US4367732A
Expired / Lapsed
US
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Skin barrier
Assignee: Coloplast AS
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Filing: 1981-11-30
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Granted: 1983-01-11
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Expires: 2001-11-30
Abstract
Abstract A skin barrier consisting of an elastic film (16), secured to the film a layer (18) of at least weakly elastic adhesive material, these two components together having low resistance to quick deformation and rapid recovery to substantially the original shape after deformation, the plastic properties of the adhesive thereby being compensated by the elasticity of the film. Optionally there may be a releasable protective cover (20,22) on the other side of the adhesive layer. The adhesive material consists of a hydrocolloid, preferably sodium carboxymethylcellulose, dispersed in a continuous phase consisting of a mixture of (a) a physically cross-linked elastomer which is a styrene-olefin-styrene block copolymer, (b) a hydrocarbon resin tackifier which is a polymer or copolymer of cyclopentadiene, dicyclopentadiene or α- or β-pinene, (c) a plasticizer for the elastomer which is compatible at least with the styrene blocks thereof and decreases the upper glass transition temperature thereof, preferably dioctyl adipate, (d) an antioxidant, and (e) optionally an oily extender compatible with the olefin blocks of the elastomer.
Inventors
- 👤 Finn Poulsen
- 👤 Peter Samuelsen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 04:23
CPC Classifications
A; A61; A61L; A61L24/00; A61L24/0047; A61L24/0073; A61L24/0094; A61L28/00; A61L28/0007; A61L28/0011; C; C09; C09J; C09J153/00; C09J153/02; A61L2400/00; A61L2400/14; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/28; C08L2666/54
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
189 words
A skin barrier, essentially consisting of the following elements in combination: (A) a non-adhesive, substantially water-impervious, elastic film, secured to one of the faces of an adhesive layer of (B) an adhesive material which is a gel-like, at least weakly elastic mixture consisting of (I) a continuous phase consisting of (a) at least one physically cross-linked elastomer selected from the group consisting of styrene-olefin-styrene block copolymers, (b) at least one hydrocarbon tackifier resin selected from the group consisting of polymers and copolymers of cyclopentadiene, dicyclopentadiene, α-pinene and β-pinene, (c) a polar plasticizer for the elastomer, being compatible at least with its styrene blocks and decreasing the upper glass transition temperature of the styrene blocks of the elastomer, (d) an antioxidant, and (e) 0-25%, based on the weight of the adhesive material, of an oily extender, (II) dispersed in the continuous phase (I) a discontinuous phase consisting of at least one hydrocolloid which is swellable in water, the aggregate of said water-impervious elastic film (A) and the adhesive material (B) adhering thereto having a low resistance to quick deformation and after deformation a rapid recovery to substantially its original shape.
Claim 2
Dependent Claim
189 words
A skin barrier, essentially consisting of the following elements in combination: (A) a non-adhesive, substantially water-impervious, elastic film, secured to one of the faces of an adhesive layer of (B) an adhesive material which is a gel-like, at least weakly elastic mixture consisting of (I) a continuous phase consisting of (a) at least one physically cross-linked elastomer selected from the group consisting of styrene-olefin-styrene block copolymers, (b) at least one hydrocarbon tackifier resin selected from the group consisting of polymers and copolymers of cyclopentadiene, dicyclopentadiene, α-pinene and β-pinene, (c) a polar plasticizer for the elastomer, being compatible at least with its styrene blocks and decreasing the upper glass transition temperature of the styrene blocks of the elastomer, (d) an antioxidant, and (e) 0-25%, based on the weight of the adhesive material, of an oily extender, (II) dispersed in the continuous phase (I) a discontinuous phase consisting of at least one hydrocolloid which is swellable in water, the aggregate of said water-impervious elastic film (A) and the adhesive material (B) adhering thereto having a low resistance to quick deformation and after deformation a rapid recovery to substantially its original shape.
Claim 3
Dependent Claim
17 words
The skin barrier claimed in claim 1, wherein the water-impervious elastic film (A) is a polyurethane film.
Claim 4
Dependent Claim
16 words
The skin barrier claimed in claim 1, wherein the elastomer (a) is a styrene-isoprene-styrene block copolymer.
Claim 5
Dependent Claim
53 words
The skin barrier claimed in claim 1, wherein the plasticizer (c) compatible both with the styrene and olefin domains of the elastomer (a) and is selected from the group consisting of esters of polyethylene glycol and polypropylene glycol with aliphatic carboxylic acids and esters of di- or polybasic carboxylic acids with aliphatic alcohols.
Claim 6
Dependent Claim
14 words
A skin barrier as claimed in claim 4, wherein the plasticizer is dioctyl adipate.
Claim 7
Dependent Claim
21 words
A skin barrier as claimed in claim 1, wherein the hydrocolloid (II) dispersed in the contiguous phase (I) is sodium carboxymethylcellulose.
Claim 8
Dependent Claim
72 words
The skin barrier claimed in claim 1, wherein the gel-like, at least weakly elastic mixture constituting the elastic layer (B) has the following composition, the percentages all being based on the weight of the material: (I) 45-90% continuous phase consisting of (a) 10-40% physically cross-linked elastomer, (b) 15-45% hydrocarbon tackifier resin, (c) 2-12% polar plasticizer for the elastomer, (d) 0.5-2.5% antioxidant, (e) 0-25% oily extender, and (II) 10-55% hydrocolloid as discontinuous phase.
Claim 9
Dependent Claim
80 words
The skin barrier claimed in claim 7, wherein the gel-like, at least weakly elastic mixture has the following composition, based on the total weight of the material: (I) about 70% continuous phase consisting of (a) about 25% styrene-isoprene-styrene block copolymer containing about 28% (based on the copolymer weight) styrene units as elastomer, (b) about 35% tackifier resin, (c) about 9% dioctyl adipate as plasticizer for the elastomer, (d) about 1% antioxidant, and (II) about 30% sodium carboxymethylcellulose as dispersed hydrocolloid.
Claim 10
Dependent Claim
26 words
The skin barrier claimed in claim 1, wherein the layer of adhesive has a thickness of 0.25-3 mm and the elastic film a thickness of 10-50μ.
Claim 11
Dependent Claim
208 words
A skin barrier, essentially consisting of the following elements in combination: (A) a non-adhesive, substantially water-impervious, elastic film, secured to one of the faces of an adhesive layer of (B) an adhesive material which is a gel-like, at least weakly elastic mixture consisting of (I) a continuous phase consisting of (a) at least one physically cross-linked elastomer selected from the group consisting of styrene-olefin-styrene block copolymers, (b) at least one hydrocarbon tackifier resin selected from the group consisting of polymers and copolymers of cyclopentadiene, dicyclopentadiene, α-pinene and β-pinene, (c) a polar plasticizer for the elastomer, being copatible at least with its styrene blocks and decreasing the upper glass transition temperature of the styrene blocks of the elastomer, (d) an antioxidant, and (e) 0-25%, based on the weight of the adhesive material, of an oily extender, (II) dispersed in the continuous phase a discontinuous phase consisting of at least one hydrocolloid which is swellable in water, (C) a detectable protective cover secured to the other face of the adhesive layer, the aggregate of said water-impervious elastic film (A) and the adhesive material (B) adhering thereto, but without the protective layer (C), having a low resistance to quick deformation and after deformation a rapid recovery to substantially its original shape.
Claim 12
Dependent Claim
208 words
A skin barrier, essentially consisting of the following elements in combination: (A) a non-adhesive, substantially water-impervious, elastic film, secured to one of the faces of an adhesive layer of (B) an adhesive material which is a gel-like, at least weakly elastic mixture consisting of (I) a continuous phase consisting of (a) at least one physically cross-linked elastomer selected from the group consisting of styrene-olefin-styrene block copolymers, (b) at least one hydrocarbon tackifier resin selected from the group consisting of polymers and copolymers of cyclopentadiene, dicyclopentadiene, α-pinene and β-pinene, (c) a polar plasticizer for the elastomer, being copatible at least with its styrene blocks and decreasing the upper glass transition temperature of the styrene blocks of the elastomer, (d) an antioxidant, and (e) 0-25%, based on the weight of the adhesive material, of an oily extender, (II) dispersed in the continuous phase a discontinuous phase consisting of at least one hydrocolloid which is swellable in water, (C) a detectable protective cover secured to the other face of the adhesive layer, the aggregate of said water-impervious elastic film (A) and the adhesive material (B) adhering thereto, but without the protective layer (C), having a low resistance to quick deformation and after deformation a rapid recovery to substantially its original shape.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-01-10 | 1986-07-12 | 1987-01-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-01-10 | 1990-07-12 | 1991-01-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-01-10 | 1994-07-12 | 1995-01-11 | $7700.00 | Window Closed / Lapsed |