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US4629663A Expired / Lapsed US ⏱️ 0.0 years remaining

Removable pressure-sensitive adhesive tape

Assignee: 3M Co
•
Filing: 1984-10-29
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Granted: 1986-12-16
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Expires: 2004-10-29
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Abstract

Abstract The adhesive layer of the novel pressure-sensitive adhesive tape comprises a polymer of a terminally unsaturated vinyl monomer such as isooctyl acrylate and an emulsifier monomer such as sodium styrene sulfonate. Preferably, the adhesive layer also contains a small amount of a noncationic external emulsifier such as sodium dodecylbenzene sulfonate. Although the tape has excellent adhesive properties, it is removable from a variety of surfaces after one hour at 120° C. and so is useful for purposes such as automotive masking tape.

Inventors

  • 👤 Francis W. Brown
  • 👤 Louis E. Winslow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:35
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/08; C09J7/00; C09J7/30; C09J7/38; C09J7/381; C09J7/385; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852; Y10T428/2878; Y10T428/2887; Y10T428/2891

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 208 words
Pressure-sensitive adhesive tape comprising a self-substaining backing sheet carrying a layer of pressure-sensitive adhesive comprising a copolymer of monomers comprising (a) from 95 to 99.8 parts by weight of at least one terminally unsaturated vinyl monomer, 60 to 100 weight percent of said monomer being selected from the class of nontertiary alkyl acrylates wherein each alkyl group has at least half of its carbon atoms in a single chain and the average length of the alkyl chain is at least 4 and not more than 12, and (b) from 0.2 to 5 parts by weight of at least one vinyl-unsaturated homopolymerizable emulsifier monomer which is a surfactant having both a hydrophobic and a hydrophilic moiety, contains at least 5 but no more than 40 carbon atoms, and is water-dispersible, the total parts by weight (a) plus (b) being 100, wherein the improvement comprises: the emulsifer monomer is a monovalent salt of a styrene sulfonate and wherein the adhesive layer contains up to 1.5% external emulsifier by weight, whereby the tape not only has an adhesive value of at least about 40 N/dm and a cohesive value of at least 100 minutes but also can be cleanly removed from a melamine test surface after one hour at 150? C.
Claim 2
Dependent Claim 208 words
Pressure-sensitive adhesive tape comprising a self-substaining backing sheet carrying a layer of pressure-sensitive adhesive comprising a copolymer of monomers comprising (a) from 95 to 99.8 parts by weight of at least one terminally unsaturated vinyl monomer, 60 to 100 weight percent of said monomer being selected from the class of nontertiary alkyl acrylates wherein each alkyl group has at least half of its carbon atoms in a single chain and the average length of the alkyl chain is at least 4 and not more than 12, and (b) from 0.2 to 5 parts by weight of at least one vinyl-unsaturated homopolymerizable emulsifier monomer which is a surfactant having both a hydrophobic and a hydrophilic moiety, contains at least 5 but no more than 40 carbon atoms, and is water-dispersible, the total parts by weight (a) plus (b) being 100, wherein the improvement comprises: the emulsifer monomer is a monovalent salt of a styrene sulfonate and wherein the adhesive layer contains up to 1.5% external emulsifier by weight, whereby the tape not only has an adhesive value of at least about 40 N/dm and a cohesive value of at least 100 minutes but also can be cleanly removed from a melamine test surface after one hour at 150? C.
Claim 3
Dependent Claim 16 words
Pressure-sensitive adhesive tape as defined in claim 1 wherein said monomers are free from zwitterion monomer.
Claim 4
Dependent Claim 16 words
Pressure-sensitive adhesive tape as defined in claim 1 wherein the monovalent salt is sodium styrene sufonate.
Claim 5
Dependent Claim 16 words
Pressure-sensitive adhesive tape as defined in claim 1 wherein said vinyl monomer includes an N-substituted acrylamide.
Claim 6
Dependent Claim 22 words
Pressure-sensitive adhesive tape as defined in claim 1 wherein the amount of the emulsifier monomer is from 0.5 to 2 weight percent.
Claim 7
Dependent Claim 12 words
The adhesive of a pressure-sensitive adhesive tape as defined in claim 1.

References Cited (Backward Citations)

US3316200A Cited
US3551479A Cited
US3617368A Cited
US3770708A Cited
US3922464A Cited
US3931087A Cited
US4012560A Cited
US4387174A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-12-15 1990-06-16 1990-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-12-15 1994-06-16 1994-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-12-15 1998-06-16 1998-12-16 $7700.00 Window Closed / Lapsed

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