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US4298709A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyhydroxyl polyether compounds containing phosphorus and polymeric resins prepared therefrom

Assignee: Dow Chemical Co
•
Filing: 1980-06-25
•
Granted: 1981-11-03
•
Expires: 2000-06-25
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Abstract

Abstract Polyhydroxyl polyether compounds containing at least one monomeric unit each of the formulae: <IMAGE> are disclosed. Polymeric condensation resins are prepared by allowing the polyhydroxyl polyethers to react with polyfunctional chain-forming compounds containing functional groups reactive with the hydroxyl groups of polyhydroxyl polyethers. The polyhydroxyl polyether compounds enhance the flame-retardant properties of polymeric condensation resins such as polyurethanes.

Inventors

  • 👤 Sally P. Ginter
  • 👤 Chester E. Pawloski
  • 👤 Violete L. Stevens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:35
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/50; C08G18/5075

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 174 words
A polymeric condensation resin comprising the reaction product of: (a) at least one polyhydroxyl polyether of the formula R{C.sub.2 H.sub.3 (Y)O.sub.m X}.sub.n where R is the residue left by the removal of n active hydrogen atoms from an initiator compound for alkylene oxide polymerization RH n ; Y is independently --H, --CH 3 , --C 2 H 5 , --CH 2 Cl, --CH 2 CCl 3 , --CH 2 Br, ##STR15## where Q is independently --Cl or --Br and a=1-5, or --CH 2 OX where X is independently --H or ##STR16## and R' and R" are each independently alkyl, phenyl, haloalkyl, halophenyl, alkoxy, haloalkoxy, polyhaloalkoxy, polyhalophenoxy alkoxy, dialkylamino, arylamino, halophenoxy, or alkylhalophenoxy of up to about 20 carbons; provided that at least one Y is --CH 2 OH and at least one Y is ##STR17## and m and n are integers such that m is at least 2, n being 1-8; and (b) a polyfunctional chain-forming compound containing functional groups reactive with hydroxyl groups of the polyhydroxyl polyether to yield the polymeric condensation resin.
Claim 2
Dependent Claim 174 words
A polymeric condensation resin comprising the reaction product of: (a) at least one polyhydroxyl polyether of the formula R{C.sub.2 H.sub.3 (Y)O.sub.m X}.sub.n where R is the residue left by the removal of n active hydrogen atoms from an initiator compound for alkylene oxide polymerization RH n ; Y is independently --H, --CH 3 , --C 2 H 5 , --CH 2 Cl, --CH 2 CCl 3 , --CH 2 Br, ##STR15## where Q is independently --Cl or --Br and a=1-5, or --CH 2 OX where X is independently --H or ##STR16## and R' and R" are each independently alkyl, phenyl, haloalkyl, halophenyl, alkoxy, haloalkoxy, polyhaloalkoxy, polyhalophenoxy alkoxy, dialkylamino, arylamino, halophenoxy, or alkylhalophenoxy of up to about 20 carbons; provided that at least one Y is --CH 2 OH and at least one Y is ##STR17## and m and n are integers such that m is at least 2, n being 1-8; and (b) a polyfunctional chain-forming compound containing functional groups reactive with hydroxyl groups of the polyhydroxyl polyether to yield the polymeric condensation resin.
Claim 3
Dependent Claim 33 words
The polymeric resin of claim 1 wherein the polyfunctional chain-forming compound of part (b) is selected from the group consisting of organic polyfunctional isocyanates, organic polycarboxylic acids, organic polyfunctional isocyanurates, and organic polyepoxides.
Claim 4
Dependent Claim 60 words
The polymeric resin of claim 1 comprising the reaction product of: (a) at least one organic polyisocyanate; (b) at least one polyhydroxyl polyether of (a); (c) an effective amount of a polyurethane blowing agent; (g) an effective amount of a polyurethane catalyst for promoting the reaction between said organic polyisocyanate and said polyhydroxyl polyether; and (e) a suitable polyurethane surfactant.
Claim 5
Dependent Claim 34 words
The polymeric resin of claim 3 wherein said organic polyfunctional isocyanate is used in amounts corresponding to at least 0.7 NCO groups for each reactive hydroxyl group present in the mixture of reactive materials.
Claim 6
Dependent Claim 51 words
The polymeric resin of claim 1 comprising the reaction product of: (a) at least one organic polyisocyanate; (b) at least one polyhydroxyl polyether of (a); (c) an effective amount of a polyisocyanurate blowing agent; and (d) an effective amount of an isocyanate-trimerization catalyst for promoting the trimerizing of the isocyanate groups.

References Cited (Backward Citations)

US3407150A Cited
US3639543A Cited
US3639541A Cited
US3741919A Cited
US3692880A Cited
US3998764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-11-02 1985-05-04 1985-11-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-11-02 1989-05-04 1989-11-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-11-02 1993-05-04 1993-11-03 $7700.00 Window Closed / Lapsed

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