US4335026A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Pressure-sensitive adhesive compositions having high shear and low peel resistance
Assignee: Johnson and Johnson Consumer Inc
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Filing: 1981-03-27
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Granted: 1982-06-15
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Expires: 2001-03-27
Abstract
Abstract Pressure-sensitive adhesive compositions having decreased resistance to peel removal while maintaining high shear resistance, i.e., holding-power adhesion, in air and in water comprising an elastomeric blend of a selected rubber and a selected olefin terpolymer having a Modulus, M60, at 60% elongation of from about 1 to about 1.5 and a polydisparity of no more than about 10, a liquid plasticizer, a reinforcing filler and a solid tackifier.
Inventors
- 👤 Ivan J. Balinth
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 09:32
CPC Classifications
C; C09; C09J; C09J121/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/06
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
235 words
A pressure-sensitive adhesive composition comprising (1) from about 25% to about 42% by weight of the total composition of an elastomeric blend consisting of a rubber and an olefin terpolymer of ethylene, propylene and 1,4-hexadiene, wherein the weight ratio of ethylene monomer to propylene monomer is approximately 3:1 and said hexadiene is present in an amount of from about 1% to about 8% by weight, having a modulus, M 60 , at 60% elongation of from about 1 to about 1.5 megapascals and a polydisparity of up to about 10, the weight ratio of said natural rubber to said terpolymer in said blend being from about 7.5:1 to about 2:1; (2) from about 5% to about 15% by weight of the total composition of a liquid plasticizer component selected from the group consisting of isomeric liquid polybutenes, mineral oils, low molecular weight polyterpenes, low viscosity rosins and mixtures thereof, with the proviso that when mineral oil is utilized, it comprises no more than 50% of the liquid plasticizer component; (3) from about 12% to about 20% by weight of the total composition of a reinforcing filler; and (4) from about 30% to 50% by weight of the total composition of a solid tackifier component, selected from the group consisting of normally solid polyterpenes, solid rosins and mixtures thereof, said pressure-sensitive adhesive composition having a Williams plasticity of from about 2 mm to about 3 mm.
Claim 2
Dependent Claim
235 words
A pressure-sensitive adhesive composition comprising (1) from about 25% to about 42% by weight of the total composition of an elastomeric blend consisting of a rubber and an olefin terpolymer of ethylene, propylene and 1,4-hexadiene, wherein the weight ratio of ethylene monomer to propylene monomer is approximately 3:1 and said hexadiene is present in an amount of from about 1% to about 8% by weight, having a modulus, M 60 , at 60% elongation of from about 1 to about 1.5 megapascals and a polydisparity of up to about 10, the weight ratio of said natural rubber to said terpolymer in said blend being from about 7.5:1 to about 2:1; (2) from about 5% to about 15% by weight of the total composition of a liquid plasticizer component selected from the group consisting of isomeric liquid polybutenes, mineral oils, low molecular weight polyterpenes, low viscosity rosins and mixtures thereof, with the proviso that when mineral oil is utilized, it comprises no more than 50% of the liquid plasticizer component; (3) from about 12% to about 20% by weight of the total composition of a reinforcing filler; and (4) from about 30% to 50% by weight of the total composition of a solid tackifier component, selected from the group consisting of normally solid polyterpenes, solid rosins and mixtures thereof, said pressure-sensitive adhesive composition having a Williams plasticity of from about 2 mm to about 3 mm.
Claim 3
Dependent Claim
20 words
The composition of claim 1 wherein the amount of said hexadiene is from about 2% to about 5% by weight.
Claim 4
Dependent Claim
16 words
The composition of claim 1 wherein the amount of said hexadiene is about 3.5% by weight.
Claim 5
Dependent Claim
19 words
The composition of claim 1 wherein said olefin terpolymer has a polydisparity of from about 4 to about 8.
Claim 6
Dependent Claim
15 words
The composition of claim 3 wherein said olefin terpolymer has a polydisparity of about 6.
Claim 7
Dependent Claim
22 words
The composition of claim 5 wherein said olefin terpolymer has a Modulus, M 60 , at 60% elongation of about 1.2 megapascals.
Claim 8
Dependent Claim
19 words
The composition of claim 1 which comprises from about 32% to about 38% by weight of said elastomeric blend.
Claim 9
Dependent Claim
37 words
The composition of claim 1 which further comprises up to 10% by weight, based on the total weight of the composition, of a material selected from the group consisting of fillers, antioxidants, stabilizers, plasticizers and color pigments.
Claim 10
Dependent Claim
26 words
The composition of claim 8 which contains from about 0.2% to about 3% by weight, based on the total weight of the composition, of a stabilizer.
Claim 11
Dependent Claim
53 words
The composition of claim 7 which comprises from about 6% to about 10% by weight of said liquid plasticizer component, from about 37% to about 43% by weight of said solid tackifier component and from about 1% to about 2% by weight, based on the total weight of the composition, of a stabilizer.
Claim 12
Dependent Claim
12 words
The composition of claim 1 wherein said rubber is a natural rubber.
Claim 13
Dependent Claim
12 words
The composition of claim 10 wherein said rubber is a natural rubber.
Claim 14
Dependent Claim
10 words
The composition of claim 10 wherein said rubber is cis-1,4-polyisoprene.
Claim 15
Dependent Claim
24 words
A surgical pressure-sensitive adhesive product comprising a flexible backing having coated on at least one side thereof a pressure-sensitive adhesive composition of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-06-14 | 1985-12-14 | 1986-06-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-06-14 | 1989-12-14 | 1990-06-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-06-14 | 1993-12-14 | 1994-06-15 | $7700.00 | Window Closed / Lapsed |