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US4287316A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent resin composition for information signal recording discs

Assignee: Kureha Corp
•
Filing: 1979-04-19
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Granted: 1981-09-01
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Expires: 1999-04-19
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Abstract

Abstract A transparent resin composition comprising (1) 6 to 100% by weight of a nitrile graft copolymer comprising a rubber trunk polymer and a branch polymer grafted thereon, which has been obtained by graft-polymerizing onto the rubber trunk polymer a monomer mixture containing an unsaturated nitrile and a monomer copolymerizable therewith, and (2) 0 to 94% by weight of a random copolymer of an unsaturated nitrile and a monomer copolymerizable therewith, the resin components of the resin composition other than the rubber trunk polymer constituting a matrix resin, wherein (a) said rubber trunk polymer has a glass transition temperature of not higher than 0° C. and constitutes 4 to 25% by weight of the resin composition, (b) the unsaturated nitrile constitutes 25 to 90% by weight of the matrix resin in the resin composition, (c) the difference in the refractive indexes between the rubber trunk polymer and the matrix resin is not more than 0.008, and (d) the resin composition, when molded into a 3 mm-thick plate, has a transmittance in diethyl phthalate of not lower than 95% with respect to the laser rays used. The above described resin composition has excellent transparency and molding fidelity and can be used for molding information signal recording discs, information pits being engraved on one side of each disc, and a metal coating being deposited thereon, the information signals recorded on the information pits being reproducible by irradiation with laser rays from the other side of said disc.

Inventors

  • 👤 Akira Kaneko
  • 👤 Masaki Ohya
  • 👤 Masayasu Suzuki
  • 👤 Akio Kobayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:30
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/18; C08L33/20; C08F; C08F265/00; C08F265/04; C08F279/00; C08F279/02; C08L51/00; C08L51/04; Y; Y10; Y10S; Y10S525/00; Y10S525/932

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 277 words
In a transparent resin composition for information signal recording discs each having information pits engraved on one side thereof and a metal coating deposited thereon, information signals recorded on the information pits being reproducible by irradiation with laser rays from the opposite side of said disc, the improvement wherein the resin composition comprises (1) 6 to 100% by weight of a nitrile graft copolymer having a rubber trunk polymer and a branch polymer grafted thereon, which has been obtained by graft-polymerizing onto the rubber trunk polymer a monomer mixture consisting of an unsaturated nitrile and at least one monomer copolymerizable therewith selected from the group consisting of alkyl acrylates, alkyl methacrylates, acrylic acid, methacrylic acid, acryl amides, and alkyl vinyl ethers, and (2) 0 to 94% by weight of a nitrile randon compolymer of an unsaturated nitrile and at least one monomer copolymerizable therewith selected from the group consisting of alkyl acrylates, alkyl methacrylates, acrylic acid, methacrylic acid, acryl amides, vinyl esters and alkyl, the components of the resin composition other than the rubber trunk polymer constituting a matrix resin, wherein: (a) said rubber trunk polymer has a glass transition temperature of not higher than 0° C. and constitutes 4 to 25% by weight of the resin composition; (b) the unsaturated nitrile constitutes 25 to 90% by weight of the matrix resin in the resin composition; (c) the difference in the refractive indexes between the rubber trunk polymer and the matrix resin is not more than 0.008; and (d) the resin composition, when molded into a 3 mm-thick plate, has a transmittance in diethyl phthalate of not lower than 95% with respect to the laser rays used.
Claim 2
Dependent Claim 277 words
In a transparent resin composition for information signal recording discs each having information pits engraved on one side thereof and a metal coating deposited thereon, information signals recorded on the information pits being reproducible by irradiation with laser rays from the opposite side of said disc, the improvement wherein the resin composition comprises (1) 6 to 100% by weight of a nitrile graft copolymer having a rubber trunk polymer and a branch polymer grafted thereon, which has been obtained by graft-polymerizing onto the rubber trunk polymer a monomer mixture consisting of an unsaturated nitrile and at least one monomer copolymerizable therewith selected from the group consisting of alkyl acrylates, alkyl methacrylates, acrylic acid, methacrylic acid, acryl amides, and alkyl vinyl ethers, and (2) 0 to 94% by weight of a nitrile randon compolymer of an unsaturated nitrile and at least one monomer copolymerizable therewith selected from the group consisting of alkyl acrylates, alkyl methacrylates, acrylic acid, methacrylic acid, acryl amides, vinyl esters and alkyl, the components of the resin composition other than the rubber trunk polymer constituting a matrix resin, wherein: (a) said rubber trunk polymer has a glass transition temperature of not higher than 0° C. and constitutes 4 to 25% by weight of the resin composition; (b) the unsaturated nitrile constitutes 25 to 90% by weight of the matrix resin in the resin composition; (c) the difference in the refractive indexes between the rubber trunk polymer and the matrix resin is not more than 0.008; and (d) the resin composition, when molded into a 3 mm-thick plate, has a transmittance in diethyl phthalate of not lower than 95% with respect to the laser rays used.
Claim 3
Dependent Claim 29 words
The composition as set forth in claim 1, in which the rubber trunk polymer constituting the nitrile graft copolymer has an average particle size of not more than 0.3μ.
Claim 4
Dependent Claim 17 words
The composition as set forth in claim 1, in which the unsaturated nitrile is acrylonitrile or methacrylonitrile.
Claim 5
Dependent Claim 29 words
The composition as set forth in claim 1, in which the nitrile random copolymer and branch polymer are composed principally of polymerized units of acrylonitrile and an alkyl acrylate.
Claim 6
Dependent Claim 32 words
The composition as set forth in claim 1, in which the nitrile random copolymer and branch polymer are composed principally of polymerized units of methacrylonitrile and at least one from alkyl methacrylate.
Claim 7
Dependent Claim 22 words
The composition as set forth in claim 1, in which the die swell ratio of the composition is not more than 1.60.
Claim 8
Dependent Claim 27 words
The composition as set forth in claim 1, in which the laser rays to be used have a wavelength in the range of 5,000 to 20,000 A.
Claim 9
Dependent Claim 27 words
The composition as set forth in claim 7, in which the laser rays to be used are laser rays which are generated from a helium-neon laser generator.

References Cited (Backward Citations)

US3222422A Cited
US3354238A Cited
US4125654A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-31 1985-03-02 1985-09-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-31 1989-03-02 1989-09-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-31 1993-03-02 1993-09-01 $7700.00 Window Closed / Lapsed

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