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US4760122A Expired / Lapsed US ⏱️ 0.0 years remaining

Cluster acrylic silicones having cyclic clusters

Assignee: Henkel Loctite Corp
•
Filing: 1986-01-06
•
Granted: 1988-07-26
•
Expires: 2006-01-06
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Abstract

Abstract Novel polyorganosiloxane polymers having at least one terminal cyclic diorganosiloxane moiety containing a plurality of acrylic units of the formula ##STR1## wherein R 1 is H or lower alkyl; X is O, NH or S; and Y is a divalent linking group.

Inventors

  • 👤 Steven T. Nakos
  • 👤 Samuel Q. Lin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:26
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/48; C08G77/50; C08G77/04; C08G77/20; Y; Y10; Y10S; Y10S525/00; Y10S525/901; Y10S525/91

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 119 words
A polyorganosiloxane polymer having a structure represented by one of the formulas: (AB).sub.m C or [(AB).sub.m ].sub.n SiR.sub.(4-n) where A is a cyclic diorganosiloxane moiety comprising between 4 and 8 siloxane repeat units, including a plurality of units of the formula ##STR15## where R 1 is H or lower alkyl, X is O, NH or S, and Y is a divalent linking group; B is an organosiloxane segment represented by the formula: ##STR16## C is A or triorganosilyl group; the R groups are the same or different organo groups other than acrylic groups or groups co-curable therewith; m is an integer of 1 or more; n is 3 or 4; and x is an integer of at least 100.
Claim 2
Dependent Claim 119 words
A polyorganosiloxane polymer having a structure represented by one of the formulas: (AB).sub.m C or [(AB).sub.m ].sub.n SiR.sub.(4-n) where A is a cyclic diorganosiloxane moiety comprising between 4 and 8 siloxane repeat units, including a plurality of units of the formula ##STR15## where R 1 is H or lower alkyl, X is O, NH or S, and Y is a divalent linking group; B is an organosiloxane segment represented by the formula: ##STR16## C is A or triorganosilyl group; the R groups are the same or different organo groups other than acrylic groups or groups co-curable therewith; m is an integer of 1 or more; n is 3 or 4; and x is an integer of at least 100.
Claim 3
Dependent Claim 38 words
A polyorganosiloxane as in claim 1 where the A segment is defined by the formula: ##STR17## where R is as previously defined, R 1 is H or alkyl, R 2 is alkylene or alkenylene and m is 3-7.
Claim 4
Dependent Claim 10 words
A polyorganosiloxane as in claim 2 where R is H.
Claim 5
Dependent Claim 10 words
A polyorganosiloxane as in claim 3 where m is 3.
Claim 6
Dependent Claim 34 words
A polyorganosiloxane as in claim 2 represented by the formula: ##STR18## where R is methyl, R 1 is H and R 2 is propenyl, and t is an integer of from 1 to 5.
Claim 7
Dependent Claim 59 words
A polyorganosiloxane as in claim 1 where the A segment is defined by the formula: ##STR19## where R, is as defined in claim 1, R is H or alkyl, R 2 is alkylene or alkenylene and R 4 is hydrocarbyl oxyhydrocarbyl, halo substituted hydrocarbyl or ##STR20## j is at least 2, k is 1-2, l is 0-5 and j+k+l=4-8.
Claim 8
Dependent Claim 10 words
A polyorganosiloxane as in claim 6 where l is 0-0.5.
Claim 9
Dependent Claim 16 words
A polyorganosiloxane as in claim 6 where j is at least 2.5 and k is 1-1.5.
Claim 10
Dependent Claim 11 words
A polyorganosiloxane as in claim 6 represented by the formula: ##STR21##
Claim 11
Dependent Claim 11 words
A polyorganosiloxane as in claim 6 represented by the formula: ##STR22##
Claim 12
Dependent Claim 84 words
A polyorganosiloxane represented by the formula A BC where A is a monovalent cyclic organosiloxane represented by the formula: ##STR23## where R is alkyl or aryl, R 1 is H or alkyl, R 2 is alkylene or alkenylene, R 4 is hydrocarbyl, oxyhydrocarbyl, halo substituted hydrocarbyl or ##STR24## j is at least 2, k is 1-2, l is 0-5 and j+k+l is 4-8; B is represented by the formula: ##STR25## where x is at least 2; and C is A or a triorganosilyl group.
Claim 13
Dependent Claim 84 words
A polyorganosiloxane represented by the formula A BC where A is a monovalent cyclic organosiloxane represented by the formula: ##STR23## where R is alkyl or aryl, R 1 is H or alkyl, R 2 is alkylene or alkenylene, R 4 is hydrocarbyl, oxyhydrocarbyl, halo substituted hydrocarbyl or ##STR24## j is at least 2, k is 1-2, l is 0-5 and j+k+l is 4-8; B is represented by the formula: ##STR25## where x is at least 2; and C is A or a triorganosilyl group.
Claim 14
Dependent Claim 10 words
A polyorganosiloxane as in claim 11 where C is A.
Claim 15
Dependent Claim 10 words
A polyorganosiloxane as in claim 11 where C is ##STR26##

References Cited (Backward Citations)

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US4364809A Cited
US4424328A Cited
US4503208A Cited
US4575545A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-26 1992-01-25 1992-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-26 1996-01-25 1996-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-26 2000-01-25 2000-07-26 $7700.00 Window Closed / Lapsed

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