US4568660A
Expired / Lapsed
US
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Cycloolefin polymerization catalyst composition
Assignee: Metton America Inc
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Filing: 1984-11-16
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Granted: 1986-02-04
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Expires: 2004-11-16
Abstract
Abstract A polymerization catalyst composition including <IMAGE> wherein R is an alkyl group having 3 to 20 carbon atoms; m is 4 or 6 and n is 0 or 1. Preferably the composition also includes, <IMAGE> wherein R1 and R2 are independently hydrogen, an alkyl or alkoxy group of form 1 to 5 carbons. Preferably r is 1; m is 4 and R is nonyl and the molar ratio of WClmOn to <IMAGE> is from about 1:1 to about 1:3.
Inventors
- 👤 Daniel W. Klosiewicz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 19:58
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/64; B; B01; B01J; B01J27/00; B01J27/06; B01J27/132; C07; C07C; C07C37/00; C07C37/11; C07C37/14; C07C37/20; C08F; C08F32/00; C08F32/08; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08; C08L; C08L69/00
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
47 words
A polymerization catalyst composition comprising: ##STR22## wherein R is an alkyl group having 3 to 20 carbon atoms; R 1 and R 2 are independently hydrogen, an alkyl or alkoxy of from 1 to 5 carbons; m is 4 or 6 and n is 0 or 1.
Claim 2
Dependent Claim
47 words
A polymerization catalyst composition comprising: ##STR22## wherein R is an alkyl group having 3 to 20 carbon atoms; R 1 and R 2 are independently hydrogen, an alkyl or alkoxy of from 1 to 5 carbons; m is 4 or 6 and n is 0 or 1.
Claim 3
Dependent Claim
34 words
The composition of claim 1 wherein n is 1; m is 4 and R is nonyl and the molar ratio of WCl m O n to ##STR23## is from about 1:1 to about 1:3.
Claim 4
Dependent Claim
18 words
The composition of claim 1 further comprising a compound selected from the group consisting of 2,4-pentanedione and diglyme.
Claim 5
Dependent Claim
9 words
The composition of claim 1 further comprising a cycloolefin.
Claim 6
Dependent Claim
27 words
The composition of claim 1 further comprising a cycloolefin and the molar ratio of WCl m O n to ##STR24## is from about 1:1 to about 1:5.
Claim 7
Dependent Claim
24 words
The composition of claim 4 wherein said cycloolefin is dicyclopentadiene said dicyclopentadiene being at least 98 percent pure prior to addition to said composition.
Claim 8
Dependent Claim
24 words
The composition of claim 5 wherein said cycloolefin is dicyclopentadiene said dicyclopentadiene being at least 98 percent pure prior to addition to said composition.
Claim 9
Dependent Claim
37 words
The catalyst composition of claim 1 wherein said WCl m O n is a mixture of WCl 4 O and WCl 6 in a molar ratio of WCl 4 O to WCl 6 from 1:9 to 2:1.
Claim 10
Dependent Claim
81 words
A polymerization catalyst composition of the formula ##STR25## wherein R is an alkyl group of from 1 to 20 carbon atoms; R 1 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 2 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 3 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 4 is hydrogen or an alkyl group of from 1 to 5 carbon atoms.
Claim 11
Dependent Claim
81 words
A polymerization catalyst composition of the formula ##STR25## wherein R is an alkyl group of from 1 to 20 carbon atoms; R 1 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 2 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 3 is hydrogen or an alkyl group of from 1 to 5 carbon atoms; R 4 is hydrogen or an alkyl group of from 1 to 5 carbon atoms.
Claim 12
Dependent Claim
9 words
The composition of claim 9 further comprising a cycloolefin.
Claim 13
Dependent Claim
10 words
The composition of claim 10 wherein said cycloolefin is dicyclopentadiene.
Claim 14
Dependent Claim
36 words
A polymerization catalyst composition comprising: ##STR26## wherein m is 4 or 6; n is 0 or 1; and R 1 and R 2 are independently hydrogen, an alkyl or alkoxy of from 1 to 5 carbons.
Claim 15
Dependent Claim
36 words
A polymerization catalyst composition comprising: ##STR26## wherein m is 4 or 6; n is 0 or 1; and R 1 and R 2 are independently hydrogen, an alkyl or alkoxy of from 1 to 5 carbons.
Claim 16
Dependent Claim
13 words
The composition of claim 12 wherein n is 1 and m is 4.
Claim 17
Dependent Claim
28 words
The composition of claim 13 further comprising a cycloolefin and wherein the molar ratio of WCl m O n to ##STR27## is from about 1:1 to about 1:5.
Claim 18
Dependent Claim
24 words
The composition of claim 14 wherein said cycloolefin is dicyclopentadiene, said dicyclopentadiene being at least 98 percent pure prior to addition to said composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-02-03 | 1989-08-05 | 1990-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-02-03 | 1993-08-05 | 1994-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-02-03 | 1997-08-05 | 1998-02-04 | $7700.00 | Window Closed / Lapsed |