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US4293446A
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Conversion of synthesis gas with iron-containing catalyst
Assignee: Mobil Oil AS
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Filing: 1980-03-12
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Granted: 1981-10-06
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Expires: 2000-03-12
Abstract
Abstract A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400 DEG F. at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
Inventors
- 👤 Stephen A. Butter
- 👤 Arthur W. Chester
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 15:21
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/42; B01J29/46; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; C; C07; C07C; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/40; C07C2529/42; C07C2529/46
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
80 words
A catalyst composition prepared by forming a homogenous, aqueous mixture of a water insoluble, decomposable iron derivative of an organic compound, a matrix and an acidic crystalline aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units and a constraint index of about 1 to 12, drying and heating said mixture to decompose the organic iron compounds, and treating it with carbon monoxide or mixtures containing the same at elevated temperatures.
Claim 2
Dependent Claim
80 words
A catalyst composition prepared by forming a homogenous, aqueous mixture of a water insoluble, decomposable iron derivative of an organic compound, a matrix and an acidic crystalline aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units and a constraint index of about 1 to 12, drying and heating said mixture to decompose the organic iron compounds, and treating it with carbon monoxide or mixtures containing the same at elevated temperatures.
Claim 3
Dependent Claim
14 words
The composition of claim 1 which has been spray-dried to produce fluid size particles.
Claim 4
Dependent Claim
12 words
The composition of claim 1 wherein said iron compound is ferrous oxalate.
Claim 5
Dependent Claim
12 words
The composition of claim 2 wherein said iron compound is ferrous oxalate.
Claim 6
Dependent Claim
13 words
The composition of claim 4 wherein said iron oxalate is formed in situ.
Claim 7
Dependent Claim
12 words
The composition of claim 1 wherein said matrix is a siliceous matrix.
Claim 8
Dependent Claim
10 words
The composition of claim 1 wherein said matrix comprises alumina.
Claim 9
Dependent Claim
10 words
The composition of claim 1 wherein said matrix comprises silica-alumina.
Claim 10
Dependent Claim
14 words
The composition of claim 6 wherein colloidal dispersions of silica and alumina are used.
Claim 11
Dependent Claim
11 words
The catalyst composition of claim 1 wherein the zeolite is ZSM-5.
Claim 12
Dependent Claim
11 words
The catalyst composition of claim 2 wherein the zeolite is ZSM-5.
Claim 13
Dependent Claim
11 words
The catalyst composition of claim 3 wherein the zeolite is ZSM-5.
Claim 14
Dependent Claim
11 words
The catalyst composition of claim 4 wherein the zeolite is ZSM-5.
Claim 15
Dependent Claim
11 words
The catalyst composition of claim 5 wherein the zeolite is ZSM-5.
Claim 16
Dependent Claim
44 words
The catalyst composition of claim 1 wherein said treatment with carbon monoxide or mixtures containing the same is carried out at atmospheric pressures and at temperatures of about 550°-650° F. for periods of time ranging from about one-half hour up to about 24 hours.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-05 | 1985-04-06 | 1985-10-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-05 | 1989-04-06 | 1989-10-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-05 | 1993-04-06 | 1993-10-06 | $7700.00 | Window Closed / Lapsed |