US4563486A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymerizable composition comprising (a) phosphorus oxyacid (b) amine and (c) inorganic material
Assignee: Imperial Chemical Industries Ltd
•
Filing: 1984-06-15
•
Granted: 1986-01-07
•
Expires: 2004-06-15
Abstract
Abstract A polymerizable composition is formed from (a) a polymerizable olefinically unsaturated substance, (b) a phosphorus oxyacid and an organic amine, at least one of which bears a polymerizable olefinically unsaturated group and optionally (c) a particulate inorganic material. Such compositions are useful in dental applications.
Inventors
- 👤 Jozef Nemcek
- 👤 Thomas A. Roberts
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 07:40
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/022; A; A61; A61K; A61K6/00; A61K6/70; A61K6/71; A61K6/76; A61K6/77; A61K6/78
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
232 words
A polymerisable composition comprising (a) an organic medium which comprises a polymerisable olefinically unsaturated substance which bears one or more polymerisable olefinically unsaturated groups; (b) a phosphorous oxyacid having the formula: ##STR5## wherein R 1 is a hydrocarbyl group or a polyether or polyester chain; and R 2 is hydrogen or a hydrocarbyl group or a polyether or polyester chain; and (c) an organic amine having the formula: ##STR6## wherein R 3 is a hydrocarbyl group or a polyether or polyester chain, and R 4 and R 5 , which may be the same or different are hydrogen, hydrocarbyl or polyether or polyester chains, except that (i) at least one of the groups R 1 , R 2 , R 3 , R 4 and R 5 comprises a polymerisable olefinically unsaturated group (ii) at least one of the groups R 1 and R 2 and at least one of the groups R 3 , R 4 and R 5 is, or is derived from, a long chain alkyl group containing 8 to 22 carbon atoms or a polyether or polyester chain of molecular weight between 300 and 10,000; and (d) a particulate inorganic material which is dispersed in the mixture of said organic medium, said phosphorus oxyacid and said organic amine; and wherein the ratio of said phosphorus oxyacid to said organic amine is in the range from 0.5:1 to 100:1.
Claim 2
Dependent Claim
232 words
A polymerisable composition comprising (a) an organic medium which comprises a polymerisable olefinically unsaturated substance which bears one or more polymerisable olefinically unsaturated groups; (b) a phosphorous oxyacid having the formula: ##STR5## wherein R 1 is a hydrocarbyl group or a polyether or polyester chain; and R 2 is hydrogen or a hydrocarbyl group or a polyether or polyester chain; and (c) an organic amine having the formula: ##STR6## wherein R 3 is a hydrocarbyl group or a polyether or polyester chain, and R 4 and R 5 , which may be the same or different are hydrogen, hydrocarbyl or polyether or polyester chains, except that (i) at least one of the groups R 1 , R 2 , R 3 , R 4 and R 5 comprises a polymerisable olefinically unsaturated group (ii) at least one of the groups R 1 and R 2 and at least one of the groups R 3 , R 4 and R 5 is, or is derived from, a long chain alkyl group containing 8 to 22 carbon atoms or a polyether or polyester chain of molecular weight between 300 and 10,000; and (d) a particulate inorganic material which is dispersed in the mixture of said organic medium, said phosphorus oxyacid and said organic amine; and wherein the ratio of said phosphorus oxyacid to said organic amine is in the range from 0.5:1 to 100:1.
Claim 3
Dependent Claim
18 words
A polymerisable composition as claimed in claim 1 in which the particulate inorganic material is a siliceous material.
Claim 4
Dependent Claim
21 words
A polymerisable composition as claimed in claim 2 in which the siliceous material is a silicate based glass or a silica.
Claim 5
Dependent Claim
21 words
A polymerisable composition as claimed in claim 1 wherein the particulate inorganic material provides 20-70% by volume of the polymerisable composition.
Claim 6
Dependent Claim
21 words
A dental composition comprising a polymerisable composition as claimed in claim 1, free-radical initiating system, and optionally a particulate inorganic material.
Claim 7
Dependent Claim
17 words
A dental composition as claimed in claim 4 wherein the free-radical initiating system is a photo-initiator system.
References Cited (Backward Citations)
US3963512A
Cited
US3956421A
Cited
US4259117A
Cited
US4222780A
Cited
US4374937A
Cited
US4439380A
Cited
US4407984A
Cited
US4442239A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-01-06 | 1989-07-08 | 1990-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-01-06 | 1993-07-08 | 1994-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-01-06 | 1997-07-08 | 1998-01-07 | $7700.00 | Window Closed / Lapsed |