US4312972A
Expired / Lapsed
US
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Interpolymers of polyurethanes and addition polymerizable monomers
Assignee: Uniroyal Ltd Canada
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Filing: 1981-03-26
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Granted: 1982-01-26
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Expires: 2001-03-26
Abstract
Abstract Interpolymerizate of polyurethane-forming ingredients (polyol, polyisocyanate) and free radical addition polymerizable monomers, at least one of which contains an hydroxyl group (e.g., styrene plus 2-hydroxyethyl methacrylate). The interpolymer is prepared in the presence of a catalyst for polyurethane formation and a free radical addition polymerization catalyst. Product is homogeneous and insoluble. System is useful in reaction injection molding processes.
Inventors
- 👤 Som N. Khanna
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 15:15
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/63; C08G18/637; C08F; C08F290/00; C08F290/02; C08F290/06; C08F290/067; C08F290/08; C08F290/14; C08F290/147; C08G18/67; C08G18/671; C08G18/672; C08G2120/00; C08G2270/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
191 words
A homogeneous insoluble crosslinked interpolymer (A) condensation-polymerizable material and (B) free-radical-addition polymerizable material, the said (A) being polyurethane-forming ingredients comprising: (a) a long-chain polyether polyol having an hydroxyl number of from 25 to 115; (b) an organic polyisocyanate having free isocyanate groups reactive with (a) to form a polyurethane; and (c) a chain-extender or crosslinking agent for the polyurethane; and the said (B) being free-radical addition polymerizable monomeric material which is a mixture of: (d) a monoethylenically unsaturated monomer of the formula R 1 HC═CHR 2 wherein R 1 is hydrogen or a C 1 to C 4 alkyl radical, and R 2 is phenyl, nitrile or an ester radical ##STR3## where R 3 is C 1 to C 4 alkyl; and (e) a monoethylenically unsaturated monomer having a single hydroxyl group selected from hydroxyalkyl acrylates and hydroxyalkyl methacrylates having from 1 to 4 carbon atoms in the alkyl group, the proportions of said ingredients being, by weight, 100parts of (a) 1 to 30 parts of (c) 10 to 200 parts of (d) 1 to 30 parts of (e), and sufficient (b) to provide an NCO index of 1.0 to 1.1.
Claim 2
Dependent Claim
191 words
A homogeneous insoluble crosslinked interpolymer (A) condensation-polymerizable material and (B) free-radical-addition polymerizable material, the said (A) being polyurethane-forming ingredients comprising: (a) a long-chain polyether polyol having an hydroxyl number of from 25 to 115; (b) an organic polyisocyanate having free isocyanate groups reactive with (a) to form a polyurethane; and (c) a chain-extender or crosslinking agent for the polyurethane; and the said (B) being free-radical addition polymerizable monomeric material which is a mixture of: (d) a monoethylenically unsaturated monomer of the formula R 1 HC═CHR 2 wherein R 1 is hydrogen or a C 1 to C 4 alkyl radical, and R 2 is phenyl, nitrile or an ester radical ##STR3## where R 3 is C 1 to C 4 alkyl; and (e) a monoethylenically unsaturated monomer having a single hydroxyl group selected from hydroxyalkyl acrylates and hydroxyalkyl methacrylates having from 1 to 4 carbon atoms in the alkyl group, the proportions of said ingredients being, by weight, 100parts of (a) 1 to 30 parts of (c) 10 to 200 parts of (d) 1 to 30 parts of (e), and sufficient (b) to provide an NCO index of 1.0 to 1.1.
Claim 3
Dependent Claim
36 words
An interpolymer as in claim 1 in which (b) is a quasi-prepolymer having a molecular weight of 300 to 600, a free NCO content of 15-40% by weight, and an equivalent weight of 140 to 300.
Claim 4
Dependent Claim
48 words
An interpolymer as in claim 2 in which (a) is a polyalkyleneether triol having an hydroxyl number of from 25 to 115, (d) is styrene and (e) is hydroxyethyl methacrylate, the amounts of the ingredients being as follows: 100 parts of (a) 1 to 30 parts of (c)
Claim 5
Dependent Claim
24 words
50 to 150 parts of (d) 10 to 30 parts of (e), and sufficient (b) to provide an NCO index of 1.0 to 1.05.
Claim 6
Dependent Claim
24 words
50 to 150 parts of (d) 10 to 30 parts of (e), and sufficient (b) to provide an NCO index of 1.0 to 1.05.
Claim 7
Dependent Claim
14 words
An interpolymer as in claim 3 in which (b) is a toluene diisocyanate-based quasi-prepolymer.
Claim 8
Dependent Claim
44 words
A method of making an interpolymer as in claim 1 comprising mixing the said ingredients in the presence of (C) a catalyst for the reaction of (a), (b), (c) and (e) to form polyurethane, and (D) a free-radical polymerization catalyst for (d) and (e).
Claim 9
Dependent Claim
49 words
A method as in claim 5 in which the said interpolymer is formed in a desired shape by reaction injection molding, by bringing separate active hydrogen containing and NCO containing streams of ingredients together and immediately injecting the mixed stream into an injection mold cavity where interpolymerization takes place.
Claim 10
Dependent Claim
36 words
A method as in claim 6 in which (b) is a quasi-prepolymer having a molecular weight of 300 to 600, a free NCO content of 15-40% by weight, and an equivalent weight of 140 to 300.
Claim 11
Dependent Claim
71 words
A method as in claim 7 in which (a) is a polyalkyleneether triol having an hydroxyl number of from 25 to 115, (d) is styrene and (e) is hydroxyethyl methacrylate, the amounts of the ingredients being as follows: 100 parts of (a) 10 to 30 parts of (c) 50 to 150 parts (d) 10 to 30 parts of (e), and sufficient (b) to provide an NCO index of 1.0 to 1.05.
Claim 12
Dependent Claim
14 words
A method as in claim 8 in which (b) is a toluene diisocyanate-based quasi-prepolymer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-25 | 1985-07-27 | 1986-01-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-25 | 1989-07-27 | 1990-01-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-25 | 1993-07-27 | 1994-01-26 | $7700.00 | Window Closed / Lapsed |