US4519432A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reinforced polyurethane tires
Assignee: Lim International SA
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Filing: 1984-02-08
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Granted: 1985-05-28
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Expires: 2004-02-08
Abstract
Abstract This invention relates to reinforced tire utilizing polyurea or polyurethane formulations having low hysteresis. The polymer having low hysteresis is formed by reacting a prepolymer of an aromatic isocyanate and a high molecular weight difunctional polyol with a chain extender mix comprising an aromatic diamine and difunctional polyol. In these compositions the aromatic diisocyanate and aromatic diamine are selected so that there is substantial symmetry between the molecules. The reinforcement used is preferably an aromatic polyamide.
Inventors
- 👤 Andreas R. Schmidt
- 👤 Herbert F. Strohmayer
- 👤 Walter Sibral
- 👤 Barton Milligan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 14:29
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/74; C08G18/76; C08G18/7614; B; B60; B60C; B60C1/00; B60C1/0025; C08G18/08; C08G18/10; C08G2380/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
270 words
In a reinforced urethane tire formed by injecting a polyurea/polyurethane forming composition comprising a prepolymer having an excess of isocyanate groups and an aromatic diamine chain extender, into a tire mold, encapsulating a reinforcing cord in said tire and then curing said composition, the improvement for producing polyurea/polyurethane composition having low hysteresis which comprises reacting: (a) a prepolymer formed by the reaction of (1) an aromatic polyisocyanate represented by the formula: ##STR5## where R 1 R 2 R 3 R 4 represents H, alkyl from 1-4 carbon atoms, CN, halogen, CO 2 R 5 , CONR 6 R 7 where R 5 represents alkyl of 1-6 carbon atoms and R 6 R 7 represents alkyl of 1-6 carbon atoms and H, and mixtures thereof and (2) a polyol of about 500-5000 molecular weight of which at least 90% of the polyol is difunctional in a quantity sufficient to provide from about 2 to 12 weight % isocyanate groups in said prepolymer; with (b) a chain extender mix comprising (1) an aromatic diamine represented by the formula: ##STR6## where R 1 R 2 R 3 R 4 represents H, alkyl from 1-4 carbon atoms, CN, halogen, CO 2 R 5 , CONR 6 R 7 where R 5 represents alkyl of 1-6 carbon atoms and R 6 R 7 represents alkyl of 1-6 carbon atoms and H, and mixtures thereof and (2) a polyol having a molecular weight of from 500-5,000 of which at least 90% of polyol is difunctional, said diamine being present in said chain extender mix to provide a proportion of from 0.5-5 equivalents amine per equivalent polyol.
Claim 2
Dependent Claim
270 words
In a reinforced urethane tire formed by injecting a polyurea/polyurethane forming composition comprising a prepolymer having an excess of isocyanate groups and an aromatic diamine chain extender, into a tire mold, encapsulating a reinforcing cord in said tire and then curing said composition, the improvement for producing polyurea/polyurethane composition having low hysteresis which comprises reacting: (a) a prepolymer formed by the reaction of (1) an aromatic polyisocyanate represented by the formula: ##STR5## where R 1 R 2 R 3 R 4 represents H, alkyl from 1-4 carbon atoms, CN, halogen, CO 2 R 5 , CONR 6 R 7 where R 5 represents alkyl of 1-6 carbon atoms and R 6 R 7 represents alkyl of 1-6 carbon atoms and H, and mixtures thereof and (2) a polyol of about 500-5000 molecular weight of which at least 90% of the polyol is difunctional in a quantity sufficient to provide from about 2 to 12 weight % isocyanate groups in said prepolymer; with (b) a chain extender mix comprising (1) an aromatic diamine represented by the formula: ##STR6## where R 1 R 2 R 3 R 4 represents H, alkyl from 1-4 carbon atoms, CN, halogen, CO 2 R 5 , CONR 6 R 7 where R 5 represents alkyl of 1-6 carbon atoms and R 6 R 7 represents alkyl of 1-6 carbon atoms and H, and mixtures thereof and (2) a polyol having a molecular weight of from 500-5,000 of which at least 90% of polyol is difunctional, said diamine being present in said chain extender mix to provide a proportion of from 0.5-5 equivalents amine per equivalent polyol.
Claim 3
Dependent Claim
26 words
The reinforced tire of claim 1 wherein said isocyanate in said prepolymer is toluene diisocyanate, and alkyl of halo-substituted derivative of toluene diisocyanate or m-phenylene diisocyanate.
Claim 4
Dependent Claim
33 words
The reinforced tire of claim 2 wherein at least 90% of the amine equivalent in the chain extender mix is toluene diamine, an alkyl or halo-substituted derivative of toluene diamine; or m-phenylene diamine.
Claim 5
Dependent Claim
27 words
The reinforced tire of claim 3 wherein said polyol in said prepolymer mix is a polyether, polyester, or polylactone polyol and has a molecular weight from 1000-3000.
Claim 6
Dependent Claim
20 words
The reinforced tire of claim 4 wherein said polyol in said chain extender mix is a polyether, or polyester polyol.
Claim 7
Dependent Claim
15 words
The reinforced tire of claim 4 wherein said polyol is polytetramethylene glycol is polycaprolactone diol.
Claim 8
Dependent Claim
13 words
The reinforced tire of claim 5 wherein said aromatic diamine is toluene diamine.
Claim 9
Dependent Claim
13 words
The reinforced tire of claim 5 wherein said aromatic diamine is diethyltoluene diamine.
Claim 10
Dependent Claim
13 words
The reinforced tire of claim 5 wherein said aromatic diamine is chlorotoluene diamine.
Claim 11
Dependent Claim
13 words
The reinforced tire of claim 5 wherein said aromatic diamine is m-phenylene diamine.
Claim 12
Dependent Claim
22 words
The reinforced tire of claim 5 wherein said aromatic diamine is ##STR7## where R is an alkyl group from 1-6 carbon atoms.
Claim 13
Dependent Claim
23 words
The reinforced tire of claim 3 wherein said isocyanate in said prepolymer is derived from m-phenylene diisocyanate and said diamine is m-phenylene diamine.
Claim 14
Dependent Claim
21 words
The reinforced tire of claim 3 wherein said isocyanate in said prepolymer is toluene diisocyanate and said diamine is toluene diamine.
Claim 15
Dependent Claim
19 words
The reinforced tire of claim 7 wherein said polyol used in the prepolymer and chain extender is the same.
Claim 16
Dependent Claim
39 words
The reinforced tire of claim 7 where the isocyanate content in the prepolymer is from 5 to 10 weight % and the proportion of aromatic amine in said chain extender mix provides from 1-3 equivalents amine per equivalent polyol.
Claim 17
Dependent Claim
14 words
The reinforced tire of claim 9 wherein said reinforcing cord is an aromatic polyamide.
References Cited (Backward Citations)
US2713884A
Cited
US3849976A
Cited
US3745151A
Cited
US3826298A
Cited
US3690363A
Cited
US3869429A
Cited
US3869430A
Cited
US3929180A
Cited
US3950590A
Cited
US3977172A
Cited
US4090547A
Cited
US4044811A
Cited
US4043725A
Cited
US4044540A
Cited
US4124345A
Cited
US4155394A
Cited
US4259129A
Cited
US4278779A
Cited
US4277295A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-05-27 | 1988-11-26 | 1989-05-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-05-27 | 1992-11-26 | 1993-05-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-05-27 | 1996-11-26 | 1997-05-28 | $7700.00 | Window Closed / Lapsed |