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US4563486A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymerizable composition comprising (a) phosphorus oxyacid (b) amine and (c) inorganic material

Assignee: Imperial Chemical Industries Ltd
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Filing: 1984-06-15
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Granted: 1986-01-07
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Expires: 2004-06-15
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Abstract

Abstract A polymerizable composition is formed from (a) a polymerizable olefinically unsaturated substance, (b) a phosphorus oxyacid and an organic amine, at least one of which bears a polymerizable olefinically unsaturated group and optionally (c) a particulate inorganic material. Such compositions are useful in dental applications.

Inventors

  • 👤 Jozef Nemcek
  • 👤 Thomas A. Roberts

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 07:40
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/022; A; A61; A61K; A61K6/00; A61K6/70; A61K6/71; A61K6/76; A61K6/77; A61K6/78

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 232 words
A polymerisable composition comprising (a) an organic medium which comprises a polymerisable olefinically unsaturated substance which bears one or more polymerisable olefinically unsaturated groups; (b) a phosphorous oxyacid having the formula: ##STR5## wherein R 1 is a hydrocarbyl group or a polyether or polyester chain; and R 2 is hydrogen or a hydrocarbyl group or a polyether or polyester chain; and (c) an organic amine having the formula: ##STR6## wherein R 3 is a hydrocarbyl group or a polyether or polyester chain, and R 4 and R 5 , which may be the same or different are hydrogen, hydrocarbyl or polyether or polyester chains, except that (i) at least one of the groups R 1 , R 2 , R 3 , R 4 and R 5 comprises a polymerisable olefinically unsaturated group (ii) at least one of the groups R 1 and R 2 and at least one of the groups R 3 , R 4 and R 5 is, or is derived from, a long chain alkyl group containing 8 to 22 carbon atoms or a polyether or polyester chain of molecular weight between 300 and 10,000; and (d) a particulate inorganic material which is dispersed in the mixture of said organic medium, said phosphorus oxyacid and said organic amine; and wherein the ratio of said phosphorus oxyacid to said organic amine is in the range from 0.5:1 to 100:1.
Claim 2
Dependent Claim 232 words
A polymerisable composition comprising (a) an organic medium which comprises a polymerisable olefinically unsaturated substance which bears one or more polymerisable olefinically unsaturated groups; (b) a phosphorous oxyacid having the formula: ##STR5## wherein R 1 is a hydrocarbyl group or a polyether or polyester chain; and R 2 is hydrogen or a hydrocarbyl group or a polyether or polyester chain; and (c) an organic amine having the formula: ##STR6## wherein R 3 is a hydrocarbyl group or a polyether or polyester chain, and R 4 and R 5 , which may be the same or different are hydrogen, hydrocarbyl or polyether or polyester chains, except that (i) at least one of the groups R 1 , R 2 , R 3 , R 4 and R 5 comprises a polymerisable olefinically unsaturated group (ii) at least one of the groups R 1 and R 2 and at least one of the groups R 3 , R 4 and R 5 is, or is derived from, a long chain alkyl group containing 8 to 22 carbon atoms or a polyether or polyester chain of molecular weight between 300 and 10,000; and (d) a particulate inorganic material which is dispersed in the mixture of said organic medium, said phosphorus oxyacid and said organic amine; and wherein the ratio of said phosphorus oxyacid to said organic amine is in the range from 0.5:1 to 100:1.
Claim 3
Dependent Claim 18 words
A polymerisable composition as claimed in claim 1 in which the particulate inorganic material is a siliceous material.
Claim 4
Dependent Claim 21 words
A polymerisable composition as claimed in claim 2 in which the siliceous material is a silicate based glass or a silica.
Claim 5
Dependent Claim 21 words
A polymerisable composition as claimed in claim 1 wherein the particulate inorganic material provides 20-70% by volume of the polymerisable composition.
Claim 6
Dependent Claim 21 words
A dental composition comprising a polymerisable composition as claimed in claim 1, free-radical initiating system, and optionally a particulate inorganic material.
Claim 7
Dependent Claim 17 words
A dental composition as claimed in claim 4 wherein the free-radical initiating system is a photo-initiator system.

References Cited (Backward Citations)

US3963512A Cited
US3956421A Cited
US4259117A Cited
US4222780A Cited
US4374937A Cited
US4439380A Cited
US4407984A Cited
US4442239A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-01-06 1989-07-08 1990-01-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-01-06 1993-07-08 1994-01-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-01-06 1997-07-08 1998-01-07 $7700.00 Window Closed / Lapsed

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