US4322518A
Expired / Lapsed
US
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Curable silicone compositions comprising liquid resin and uses thereof
Assignee: Dow Silicones Corp
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Filing: 1980-12-02
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Granted: 1982-03-30
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Expires: 2000-12-02
Abstract
Abstract Curable silicone compositions are disclosed which comprise a liquid copolymeric organopolysiloxane comprising SiO 2 and silicon-bonded hydroxyl radicals and/or silicon-bonded hydrogen radicals in varying amounts and a polydiorganosiloxane containing silicon-bonded vinyl radicals and/or silicon bonded hydroxyl radicals. The curable silicone compositions are useful as coatings for substrates.
Inventors
- 👤 John D. Blizzard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 09:56
CPC Classifications
C; C08; C08G; C08G77/00; C08G77/42; C08G77/44; C08G77/04; C08G77/12; C08G77/14; C08G77/16; C08L; C08L83/00; C08L83/04; C08G77/20; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31609; Y10T428/31612; Y10T428/31652; Y10T428/31663; Y10T428/31725; Y10T428/31739
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
207 words
A composition comprising (I) a liquid copolymeric organopolysiloxane, prepared by a method comprising (A) forming a homogeneous mixture having an acid number greater than zero and comprising (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R 3 SiO 1/2 siloxane units and SiO 4/2 siloxane units wherein the ratio of the number of said R 3 SiO 1/2 siloxane units to the number of said SiO 4/2 siloxane units has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen radical per molecule of said organohydrogenpolysiloxane, and (B) heating said homogeneous mixture to remove substantially all of said organic solvent therefrom and (II) a polydiorganosiloxane having the formula ZR'".sub.2 SiO(R'".sub.2 SiO).sub.c SiR'".sub.2 Z wherein Z denotes hydroxyl or R'" and each R'" denotes independently, a monovalent hydrocarbon radical, there being an average of at least two vinyl radicals or silicon-bonded hydroxyl radicals per molecule and c has a value sufficient to provide a viscosity of from 0.1 to 10,000 Pa·s at 25° C. for the polydiorganosiloxane.
Claim 2
Dependent Claim
207 words
A composition comprising (I) a liquid copolymeric organopolysiloxane, prepared by a method comprising (A) forming a homogeneous mixture having an acid number greater than zero and comprising (a) an organic solvent solution of a resinous copolymeric siloxane containing silicon-bonded hydroxyl radicals and consisting essentially of R 3 SiO 1/2 siloxane units and SiO 4/2 siloxane units wherein the ratio of the number of said R 3 SiO 1/2 siloxane units to the number of said SiO 4/2 siloxane units has a value of from 0.6/1 to 0.9/1 and each R denotes, independently, a monovalent hydrocarbon radical and (b) a liquid organohydrogenpolysiloxane wherein each organic radical is, independently, a monovalent hydrocarbon radical, there being an average of at least one silicon-bonded hydrogen radical per molecule of said organohydrogenpolysiloxane, and (B) heating said homogeneous mixture to remove substantially all of said organic solvent therefrom and (II) a polydiorganosiloxane having the formula ZR'".sub.2 SiO(R'".sub.2 SiO).sub.c SiR'".sub.2 Z wherein Z denotes hydroxyl or R'" and each R'" denotes independently, a monovalent hydrocarbon radical, there being an average of at least two vinyl radicals or silicon-bonded hydroxyl radicals per molecule and c has a value sufficient to provide a viscosity of from 0.1 to 10,000 Pa·s at 25° C. for the polydiorganosiloxane.
Claim 3
Dependent Claim
31 words
A composition according to claim 1 wherein the liquid copolymeric organopolysiloxane is prepared from a homogeneous mixture having an acid number of from 0.1 to 1, extrapolated to the solvent-free state.
Claim 4
Dependent Claim
39 words
A composition according to claim 2 wherein the ratio of the total number of silicon-bonded hydrogen atoms in component (b) to the total number of silicon-bonded hydroxyl radicals in component (a) has a value of at least about 2.
Claim 5
Dependent Claim
56 words
A composition according to claim 3 wherein the liquid copolymeric organopolysiloxane is prepared from a resinous copolymeric siloxane consisting of (CH 3 ) 3 SiO 1/2 siloxane units and SiO 4/2 siloxane units and having a silicon-bonded hydroxyl content of from 1 to 5 percent by weight and an acid number of from 0.3 to 1.4.
Claim 6
Dependent Claim
65 words
A composition according to claim 4 wherein the liquid copolymeric organopolysiloxane is prepared from an organohydrogenpolysiloxane having the formula (R")(CH 3 ) 2 SiO{(CH 3 ) 2 SiO} a {(CH 3 )(H)SiO} b Si(CH 3 ) 2 (R") wherein each R" denotes, independently, a methyl radical or a hydrogen radical and a and b denote numbers, each having an average value of zero or more.
Claim 7
Dependent Claim
44 words
A composition according to claim 5 wherein the organohydrogenpolysiloxane that is used to prepare the liquid copolymeric organopolysiloxane has the formula (CH 3 ) 3 SiO{(CH 3 )(H)SiO} b Si(CH 3 ) 3 wherein b has an average value of from 30 to 70.
Claim 8
Dependent Claim
34 words
A composition according to claim 6 wherein the liquid copolymeric organopolysiloxane is prepared from 40 to 60 parts by weight of resinous copolymeric siloxane and from 40 to 60 parts by weight of organohydrogenpolysiloxane.
Claim 9
Dependent Claim
65 words
A composition according to claim 7 wherein the polydiorganosiloxane has the formula (CH 2 ═CH)(CH 3 ) 2 Si{(CH 3 ) 2 SiO} c (1-d) {(CH 3 )(CH 2 ═CH)SiO} cd Si(CH 3 ) 2 (CH═CH 2 ) wherein d has a value sufficient to limit the total number of vinyl radicals to no more than 5 percent of all organic radicals in the polydiorganosiloxane.
Claim 10
Dependent Claim
17 words
A composition according to claim 7 wherein the polydiorganosiloxane has the formula HO(CH.sub.3).sub.2 SiO(CH.sub.3).sub.2 SiO.sub.c Si(CH.sub.3).sub.2 OH.
Claim 11
Dependent Claim
21 words
A composition according to claims 1, 2, 3, 4, 5, 6, 7, 8 or 9 further comprising an organohydrogenpolysiloxane curing agent.
Claim 12
Dependent Claim
18 words
A composition obtained by mixing a curing amount of a curing catalyst with the composition of claim 10.
Claim 13
Dependent Claim
27 words
A composition obtained by mixing a curing amount of a curing catalyst with the composition of claim 1, 2, 3, 4, 5, 6, 7, 8 or 9.
Claim 14
Dependent Claim
9 words
A substrate bearing the cured composition of claim 11.
Claim 15
Dependent Claim
9 words
A substrate bearing the cured composition of claim 12.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-03-29 | 1985-09-28 | 1986-03-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-03-29 | 1989-09-28 | 1990-03-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-03-29 | 1993-09-28 | 1994-03-30 | $7700.00 | Window Closed / Lapsed |