Polyurethanes and polyurethane-ureas based on aromatic uret dione diamine adducts

Claim 2

An aromatic uret dione diurea diamine corresponding to the formula ##STR11## in which X represents an aromatic radical having a molecular weight of from 76 to 499, Y represents an aromatic radical having a molecular weight of from 76 to 10,000 or a radical derived from a high molecular weight diamine corresponding to the formula ##STR12## in which Z represents a radical derived from a dihydroxy compound HO--Z--OH, provided that when Y represents a group derived from a diamine having a molecular weight ≧500 X does not represent a 2,4-diphenyl sulfide radical, m represents a number of from 1 to 10 and n represents a number of from 1 to 3.

Claim 3

The aromatic uret dione diurea diamine of claim 1 in which X represents a 2,4-tolylene and/or 4,4'-diphenyl methane and/or 2,4'-diphenyl methane radical.

Claim 4

The aromatic uret dione diurea diamine of claim 1 in which m represents a number of from 1 to 2.

Claim 5

The aromatic uret dione diurea diamine of claim 1 in which Y represents a 4,4'-diphenyl methane radical and/or 3,5-diisopropyl-3',5'-diethyl-4,4'-diphenyl methane radical and/or 3,5-diethyl-2,4-(2,6-) tolylene radical and/or 1,4-phenylene radical.

Claim 6

The aromatic uret dione diurea diamine of claim 1 in which Y represents a radical derived from a diamine having a molecular weight of from 1000 to 6000.

Claim 7

A process for the production of aromatic uret dione diurea diamines in finely particulate or suspended form which diamines correspond to the formula ##STR13## in which X represents an aromatic radical having a molecular weight of from 76 to 499, Y represents an aromatic radical having a molecular weight of from 76 to 10,000 or a radical corresponding to the formula ##STR14## in which Z represents a radical derived from a dihydroxy compound HO--Z--OH, provided that when Y represents a radical derived from a diamine H 2 N--Y--NH 2 having a molecular weight ≧500, X does not represent a 2,4'-diphenyl sulfide radical, m represents a number of from 1 to 10 and n represents a number of from 1 to 3 comprising mixing an aromatic diamine H 2 N--Y--NH 2 with a finely particulate diisocyanate corresponding to the formula ##STR15## in a molar ratio of diamine to diisocyanate of at least 1.8:1.

Claim 8

A process for the production of aromatic uret dione diurea diamines in finely particulate or suspended form which diamines correspond to the formula ##STR13## in which X represents an aromatic radical having a molecular weight of from 76 to 499, Y represents an aromatic radical having a molecular weight of from 76 to 10,000 or a radical corresponding to the formula ##STR14## in which Z represents a radical derived from a dihydroxy compound HO--Z--OH, provided that when Y represents a radical derived from a diamine H 2 N--Y--NH 2 having a molecular weight ≧500, X does not represent a 2,4'-diphenyl sulfide radical, m represents a number of from 1 to 10 and n represents a number of from 1 to 3 comprising mixing an aromatic diamine H 2 N--Y--NH 2 with a finely particulate diisocyanate corresponding to the formula ##STR15## in a molar ratio of diamine to diisocyanate of at least 1.8:1.

Claim 9

The process of claim 6 in which the aromatic diamine H 2 N--Y--NH 2 is used in the form of a solution in an isocyanate-inert solvent or in a relatively high molecular weight polyol.

Claim 10

The process of claim 6 in which the finely particulate uret dione diisocyanate is suspended in an isocyanate-inert solvent and/or relatively high molecular weight polyol.

Claim 11

A process for the production of urea-group-containing high molecular weight polyaddition products comprising reacting (a) the aromatic uret dione diurea diamine of claim 1 with (b) an NCO-prepolymer of polyol and excess polyisocyanate and/or a polyisocyanate at a temperature greater than 100° C. in quantities such that the equivalent ratio of NCO-groups to the sum of OH- and NH 2 -groups is from 0.9 to 1.4.

Claim 12

The process of claim 9 in which a polyhydroxyl compound having a molecular weight of from 400 to 10,000 is included in the reaction mixture.

Claim 13

The process of claim 9 in which a chain extender having a molecular weight of from 32 to 399 is included in the reaction mixture.

Claim 14

The process of claim 9 further comprising the step of crosslinking the reaction product of (a) and (b) in the presence of excess OH- and/or NH 2 -groups at a temperature above 140° C.

Claim 15

A self-crosslinking one component system at temperatures above 140° C. comprising the reaction product of a (i) long chain diamine H 2 N--Y--NH 2 having a molecular weight of at least 500 where Y represents a radical corresponding to the formula ##STR16## in which Z represents a radical derived from a dihydroxy compound HO--Z--OH with (ii) a uret dione diisocyanate.

Claim 16

A self-crosslinking one component system at temperatures above 140° C. comprising the reaction product of a (i) long chain diamine H 2 N--Y--NH 2 having a molecular weight of at least 500 where Y represents a radical corresponding to the formula ##STR16## in which Z represents a radical derived from a dihydroxy compound HO--Z--OH with (ii) a uret dione diisocyanate.