US4394239A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Electro-chemical sensor for the detection of reducing gases, in particular carbon monoxide, hydrazine and hydrogen in air
Assignee: Bayer AG
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Filing: 1981-08-24
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Granted: 1983-07-19
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Expires: 2001-08-24
Abstract
Abstract A sensor consists of a catalytically active measuring electrode communicating with a non-polarizable atmospheric oxygen electrode by way of an aqueous acid electrolyte. The electrolyte used is an aqueous gelatinous polymeric adhesive in which ionogenic substances are dissolved. Due to the adhesive properties of the electrolyte, a 3-phase boundary of air-catalyst-electrolyte is formed at the transition to the measuring electrode and substantially determines the measuring process.
Inventors
- 👤 Dieter Kitzelmann
- 👤 Jacques Deprez
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:15
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/404; G01N27/4045
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
116 words
In an electro-chemical sensor for the measurement of carbon monoxide, hydrogen or hydrazine in ambient air, comprising a catalyst containing measuring electrode exposed to ambient air and communicating through an aqueous acid electrolyte with a non-polarizable counter electrode, the improvement comprising: (a) a body of an aqueous hygroscopic polymer gel in which ionogenic substances are dissolved, the gel body having sticky surfaces, (b) the measuring electrode comprising a porous sheet-like matrix, coated with catalyst particles, (c) the matrix being firmly anchored at the surface of the polymer gel in a self-supporting manner and the catalyst particles being embedded with part of their surfaces in the gel and with the remaining surface portions protruding from the gel.
Claim 2
Dependent Claim
116 words
In an electro-chemical sensor for the measurement of carbon monoxide, hydrogen or hydrazine in ambient air, comprising a catalyst containing measuring electrode exposed to ambient air and communicating through an aqueous acid electrolyte with a non-polarizable counter electrode, the improvement comprising: (a) a body of an aqueous hygroscopic polymer gel in which ionogenic substances are dissolved, the gel body having sticky surfaces, (b) the measuring electrode comprising a porous sheet-like matrix, coated with catalyst particles, (c) the matrix being firmly anchored at the surface of the polymer gel in a self-supporting manner and the catalyst particles being embedded with part of their surfaces in the gel and with the remaining surface portions protruding from the gel.
Claim 3
Dependent Claim
25 words
The sensor according to claim 1, wherein the matrix consists of a meshed electrically conductive grid, which is applied to the gel electrolyte by pressure.
Claim 4
Dependent Claim
33 words
The sensor according to claim 1 or 2, for the measurement of carbon monoxide and hydrogen, wherein the matrix and the counter electrode consists of a graphite fleece and the catalyst is platinum.
Claim 5
Dependent Claim
37 words
The sensor according to claim 1 or 2, for the measurement of hydrazine, wherein the matrix consists of a carbon fleece coated with gold and the counter electrode consists of a carbon fleece coated with platinum black.
References Cited (Backward Citations)
DE2155935A1
Cited
DE2316365A1
Cited
US4049503A
Cited
US4141800A
Cited
US4227974A
Cited
US4149948A
Cited
US4227984A
Cited
US4207162A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-07-18 | 1987-01-17 | 1987-07-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-07-18 | 1991-01-17 | 1991-07-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-07-18 | 1995-01-17 | 1995-07-19 | $7700.00 | Window Closed / Lapsed |