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US4644045A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making spunbonded webs from linear low density polyethylene

Assignee: Fort James Corp
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Filing: 1986-03-14
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Granted: 1987-02-17
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Expires: 2006-03-14
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Abstract

Abstract Spunbonded nonwoven webs having excellent properties, particularly softness, can be made from linear low density polyethylene having a critical combination of certain key properties. These properties are percent crystallinity, cone die melt flow, die swell, relation of die swell to melt index, and polymer uniformity. The polyethylene is extruded through a spinneret at a temperature between about 185° and 215° C. and drawn through an air gun to form the spunbonded web.

Inventors

  • 👤 R. William Fowells

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 09:42
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; Y; Y10; Y10S; Y10S264/00; Y10S264/75; Y10T; Y10T442/00; Y10T442/60; Y10T442/681

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 133 words
In the method of forming a spunbonded nonwoven web of continuous polyolefin filaments by extruding the polyolefin at a temperature above its melting point through a spinneret to form filaments of the polyolefin, drawing the filaments with an air gun, and depositing the filaments on a web-forming surface to form the nonwoven web, the improvement wherein the polyolefin is a linear copolymer of ethylene and an ethylenically unsaturated alpha-olefin having 4 to 8 carbon atoms, the copolymer having a percent crystallinity of at least 33 percent, a cone die melt flow of between about 65 and 85 grams/ten minutes, and a ratio of the natural logarithm of die swell to melt index of between about 0.014 and 0.020, and wherein the copolymer is extruded at a temperature between about 185° and 215° C.
Claim 2
Dependent Claim 133 words
In the method of forming a spunbonded nonwoven web of continuous polyolefin filaments by extruding the polyolefin at a temperature above its melting point through a spinneret to form filaments of the polyolefin, drawing the filaments with an air gun, and depositing the filaments on a web-forming surface to form the nonwoven web, the improvement wherein the polyolefin is a linear copolymer of ethylene and an ethylenically unsaturated alpha-olefin having 4 to 8 carbon atoms, the copolymer having a percent crystallinity of at least 33 percent, a cone die melt flow of between about 65 and 85 grams/ten minutes, and a ratio of the natural logarithm of die swell to melt index of between about 0.014 and 0.020, and wherein the copolymer is extruded at a temperature between about 185° and 215° C.
Claim 3
Dependent Claim 19 words
The improvement of claim 1 wherein the copolymer has a degree of cystallinity between about 43 and 58 percent.
Claim 4
Dependent Claim 17 words
The improvement of claim 1 wherein the percent crystallinity is determined by measuring the enthalpy of fusion.
Claim 5
Dependent Claim 19 words
The improvement of claim 3 wherein the enthalpy of fusion is between about 30 and 40 calories per gram.
Claim 6
Dependent Claim 19 words
The improvement of claim 1 wherein the copolymer has a melt index between about 25 and 40 grams/ten minutes.
Claim 7
Dependent Claim 19 words
The improvement of claim 1 wherein the copolymer has a melt index between about 30 and 36 grams/ten minutes.
Claim 8
Dependent Claim 17 words
The improvement of claim 1 wherein the copolymer has a die swell between about 1.60 and 1.85.
Claim 9
Dependent Claim 15 words
The improvement of claim 1 wherein the copolymer has a density less than about 0.955.
Claim 10
Dependent Claim 17 words
The improvement of claim 1 wherein the copolymer has a die swell between about 1.50 and 1.95.
Claim 11
Dependent Claim 18 words
The improvement of claim 9 wherein the copolymer has a peak width of less than about 25 degrees.
Claim 12
Dependent Claim 165 words
In the method of forming a spunbonded nonwoven web of continuous polyolefin filaments by extruding the polyolefin at a temperature above its melting point through a spinneret to form filaments of the polyolefin, drawing the filaments with an air gun, and depositing the filaments on a web-forming surface to form the nonwoven web, the improvement wherein the polyolefin is a linear copolymer of ethylene and an ethylenically unsaturated alpha-olefin having 4 to 8 carbon atoms, the copolymer having a percent crystallinity as determined from enthalpy of fusion of between about 43 and 58 percent, a cone die melt flow between about 65 and 85 grams/ten minutes, a die swell between about 1.50 and 1.95, a melt index between 25 and 40grams/ten minutes, a ratio of the natural logarithm of the die swell to the melt index between about 0.014 and 0.020, a peak width of less than about 25 degrees, and wherein the copolymer is extruded at a temperature between about 185° and 215° C.
Claim 13
Dependent Claim 165 words
In the method of forming a spunbonded nonwoven web of continuous polyolefin filaments by extruding the polyolefin at a temperature above its melting point through a spinneret to form filaments of the polyolefin, drawing the filaments with an air gun, and depositing the filaments on a web-forming surface to form the nonwoven web, the improvement wherein the polyolefin is a linear copolymer of ethylene and an ethylenically unsaturated alpha-olefin having 4 to 8 carbon atoms, the copolymer having a percent crystallinity as determined from enthalpy of fusion of between about 43 and 58 percent, a cone die melt flow between about 65 and 85 grams/ten minutes, a die swell between about 1.50 and 1.95, a melt index between 25 and 40grams/ten minutes, a ratio of the natural logarithm of the die swell to the melt index between about 0.014 and 0.020, a peak width of less than about 25 degrees, and wherein the copolymer is extruded at a temperature between about 185° and 215° C.

References Cited (Backward Citations)

US3692618A Cited
US4298713A Cited
US4434204A Cited
US4554202A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-16 1990-08-18 1991-02-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-16 1994-08-18 1995-02-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-16 1998-08-18 1999-02-17 $7700.00 Window Closed / Lapsed

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