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US4806825A Expired / Lapsed US ⏱️ 0.0 years remaining

Infra-red phosphors

Assignee: EMI Group Ltd
•
Filing: 1988-05-19
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Granted: 1989-02-21
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Expires: 2008-05-19
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Abstract

Abstract A phosphor comprises a chromium activated alkaline earth aluminate having a hexagonal crystal structure and incorporates divalent europium as a sensitizer. The phosphor may also incorporate one or more of divalent manganese and/or zinc and/or magnesium. Such a phosphor emits in the infra-red.

Inventors

  • 👤 Colin L. R. Catherall
  • 👤 Martin J. Fuller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:37
CPC Classifications
H; H01; H01J; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/44; C; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7728; C09K11/7734

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 149 words
A trivalent chromium activated alkaline earth aluminate phosphor having a hexagonal crystal structure and divalent europium and optionally one or more of divalent manganese and zinc incorporated therein, and emitting in the region of the electromagnetic spectrum between 650 and 800 nm, having a composition represented by: (A.sub.(w-y) B.sub.x Eu.sub.y Cr.sub.z)O.sub.(w+x+3z/2) Al.sub.2 O.sub.3 where A is barium, strontium or a combination thereof, B is magnesium which is replaceable partly or wholly by zinc and/or divalent manganese, w is in the range of from 0.01 to 0.6, x is in the range of from 0.01 to 0.98, y is in the range of from 0.005 w to 0.70 w, and z is in the range of from 0.0001 to 0.06, the divalent europium functioning as a sensitizer by absorbing ultraviolet radiation incident thereon and converting said radiation to energies that are absorbed by trivalent chromium and converted to infra-red radiation.
Claim 2
Dependent Claim 149 words
A trivalent chromium activated alkaline earth aluminate phosphor having a hexagonal crystal structure and divalent europium and optionally one or more of divalent manganese and zinc incorporated therein, and emitting in the region of the electromagnetic spectrum between 650 and 800 nm, having a composition represented by: (A.sub.(w-y) B.sub.x Eu.sub.y Cr.sub.z)O.sub.(w+x+3z/2) Al.sub.2 O.sub.3 where A is barium, strontium or a combination thereof, B is magnesium which is replaceable partly or wholly by zinc and/or divalent manganese, w is in the range of from 0.01 to 0.6, x is in the range of from 0.01 to 0.98, y is in the range of from 0.005 w to 0.70 w, and z is in the range of from 0.0001 to 0.06, the divalent europium functioning as a sensitizer by absorbing ultraviolet radiation incident thereon and converting said radiation to energies that are absorbed by trivalent chromium and converted to infra-red radiation.
Claim 3
Dependent Claim 11 words
A phosphor according to claim 1 having divalent manganese incorporated therein.
Claim 4
Dependent Claim 18 words
A phosphor according to claim 1 in which w is in the range of from 0.015 to 0.35.
Claim 5
Dependent Claim 18 words
A phosphor according to claim 3 in which w is in the range of from 0.075 to 0.30.
Claim 6
Dependent Claim 18 words
A phosphor according to claim 1 in which x is in the range of from 0.012 to 0.65.
Claim 7
Dependent Claim 18 words
A phosphor according to claim 5 in which x is in the range of from 0.055 to 0.45.
Claim 8
Dependent Claim 20 words
A phosphor according to claim 1 in which y is in the range of from 0.005 w to 0.50 w.
Claim 9
Dependent Claim 20 words
A phosphor according to claim 7 in which y is in the range of from 0.0075 w to 0.25 w.
Claim 10
Dependent Claim 18 words
A phosphor according to claim 1 in which z is in the range of from 0.0003 to 0.025.
Claim 11
Dependent Claim 18 words
A phosphor according to claim 9 in which z is in the range of from 0.0005 to 0.0125.
Claim 12
Dependent Claim 11 words
A luminescent screen comprising a phosphor as claimed in claim 1.
Claim 13
Dependent Claim 20 words
A fluorescent lamp comprising an envelope, the internal surface of which is coated with a phosphor according to claim 1.
Claim 14
Dependent Claim 16 words
A fluorescent lamp according to claim 12 which is a low pressure mercury vapour discharge lamp.
Claim 15
Dependent Claim 16 words
A fluorescent lamp according to claim 12 which is a low pressure cadmium vapour discharge lamp.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-02-21 1992-08-22 1993-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-02-21 1996-08-22 1997-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-02-21 2000-08-22 2001-02-21 $7700.00 Window Closed / Lapsed

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