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US4680044A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of modifying the refractive index of fluoride glass

Assignee: Raytheon Co
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Filing: 1985-11-25
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Granted: 1987-07-14
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Expires: 2005-11-25
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Abstract

Abstract The present invention relates to a method of producing a fluoride glass preform and/or fiber having a modified refractive index by heating the fluoride glass preform to a temperature that is above its glass transition temperature, but below its devitrification temperature; inserting a first electrode into the inner core of the preform and surrounding the outer perimeter of the preform with a second electrode of opposite polarity; means for generating an electromotive force; and applying an electromotive force through the first electrode and the second electrode which causes a movement of positive ions toward the electrode of opposite charge while simultaneously causing a movement of negative ions toward its electrode of opposite charge such that the movement of these ions results in a modification of the refractive index of the preform.

Inventors

  • 👤 Ricardo C. Pastor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 05:48
CPC Classifications
C; C03; C03C; C03C25/00; C03B; C03B37/00; C03B37/01; C03B37/02; C03B37/025; C03B37/027; C03C23/00; C03C25/62; C03C25/6206; C03C25/6208; C03B2201/00; C03B2201/80; C03B2201/82; C03B2205/00; C03B2205/02; Y; Y10; Y10S; Y10S65/00; Y10S65/15; Y10S65/16

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 137 words
A method of modifying the refractive index of a fluoride glass preform having an outer periphery and an inner core comprising: (a) heating the fluoride glass preform to a temperature that is above its glass transition temperature, but below its devitrification temperatue; (b) inserting a first electrode into the inner core of the preform and surrounding the outer perimeter of the preform with a second electrode of opposite polarity; (c) generating an electromotive force using a generating means; and (d) applying an electromotive force through the first electrode and the second electrode which causes a movement of positive ions toward the electrode of opposite charge while simultaneously causing a movement of negative ions toward its electrode of opposite charge such that the movement of these ions results in a modification of the refractive index of the preform.
Claim 2
Independent Claim 137 words
A method of modifying the refractive index of a fluoride glass preform having an outer periphery and an inner core comprising: (a) heating the fluoride glass preform to a temperature that is above its glass transition temperature, but below its devitrification temperatue; (b) inserting a first electrode into the inner core of the preform and surrounding the outer perimeter of the preform with a second electrode of opposite polarity; (c) generating an electromotive force using a generating means; and (d) applying an electromotive force through the first electrode and the second electrode which causes a movement of positive ions toward the electrode of opposite charge while simultaneously causing a movement of negative ions toward its electrode of opposite charge such that the movement of these ions results in a modification of the refractive index of the preform.
Claim 3
Dependent Claim 41 words
The method of claim 1 further comprising a second electrode which surrounds the outer perimeter of the preform having an aperture, such that a laser beam directed through the aperture will provide irradiation, resulting in photoactivation of ions within the preform.
Claim 4
Dependent Claim 46 words
The method of claim 1 further comprising a first electrode and a second electrode such that the symmetry and configuration of such first and second electrode is modified to a predetermined arrangement in order to modify the refractive index of the preform to a desired level.
Claim 5
Dependent Claim 12 words
The method of claim 1 wherein the electromotive force generated is pulsed.
Claim 6
Independent Claim 144 words
A method of modifying the refractive index of a fluoride glass preform having an outer periphery and an inner core comprising: (a) heating the fluoride glass preform to a temperature that is above its glass transition temperature, but below its devitrification temperatue; (b) inserting a cathode into the inner core of the preform and surrounding the outer perimeter of the preform with an anode; (c) generating an electromotive force using a generating means; (d) applying an electromotive force through the cathode and the anode which causes a movement of positive ions from the outer periphery of the preform toward the cathode at the inner core while simultaneously causing a movement of negative ions toward the anode at the outer periphery of the preform, such that a higher refractive index is thereby induced at the inner core of the preform than at its outer periphery.
Claim 7
Independent Claim 144 words
A method of modifying the refractive index of a fluoride glass preform having an outer periphery and an inner core comprising: (a) heating the fluoride glass preform to a temperature that is above its glass transition temperature, but below its devitrification temperatue; (b) inserting a cathode into the inner core of the preform and surrounding the outer perimeter of the preform with an anode; (c) generating an electromotive force using a generating means; (d) applying an electromotive force through the cathode and the anode which causes a movement of positive ions from the outer periphery of the preform toward the cathode at the inner core while simultaneously causing a movement of negative ions toward the anode at the outer periphery of the preform, such that a higher refractive index is thereby induced at the inner core of the preform than at its outer periphery.
Claim 8
Dependent Claim 40 words
The method of claim 5 further comprising an anode which surrounds the outer perimeter of the preform having an aperture, such that a laser beam directed through the aperture will provide irradiation, resulting in photoactivation of ions within the preform.
Claim 9
Dependent Claim 43 words
The method of claim 5 further comprising an anode and a cathode such that the symmetry and configuration of such anode and cathode is modified to a predetermined arrangement in order to modify the refractive index of the preform to a desired level.
Claim 10
Dependent Claim 12 words
The method of claim 5 wherein the electromotive force generated is pulsed.
Claim 11
Dependent Claim 26 words
The method of claim 7 wherein the anode and the cathode of a square configuration, thereby assisting in the production of a ribbon or flat fiber.

References Cited (Backward Citations)

US4388097A Cited
US4504300A Cited
JPS59137329A Cited
US4537864A Cited
US4578252A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-07-13 1991-01-12 1991-07-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-07-13 1995-01-12 1995-07-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-07-13 1999-01-12 1999-07-14 $7700.00 Window Closed / Lapsed

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