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US4274599A Expired / Lapsed US ⏱️ 0.0 years remaining

Ore grinding process including a grinding aid of an anionic polyelectrolyte

Assignee: Dow Chemical Co
•
Filing: 1978-08-11
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Granted: 1981-06-23
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Expires: 1998-08-11
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Abstract

Abstract A process for grinding coal or ores containing metal values comprising carrying out said grinding in a liquid medium and with a grinding aid comprising an anionic polyelectrolyte dispersible in the liquid medium and having a hydrocarbon backbone and a plurality of pendant anionic groups, said grinding aid being present in an amount effective to provide increased grinding efficiency.

Inventors

  • 👤 Willy Manfroy
  • 👤 Richard R. Klimpel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:36
CPC Classifications
B; B02; B02C; B02C23/00; B02C23/06

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 60 words
A process for grinding coal or ores containing metal values comprising carrying out said grinding in the presence of a liquid medium and a grinding aid comprising an anionic polyelectrolyte dispersible in said medium and having a polyethylenic backbone and a plurality of pendant anionic groups, said grinding aid being employed in an amount effective to provide increased grinding efficiency.
Claim 2
Dependent Claim 60 words
A process for grinding coal or ores containing metal values comprising carrying out said grinding in the presence of a liquid medium and a grinding aid comprising an anionic polyelectrolyte dispersible in said medium and having a polyethylenic backbone and a plurality of pendant anionic groups, said grinding aid being employed in an amount effective to provide increased grinding efficiency.
Claim 3
Dependent Claim 29 words
The process of claim 1 wherein the proportion of anionic groups in the polyelectrolyte range from about 1 to about 14 milliequivalents of anionic moiety per gram of electrolyte.
Claim 4
Dependent Claim 29 words
The process of claim 2 wherein the proportion of anionic groups in the polyelectrolyte range from about 2 to about 12 milliequivalents of anionic moiety per gram of polyelectrolyte.
Claim 5
Dependent Claim 22 words
The process of claim 1 wherein the pendant anionic groups on the polyethylenic backbone have a pKa of about 8 or less.
Claim 6
Dependent Claim 22 words
The process of claim 2 wherein the pendant anionic groups on the polyethylenic backbone have a pKa of about 6 or less.
Claim 7
Dependent Claim 22 words
The process of claim 3 wherein the pendant anionic groups on the polyethylenic backbone have a pKa of about 6 or less.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the anionic groups are carboxylate or sulfonate.
Claim 9
Dependent Claim 13 words
The process of claim 4 wherein the anionic groups are carboxylate or sulfonate.
Claim 10
Dependent Claim 17 words
The process of claim 1 wherein the polyelectrolyte is a water-dispersible polymer or copolymer of anionic monomers.
Claim 11
Dependent Claim 68 words
The process of claim 9 wherein said polyelectrolyte is a polymer of alpha,beta-ethylenically unsaturated carboxylic acids, partial esters of alpha,beta-ethylenically unsaturated polycarboxylic acids, N-sulfoalkyl derivatives of alpha,beta-ethylenically unsaturated amides, sulfoalkyl esters of alpha,beta-ethylenically unsaturated carboxylic acids, alpha,beta-ethylenically unsaturated aromatic sulfonic acids, including copolymers of at least one of the aforementioned monomers with at least one other ethylenically unsaturated monomer; sulfonated monovinylidene aromatic polymers; or sulfonated aliphatic monoolefinic polymers.
Claim 12
Dependent Claim 19 words
The process of claim 1 wherein the polyelectrolyte has a molecular weight of from about 200 to about 100,000.
Claim 13
Dependent Claim 19 words
The process of claim 1 wherein the polyelectrolyte has a molecular weight of from about 1000 to about 60,000.
Claim 14
Dependent Claim 19 words
The process of claim 1 wherein the polyelectrolyte has a molecular weight of from about 2000 to about 20,000.
Claim 15
Dependent Claim 12 words
The process of claim 1 wherein ores containing metal values are ground.
Claim 16
Dependent Claim 9 words
The process of claim 1 wherein coal is ground.
Claim 17
Dependent Claim 12 words
The process of claim 14 wherein the ore is an iron ore.
Claim 18
Dependent Claim 12 words
The process of claim 14 wherein the ore is a copper ore.
Claim 19
Dependent Claim 12 words
The process of claim 14 wherein the ore is a gold ore.
Claim 20
Dependent Claim 25 words
The process of claim 10 wherein the polyelectrolyte is a polymer of alpha,beta-ethylenically unsaturated carboxylic acids or the partial esters of alpha-beta-ethylenically unsaturated polycarboxylic acids.
Claim 21
Dependent Claim 12 words
The process of claim 19 wherein ores containing metal values are ground.
Claim 22
Dependent Claim 9 words
The process of claim 19 wherein coal is ground.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-22 1984-12-22 1985-06-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-22 1988-12-22 1989-06-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-22 1992-12-22 1993-06-23 $7700.00 Window Closed / Lapsed

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