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US4460735A Expired / Lapsed US ⏱️ 0.0 years remaining

Blend of polycarbonate and wholly aromatic polyester

Assignee: Celanese Corp
•
Filing: 1980-07-03
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Granted: 1984-07-17
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Expires: 2000-07-03
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Abstract

Abstract A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 75 percent by weight, based upon the total weight of the blend, of a polycarbonate and approximately 25 to approximately 95 percent by weight, based upon the total weight of the blend, of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend.

Inventors

  • 👤 Michael F. Froix

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:36
CPC Classifications
C; C08; C08L; C08L67/00; C08L69/00

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 86 words
A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 40 percent by weight, based upon the total weight of components (a) and (b), of a polycarbonate, and (b) approximately 60 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from said blend.
Claim 2
Dependent Claim 86 words
A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 40 percent by weight, based upon the total weight of components (a) and (b), of a polycarbonate, and (b) approximately 60 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from said blend.
Claim 3
Dependent Claim 27 words
A polymer blend according to claim 1 which is capable of undergoing melt processing at a temperature within the range of approximately 260° C. to 350° C.
Claim 4
Dependent Claim 27 words
A polymer blend according to claim 1 which is capable of undergoing melt processing at a temperature within the range of approximately 280° C. to 300° C.
Claim 5
Dependent Claim 17 words
A polymer blend according to claim 1 wherein said polycarbonate has repeating units of the formula: ##STR6##
Claim 6
Dependent Claim 31 words
A polymer blend according to claim 1 wherein said wholly aromatic polyester apart from said blend is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.
Claim 7
Dependent Claim 41 words
A polymer blend according to claim 1 wherein said wholly aromatic polyester apart from said blend exhibits an inherent viscosity of at least approximately 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 8
Dependent Claim 112 words
A polymer blend according to claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR7## where R is methyl, chloro, bromo, or mixtures thereof, and is substituted for a hydrogen atom present upon the aromatic ring, and wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.
Claim 9
Dependent Claim 18 words
A polymer blend according to claim 7, wherein said R group of moiety IV is a methyl group.
Claim 10
Dependent Claim 59 words
A polymer blend according to claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature below approximately 325° C. apart from said blend and consists essentially of the recurring moieties I, II, and III wherein: ##STR8## wherein said polyester comprises approximately 30 to 70 mole percent of moiety I.
Claim 11
Dependent Claim 44 words
A molding compound comprising the polymer blend of claim 1 which incorporates approximately 1 to 50 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.
Claim 12
Dependent Claim 41 words
A molding compound according to claim 10 which incorporates approximately 10 to 30 percent by weight based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.
Claim 13
Dependent Claim 10 words
A molded article comprising the polymer blend of claim 1.
Claim 14
Dependent Claim 14 words
A fiber which has been melt spun from the polymer blend of claim 1.
Claim 15
Dependent Claim 14 words
A film which has been melt extruded from the polymer blend of claim 1.
Claim 16
Dependent Claim 24 words
A polymer blend according to claim 1 which is capable of being satisfactorily molded while employing a mold temperature less than approximately 100° C.
Claim 17
Dependent Claim 157 words
A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 40 percent by weight, based upon the total weight of components (a) and (b), of a polycarbonate having repeating units of the formula: ##STR9## and (b) approximately 60 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR10## wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.
Claim 18
Dependent Claim 157 words
A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties comprising: (a) approximately 5 to approximately 40 percent by weight, based upon the total weight of components (a) and (b), of a polycarbonate having repeating units of the formula: ##STR9## and (b) approximately 60 to approximately 95 percent by weight, based upon the total weight of components (a) and (b), of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase at a temperature no higher than approximately 320° C. apart from said blend and consists essentially of the recurring moieties I, II, III, and IV wherein: ##STR10## wherein said polyester comprises approximately 20 to 60 mole percent of moiety I, approximately 5 to 18 mole percent of moiety II, approximately 5 to 35 mole percent of moiety III, and approximately 20 to 40 mole percent of moiety IV.
Claim 19
Dependent Claim 75 words
A polymer blend according to claim 16 wherein said melt processable wholly aromatic polyester consists essentially of approximately 35 to 45 mole percent of moiety I, approximately 10 to 15 mole percent of moiety II, approximately 15 to 25 mole percent of moiety III, and approximately 25 to 35 mole percent of moiety IV, with the proviso that the total molar concentration of moieties II and III is substantially identical to that of moiety IV.
Claim 20
Dependent Claim 27 words
A polymer blend according to claim 16 which is capable of undergoing melt processing at a temperature within the range of approximately 280° C. to 300° C.
Claim 21
Dependent Claim 39 words
A polymer blend according to claim 16 wherein said wholly aromatic polyester apart from said blend exhibits an inherent viscosity of at least 2.0 dl./g. when dissolved in a concentration of 0.3 weight/volume percent in pentafluorophenol at 60° C.
Claim 22
Dependent Claim 39 words
A polymer blend according to claim 19 wherein said wholly aromatic polyester apart from said blend exhibits an inherent viscosity of approximately 2.0 to 8.0 when dissolved in a concentration of 0.3 weight/volume percent in pentafluorophenol at 60° C.
Claim 23
Dependent Claim 44 words
A molding compound comprising the polymer blend of claim 16 which incorporates approximately 1 to 50 percent by weight, based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agent, and mixtures thereof.
Claim 24
Dependent Claim 41 words
A molding compound according to claim 21 which incorporates approximately 10 to 30 percent by weight based upon the total weight of said molding compound, of a material selected from the group consisting of solid filler, reinforcing agnet, and mixtures thereof.
Claim 25
Dependent Claim 10 words
A molded article comprising the polymer blend of claim 16.
Claim 26
Dependent Claim 14 words
A fiber which has been melt spun from the polymer blend of claim 16.
Claim 27
Dependent Claim 14 words
A film which has been melt extruded from the polymer blend of claim 16.
Claim 28
Dependent Claim 10 words
A molded article comprising the polymer blend of claim 16.
Claim 29
Dependent Claim 30 words
A molded article according to claim 26 which exhibits a tensile strength of no less than approximately 25,000 p.s.i. and a flexural strength of no less than approximately 19,000 p.s.i.

References Cited (Backward Citations)

US3856884A Cited
US4184996A Cited
GB2008598A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-17 1988-01-16 1988-07-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-17 1992-01-16 1992-07-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-17 1996-01-16 1996-07-17 $7700.00 Window Closed / Lapsed

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