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US4857579A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermosettable fiber reinforced resin compositions

Assignee: Union Carbide Corp
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Filing: 1987-11-25
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Granted: 1989-08-15
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Expires: 2007-11-25
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Abstract

Abstract Described herein are curable molding compositions comprising a mixture of: I. from about 25 to about 90 weight percent of a thermosetting resin containing: (a) from about 5 to about 95 weight percent of a polyester resin derived from the reaction of a poly(acrylate) and a vinyl monomer, said poly(acrylate) and vinyl monomer essentially free from functional groups reactive with the polyol or the polyisocyanate of (b); (b) from about 95 to about 5 weight percent of a polyurethane derived from the reaction of a saturated polyol and a polyisocyanate, said polyol and polyisocyanate free from unsaturated groups capable of copolymerizing with the poly(acrylate) or vinyl monomer of (a); and II. from about 75 to about 10 weight percent of one or more fibers with a melting point or a glass transition temperature above about 130° C.; wherein (b) constitutes less than 40 weight percent of (I) and (II).

Inventors

  • 👤 Linda A. Domeier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 09:06
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/63; C08G18/637; C08K; C08K7/00; C08K7/02; C08L75/00; C08L75/04; C08G2120/00; C08L2205/00; C08L2205/14; C08L2205/16

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 231 words
A curable molding composition consisting of a mixture of: I. from about 25 to 50 weight percent of a thermosetting resin containing: (a) from about 25 to about 75 weight percent of a polyesfter resin produced by the coreaction of a poly(acrylate) and styrene in the presence of a catalyst for said coreaction, said poly(acrylate) being essentially free from functional groups reactive with the polyol or the polyisocyanate of (b); said poly(acrylate) being characterized by the following emprical formula: ##STR12## wherein R is the residue of an organic polyhydric alcohol which contained alcoholic hydroxyl groups bonded to different carbon atoms, R 1 and R 2 are independently hydrogen or methyl, and n is 1 to 3; (b) from about 75 to about 25 weight percent of a polyurethane produced by the reaction of (i) a saturated polyol having a functionality of from about 2 to about 8 and an equivalent weight of from about 30 to about 350 and (ii) a polyisocyanate having an isocyanate equivalent weight of less than about 300, said polyol and polyisocyante being free from unsaturated groups capable of copolymerizing with the poly(acrylate) or styrene of (a); and II. from about 75 to about 50 weight percent of one or more fibers having a melting point or a glass transition temperature above about 130° C.; wherein (b) constitutes less than 40 weight percent of (I) and (II).
Claim 2
Dependent Claim 231 words
A curable molding composition consisting of a mixture of: I. from about 25 to 50 weight percent of a thermosetting resin containing: (a) from about 25 to about 75 weight percent of a polyesfter resin produced by the coreaction of a poly(acrylate) and styrene in the presence of a catalyst for said coreaction, said poly(acrylate) being essentially free from functional groups reactive with the polyol or the polyisocyanate of (b); said poly(acrylate) being characterized by the following emprical formula: ##STR12## wherein R is the residue of an organic polyhydric alcohol which contained alcoholic hydroxyl groups bonded to different carbon atoms, R 1 and R 2 are independently hydrogen or methyl, and n is 1 to 3; (b) from about 75 to about 25 weight percent of a polyurethane produced by the reaction of (i) a saturated polyol having a functionality of from about 2 to about 8 and an equivalent weight of from about 30 to about 350 and (ii) a polyisocyanate having an isocyanate equivalent weight of less than about 300, said polyol and polyisocyante being free from unsaturated groups capable of copolymerizing with the poly(acrylate) or styrene of (a); and II. from about 75 to about 50 weight percent of one or more fibers having a melting point or a glass transition temperature above about 130° C.; wherein (b) constitutes less than 40 weight percent of (I) and (II).
Claim 3
Dependent Claim 17 words
A molding composition as defined in claim 1 wherein the poly(acrylate) is ethoxylated bisphenol-A dimethacrylate or diacrylate.
Claim 4
Dependent Claim 17 words
A molding composition as defined in claim 1 wherein the poly(acrylate) is tetraethylene glycol dimethacrylate or diacrylate.
Claim 5
Dependent Claim 17 words
A molding composition as defined in claim 1 wherein the poly(acrylate) is diethylene glycol dimethacrylate or diacrylate.
Claim 6
Dependent Claim 24 words
A molding composition as defined in claim 1 wherein the poly(acrylate) and styrene are combined in proportions of from about 30:70 to about 70:30.
Claim 7
Dependent Claim 35 words
A molding composition as defined in claim 1 wherein the polyol and polyisocyanate are combined such that the molar ratio of isocyanate to hydroxyl groups is in the range of from about 1.2:1 to 0.8:1.
Claim 8
Dependent Claim 25 words
A molding composition as defined in claim 1 wherein the catalyst for the coreaction of the poly(acrylate) and styrene is a peroxide or azo compound.
Claim 9
Dependent Claim 17 words
A molding composition as defined in claim 1 which contains a catalyst for formation of the polyurethane.
Claim 10
Dependent Claim 25 words
A molding composition as designed in claim 1 in which the thermosetting resin contains about 50 weight percent of each of the polyester and polyurethane.
Claim 11
Dependent Claim 21 words
A molding composition as defined in claim 1 wherein the fibers are fiberglass, carbon fibers, aromatic polyamide fibers, or mixtures thereof.
Claim 12
Dependent Claim 21 words
A molding composition as defined in claims 1 or 10 which contains no more than about 65 weight percent of fiber.
Claim 13
Dependent Claim 14 words
A molded article produced from the composition of claims 1, 2, 3, or 4.

References Cited (Backward Citations)

US3700752A Cited
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US3886229A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-14 1993-02-13 1993-08-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-14 1997-02-13 1997-08-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-14 2001-02-13 2001-08-15 $7700.00 Window Closed / Lapsed

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