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US4394239A Expired / Lapsed US ⏱️ 0.0 years remaining

Electro-chemical sensor for the detection of reducing gases, in particular carbon monoxide, hydrazine and hydrogen in air

Assignee: Bayer AG
•
Filing: 1981-08-24
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Granted: 1983-07-19
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Expires: 2001-08-24
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Abstract

Abstract A sensor consists of a catalytically active measuring electrode communicating with a non-polarizable atmospheric oxygen electrode by way of an aqueous acid electrolyte. The electrolyte used is an aqueous gelatinous polymeric adhesive in which ionogenic substances are dissolved. Due to the adhesive properties of the electrolyte, a 3-phase boundary of air-catalyst-electrolyte is formed at the transition to the measuring electrode and substantially determines the measuring process.

Inventors

  • 👤 Dieter Kitzelmann
  • 👤 Jacques Deprez

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:15
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/404; G01N27/4045

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 116 words
In an electro-chemical sensor for the measurement of carbon monoxide, hydrogen or hydrazine in ambient air, comprising a catalyst containing measuring electrode exposed to ambient air and communicating through an aqueous acid electrolyte with a non-polarizable counter electrode, the improvement comprising: (a) a body of an aqueous hygroscopic polymer gel in which ionogenic substances are dissolved, the gel body having sticky surfaces, (b) the measuring electrode comprising a porous sheet-like matrix, coated with catalyst particles, (c) the matrix being firmly anchored at the surface of the polymer gel in a self-supporting manner and the catalyst particles being embedded with part of their surfaces in the gel and with the remaining surface portions protruding from the gel.
Claim 2
Dependent Claim 116 words
In an electro-chemical sensor for the measurement of carbon monoxide, hydrogen or hydrazine in ambient air, comprising a catalyst containing measuring electrode exposed to ambient air and communicating through an aqueous acid electrolyte with a non-polarizable counter electrode, the improvement comprising: (a) a body of an aqueous hygroscopic polymer gel in which ionogenic substances are dissolved, the gel body having sticky surfaces, (b) the measuring electrode comprising a porous sheet-like matrix, coated with catalyst particles, (c) the matrix being firmly anchored at the surface of the polymer gel in a self-supporting manner and the catalyst particles being embedded with part of their surfaces in the gel and with the remaining surface portions protruding from the gel.
Claim 3
Dependent Claim 25 words
The sensor according to claim 1, wherein the matrix consists of a meshed electrically conductive grid, which is applied to the gel electrolyte by pressure.
Claim 4
Dependent Claim 33 words
The sensor according to claim 1 or 2, for the measurement of carbon monoxide and hydrogen, wherein the matrix and the counter electrode consists of a graphite fleece and the catalyst is platinum.
Claim 5
Dependent Claim 37 words
The sensor according to claim 1 or 2, for the measurement of hydrazine, wherein the matrix consists of a carbon fleece coated with gold and the counter electrode consists of a carbon fleece coated with platinum black.

References Cited (Backward Citations)

DE2155935A1 Cited
DE2316365A1 Cited
US4049503A Cited
US4141800A Cited
US4227974A Cited
US4149948A Cited
US4227984A Cited
US4207162A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-18 1987-01-17 1987-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-18 1991-01-17 1991-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-18 1995-01-17 1995-07-19 $7700.00 Window Closed / Lapsed

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