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US4376688A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for producing semiconductor films

Assignee: Xerox Corp
•
Filing: 1981-04-03
•
Granted: 1983-03-15
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Expires: 2001-04-03
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Abstract

Abstract A method for producing semiconducting films on a substrate wherein a plasma of a reactive gas is generated and an ion beam from the plasma is directed and accelerated toward a target of material of which the film is to be formed. The target which is maintained in a vacuum chamber at reduced pressure, is sputtered with the reactive ion beam and the material sputtered off the target is collected as a film on a substrate which is physically isolated from the plasma generating process and the sputtering process. Preferably the reactive gas is present in a mixture with an inert gas heavier than the reactive gas.

Inventors

  • 👤 Gerald P. Ceasar
  • 👤 Scott F. Grimshaw

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 01:31
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/22; C23C14/34; C23C14/46; H; H10; H10P; H10P14/00; H10P14/20; H10P14/22; H10P14/29; H10P14/2901; H10P14/2922; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/36; H10P14/3602

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 88 words
A method for producing semiconducting films on a substrate comprising generating a plasma of reactive gas, extracting, accelerating and directing an ion beam from said plasma toward a target of material of which the film is to be formed, said target being maintained in a vacuum chamber at reduced pressure, sputtering said target with said reactive ion beam to sputter the target material, collecting said sputtered target material as a film on said substrate, said substrate being physically isolated from the plasma generating process and the sputtering process.
Claim 2
Independent Claim 88 words
A method for producing semiconducting films on a substrate comprising generating a plasma of reactive gas, extracting, accelerating and directing an ion beam from said plasma toward a target of material of which the film is to be formed, said target being maintained in a vacuum chamber at reduced pressure, sputtering said target with said reactive ion beam to sputter the target material, collecting said sputtered target material as a film on said substrate, said substrate being physically isolated from the plasma generating process and the sputtering process.
Claim 3
Dependent Claim 27 words
The method of claim 1 wherein said reactive gas is present in a mixture of said reactive gas with an inert gas heavier than said reactive gas.
Claim 4
Dependent Claim 11 words
The method of claim 1 wherein said reactive gas is hydrogen.
Claim 5
Dependent Claim 26 words
The method of claim 1 wherein said semiconducting film and said target material comprise the same element or elements from Group IVa of the Periodic Table.
Claim 6
Dependent Claim 21 words
The method of claim 4 wherein said semiconducting film is amorphous silicon and said target material comprises substantially pure crystalline silicon.
Claim 7
Dependent Claim 28 words
The method of claim 5 wherein said reactive gas is hydrogen and said amorphous film of silicon has silicon atoms coordinated with hydrogen substantially completely as the monohydride.
Claim 8
Dependent Claim 11 words
The method of claim 1 wherein said ion beam is collimated.
Claim 9
Dependent Claim 15 words
The method of claim 1 wherein said target is an amorphous polycrystalline or crystalline material.
Claim 10
Dependent Claim 12 words
The method of claim 1 wherein the substrate is at ambient temperature.
Claim 11
Dependent Claim 21 words
The method of claim 1 wherein the substrate is maintained at temperature of from about 25° C. to about 300° C.
Claim 12
Dependent Claim 11 words
The method of claim 2 wherein said inert gas is argon.
Claim 13
Dependent Claim 35 words
The method of claim 3 wherein said reactive hydrogen is present in said plasma in an amount of up to about 90 percent by volume the remainder being an inert gas heavier than the hydrogen.
Claim 14
Dependent Claim 10 words
The method of claim 1 wherein said substrate is flexible.
Claim 15
Dependent Claim 31 words
The method of claim 2 wherein said reactive gas is present in an amount sufficient to passivate some of the dangling bonds formed in the sputtered material collected on said substrate.
Claim 16
Dependent Claim 27 words
The method of claim 4 wherein said amorphous silicon is deposited at a rate of from about 0.6 microns per hour to about 3.0 microns per hour.
Claim 17
Dependent Claim 25 words
The method of claim 4 wherein the pressure in the vacuum chamber during sputtering is from about 5×10 -9 Torr to about 10 -3 Torr.

References Cited (Backward Citations)

US3494852A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-14 1986-09-13 1987-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-14 1990-09-13 1991-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-14 1994-09-13 1995-03-15 $7700.00 Window Closed / Lapsed

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