an array of circularly exposed areas of about 500 Å diameter, (H) developing the exposed areas to open circular holes of about 500 Å in diameter on the surface of the deposited silicon dioxide, (I) etching circular holes in the silicon dioxide layer, (J) stripping the e-beam resist from the silica layer and placing the resulting sample in a suitable annealing furnace, and (K) heating the sample to about 900° C. for about 15 seconds and then cooling.
Claim 2
Dependent Claim 221 words
Method of making a multidimensional quantum-well array from a single crystal wafer of gallium arsenide as the substrate including the steps of: (A) epitaxially depositing a film of about 5000 Å of gallium arsenide onto the top surface of the substrate, (B) depositing thereover a superlattice buffer of ten periods of approximately 100 Å of gallium arsenide and 15 Å of gallium aluminum arsenide, (C) epitaxially depositing about 5000 Å of gallium arsenide onto the superlattice buffer, (D) epitaxially depositing about 1000 Å of gallium aluminum arsenide thereover, (E) epitaxially depositing about 500 Å of gallium arsenide thereover, (F) depositing about 500 Å of silicon dioxide thereover, (G) spinning an electron-beam sensitive resist onto the silicon dioxide film to a thickness of about 1000 to 2000 Å and exposing the resist to an electron beam focused properly and of sufficient flux to produce an array of circularly exposed areas of about 500 Å diameter, (H) developing the exposed areas to open circular holes of about 500 Å in diameter on the surface of the deposited silicon dioxide, (I) etching circular holes in the silicon dioxide layer, (J) stripping the e-beam resist from the silica layer and placing the resulting sample in a suitable annealing furnace, and (K) heating the sample to about 900° C. for about 15 seconds and then cooling.
Claim 3
Dependent Claim 13 words
Method according to claim 1 wherein the electron beam sensitive resist is PMMA.
Claim 4
Dependent Claim 19 words
Method according to claim 1 wherein the circular holes are etched in the silicon dioxide layer by plasma techniques.
Claim 5
Dependent Claim 20 words
Method according to claim 1 wherein the circular holes are etched in the silicon dioxide layer by wet chemical techniques.
Claim 6
Dependent Claim 14 words
Method according to claim 1 wherein the annealing furnace is a rapid thermal annealer.
Claim 7
Dependent Claim 225 words
Method of making a multidimensional quantum-well array from a single crystal wafer of gallium arsenide as the substrate including the steps of: (A) epitaxially depositing a film of about 5000 Å of gallium arsenide onto the top surface of the substrate, (B) depositing thereover a superlattice buffer of ten periods of approximately 100 Å of gallium arsenide and 15 Å of gallium aluminum arsenide, (C) epitaxially depositing about 5000 Å of gallium arsenide onto the superlattice buffer, (D) epitaxially depositing about 1000 Å of gallium aluminum arsenide thereover, (E) epitaxially depositing about 500 Å of gallium arsenide thereover, (F) depositing about 1000 to 3000 Å of silicon dioxide thereover, (G) spinning an electron-beam resist of PMMA onto the silicon dioxide film to a thickness of about 500 Å and exposing the resist to an electron beam focused properly and a sufficient flux to produce an array of circularly exposed areas of about 500 Å diameter, (H) developing the exposed areas to open circular holes of about 500 Å diameter on the surface of the deposited silicon dioxide, (I) etching circular holes in the silicon dioxide layer by wet chemical techniques, (J) stripping the e-beam resist from the silica layer and placing the resulting sample in a rapid thermal annealer, and (K) heating the sample to about 900° C. for about 15 seconds and then cooling.
Claim 8
Dependent Claim 225 words
Method of making a multidimensional quantum-well array from a single crystal wafer of gallium arsenide as the substrate including the steps of: (A) epitaxially depositing a film of about 5000 Å of gallium arsenide onto the top surface of the substrate, (B) depositing thereover a superlattice buffer of ten periods of approximately 100 Å of gallium arsenide and 15 Å of gallium aluminum arsenide, (C) epitaxially depositing about 5000 Å of gallium arsenide onto the superlattice buffer, (D) epitaxially depositing about 1000 Å of gallium aluminum arsenide thereover, (E) epitaxially depositing about 500 Å of gallium arsenide thereover, (F) depositing about 1000 to 3000 Å of silicon dioxide thereover, (G) spinning an electron-beam resist of PMMA onto the silicon dioxide film to a thickness of about 500 Å and exposing the resist to an electron beam focused properly and a sufficient flux to produce an array of circularly exposed areas of about 500 Å diameter, (H) developing the exposed areas to open circular holes of about 500 Å diameter on the surface of the deposited silicon dioxide, (I) etching circular holes in the silicon dioxide layer by wet chemical techniques, (J) stripping the e-beam resist from the silica layer and placing the resulting sample in a rapid thermal annealer, and (K) heating the sample to about 900° C. for about 15 seconds and then cooling.

References Cited (Backward Citations)

US4261771A Cited
US4503447A Cited
US4637122A Cited
US4654090A Cited
US4748132A Cited
US4771010A Cited
US4751946A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-27 1993-05-29 1993-11-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-27 1997-05-29 1997-11-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-27 2001-05-29 2001-11-28 $7700.00 Window Closed / Lapsed

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