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US4308151A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent-compatible fabric softening and antistatic compositions

Assignee: Procter and Gamble Co
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Filing: 1981-03-18
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Granted: 1981-12-29
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Expires: 2001-03-18
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Abstract

Abstract Detergent-compatible antistatic compositions are described containing a combination of cationic antistatic agents and hydrogenated triglycerides as discrete particles. Preferred compositions also include certain smectite clay materials to permit the simultaneous attainment of fabric softening, static-reduction and cleansing effects of fabrics washed therein.

Inventors

  • 👤 Cushman M. Cambre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:57
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/322; D06M13/46; D06M13/463; C; C11; C11D; C11D1/00; C11D1/38; C11D1/62; C11D1/66; C11D1/667; C11D1/835; C11D3/00; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253; C11D3/126; C11D1/02; C11D1/12; C11D1/14; C11D1/22

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 297 words
A particulate detergent additive product adapted to prevent static buildup on textiles when applied thereto from a detergent wash liquor, said particulate product being an intimate mixture of: (a) from about 5% to about 95% by weight of the particles of quaternary ammonium compounds of formula [R 1 R 2 R 3 R 4 N] + Y - , wherein at least one of R 1 R 2 R 3 and R 4 is an organic radical containing a group selected from a C 16 -C 22 aliphatic radical, or an alkyl phenyl or alkyl benzyl radical having 10 to 16 carbon atoms in the alkyl chain, the remaining group or groups being selected from C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl, and cyclic structures in which the nitrogen atom forms part of the ring, Y consituting an anionic radical selected from the group consisting of hydroxide, halide, acetate, sulphate, methylsulfate ions and phosphate ions, and (b) from about 5% to about 95% by weight of the particles of a dispersion inhibitor, being a solid organic material having a maximum solubility in water of 50 ppm max at 25° C. and a softening point in the range of from about 100° F. to about 200° F., and comprising at least about 1% by weight of solid hydrogenated triglycerides of fatty acids having chain lengths of from about 12 to about 22 carbon atoms, substantially all of the individual particles having a size within the range from about 10 microns to about 500 microns, said product having a solubility in water of 50 ppm max at 25° C. and having a softening point in the range of from about 100° F. to about 200° F. and said product being essentially free of hydrogenated castor oil.
Claim 2
Dependent Claim 297 words
A particulate detergent additive product adapted to prevent static buildup on textiles when applied thereto from a detergent wash liquor, said particulate product being an intimate mixture of: (a) from about 5% to about 95% by weight of the particles of quaternary ammonium compounds of formula [R 1 R 2 R 3 R 4 N] + Y - , wherein at least one of R 1 R 2 R 3 and R 4 is an organic radical containing a group selected from a C 16 -C 22 aliphatic radical, or an alkyl phenyl or alkyl benzyl radical having 10 to 16 carbon atoms in the alkyl chain, the remaining group or groups being selected from C 1 -C 4 alkyl, C 2 -C 4 hydroxyalkyl, and cyclic structures in which the nitrogen atom forms part of the ring, Y consituting an anionic radical selected from the group consisting of hydroxide, halide, acetate, sulphate, methylsulfate ions and phosphate ions, and (b) from about 5% to about 95% by weight of the particles of a dispersion inhibitor, being a solid organic material having a maximum solubility in water of 50 ppm max at 25° C. and a softening point in the range of from about 100° F. to about 200° F., and comprising at least about 1% by weight of solid hydrogenated triglycerides of fatty acids having chain lengths of from about 12 to about 22 carbon atoms, substantially all of the individual particles having a size within the range from about 10 microns to about 500 microns, said product having a solubility in water of 50 ppm max at 25° C. and having a softening point in the range of from about 100° F. to about 200° F. and said product being essentially free of hydrogenated castor oil.
Claim 3
Dependent Claim 30 words
A particulate detergent additive product according to claim 1 wherein substantially all of the particles have a size within the range of from about 25 microns to about 250 microns.
Claim 4
Dependent Claim 30 words
A particulate detergent additive product according to claim 1 wherein substantially all of the particles have a size within the range of from about 50 microns to about 150 microns.
Claim 5
Dependent Claim 28 words
A particulate detergent additive product according to claim 1 wherein the particles have a softening point in the range of from about 150° F. to about 175° F.
Claim 6
Dependent Claim 31 words
A particulate detergent additive product according to claim 1 wherein the weight ratio of quaternary ammonium compound to dispersion inhibitor lies in the range of from about 1:1 to about 8:1.
Claim 7
Dependent Claim 31 words
A particulate detergent additive product according to claim 1 wherein the weight ratio of quaternary ammonium compound to dispersion inhibitor lies in the range of from about 5:1 to about 2:1.
Claim 8
Dependent Claim 28 words
A particulate detergent additive product according to claim 2 wherein the intimate mixture is formed of a solidified comelt of the quaternary ammonium compound and the dispersion inhibitor.
Claim 9
Dependent Claim 27 words
A particulate detergent additive product according to claim 1 wherein the quaternary ammonium compound is selected from ditallow dimethyl ammonium chloride and ditallow dimethyl ammonium methyl sulfate.
Claim 10
Dependent Claim 58 words
A detergent composition adapted to prevent static buildup on textiles laundered therewith consisting essentially of: (a) from about 5% to about 90% by weight of the composition of a surfactant selected from the group consisting of anionic, nonionic, and zwitterionic surfactants, (b) from about 3% to about 50% by weight of the detergent additive product of claim 1.
Claim 11
Dependent Claim 27 words
A detergent composition according to claim 9 wherein substantially of of the detergent additive product particles have a size within the range 25 microns to 250 microns.
Claim 12
Dependent Claim 25 words
A detergent composition according to claim 9 wherein the detergent additive product particles have a softening point in the range 150° F. to 175° F.
Claim 13
Dependent Claim 33 words
A detergent composition according to claim 9 wherein the detergent additive product has a weight ratio of quaternary ammonium compound to dispersion inhibitor in the range of from about 1:1 to about 8:1.
Claim 14
Dependent Claim 30 words
A detergent composition according to claim 9 wherein the detergent additive product is an intimate mixture formed of a solidified comelt of the quaternary ammonium compound and the dispersion inhibitor.
Claim 15
Dependent Claim 74 words
A granular detergent additive product consisting essentially of: (a) from about 5% to about 95% by weight of the detergent additive of claim 1; and (b) from about 95% to about 5% by weight of the product of a detergent adjunct selected from the group consisting of organic and inorganic detergency builders, chlorine and peroxybleach compounds, soil suspending agents, suds modifiers, enzymes, antibacterial agents, and optical brighteners, and mixtures of any of the foregoing.
Claim 16
Dependent Claim 37 words
A granular detergent additive product according to claim 14 wherein the detergent adjunct is a detergency builder selected from the group consisting of alkali metal, ammonium and alkanolammonium, polyphosphates, pyrophosphates, bicarbonates, carbonates, silicates, borates, nitrilotriacetates, and citrates.
Claim 17
Dependent Claim 44 words
A granular detergent additive product according to claim 14 wherein the detergent adjunct is a detergency builder selected from the group consisting of fully hydrated alkali metal zeolite A, B and X-type materials having a particle diameter from about 0.01 to about 10 microns.
Claim 18
Dependent Claim 25 words
A granular additive product according to claim 14 wherein the bleach is selected from the group consisting of sodium perborate, sodium percarbonate, and potassium monopersulfate.
Claim 19
Dependent Claim 28 words
A granular detergent additive product according to claim 14 wherein the enzyme is selected from the group consisting of alkaline and neutral proteases and amylases, and mixtures thereof.
Claim 20
Dependent Claim 101 words
A granular detergent composition adapted to prevent static buildup on textiles laundered therewith consisting essentially of: (a) from about 10% to about 25% by weight of the compositions of an anionic surfactant selected from the group consisting of water-soluble C 10-13 linear and branched alkyl benzene sulfonates, C 10-20 linear alkyl sulfates, C 10-20 alkane sulfonates, C 10-20 olefin sulfonates and mixtures thereof; (b) from about 10% to about 60% by weight of the composition of a detergent builder salt; and (c) from about 3% to about 25% by weight of the composition of the detergent additive product of claim 1.
Claim 21
Dependent Claim 27 words
A granular detergent composition according to claim 19 wherein the detergent builder is present in an amount of from 15% to 45% by weight of the composition.
Claim 22
Dependent Claim 37 words
A granular detergent composition according to claim 19 wherein the detergent builder comprises a water soluble salt selected from the group consisting of alkali metal, ammonium and alkanolammonium, polyphosphates, pyrophosphates, bicarbonates, carbonates, silicates, borates, nitrilotriacetates, and citrates.
Claim 23
Dependent Claim 48 words
A granular detergent composition according to claim 21 whrein the detergent builder additionally comprises from about 5% to about 25% of a detergent builder is selected from fully hydrated alkali metal zeolite A, B and X-type materials having particle diameters of from about 0.01 to about 10 microns.
Claim 24
Dependent Claim 43 words
A granular detergent composition according to claim 19 including from about 5% to about 20% by weight of the composition of a smectite clay selected from the group consisting of alkali metal and calcium montmorillonites, alkali metal saponites and hectorites, and mixtures thereof.
Claim 25
Dependent Claim 21 words
A granular detergent composition according to claim 19 including 0.1% to 5% of a fabric conditioning agent serving to reduce wrinkling.

References Cited (Backward Citations)

US4062647A Cited
US4062647B1 Cited
US3892681A Cited
US3985669A Cited
US3936537A Cited
US4096072A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-28 1985-06-29 1985-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-28 1989-06-29 1989-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-28 1993-06-29 1993-12-29 $7700.00 Window Closed / Lapsed

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