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US4265802A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester of para-hydroxy benzoic acid, 1,4-bis(para-carboxyphenoxy) benzene, aromatic diol and aromatic diacid capable of undergoing melt processing

Assignee: Celanese Corp
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Filing: 1980-01-04
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Granted: 1981-05-05
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Expires: 2000-01-04
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Abstract

Abstract A novel polyester is provided which has been found to exhibit an optically anisotropic melt phase which enables it readily to undergo melt processing to form quality fibers, films, molded articles, etc. The polyester of the present invention contains recurring para-oxybenzoyl and para-phenylenedioxy-4,4'-dibenzoyl moieties in addition to moieties derived from at least one aromatic diol and at least one additional aromatic diacid in the proportions indicated. The hydrogen atoms present upon the aromatic rings derived from the aromatic diol and additional aromatic diacid optionally may be at least partially substituted (as described). The wholly aromatic polyester is capable of forming the desired anisotropic melt at a temperature below approximately 400° C., and in a preferred embodiment at a temperature below approximately 360° C.

Inventors

  • 👤 Eui W. Choe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:59
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/02; C08G63/60; C08G63/605

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 184 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR14## III is a dioxy aryl moiety of the formula --O--AR--O-- where Ar is a divalent radical comprising at least one aromatic ring wherein at least one hydrogen atom present upon an aromatic ring optionally may be substituted with methyl, chloro, bromo, phenyl, alkoxy having 1 to 4 carbon atoms, and mixtures of the foregoing, and IV is a dicarboxy aryl moiety of the formula ##STR15## where Ar' is a divalent radical comprising at least one aromatic ring wherein at least one hydrogen atom present upon an aromatic ring optionally may be substituted with methyl, chloro, bromo, phenyl, alkoxy having 1 to 4 carbon atoms, and mixtures of the foregoing, and wherein said polyester comprises approximately 30 to 60 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, approximately 20 to 35 mole percent of moiety III, and approximately 10 to 25 mole percent of moiety IV.
Claim 2
Dependent Claim 184 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR14## III is a dioxy aryl moiety of the formula --O--AR--O-- where Ar is a divalent radical comprising at least one aromatic ring wherein at least one hydrogen atom present upon an aromatic ring optionally may be substituted with methyl, chloro, bromo, phenyl, alkoxy having 1 to 4 carbon atoms, and mixtures of the foregoing, and IV is a dicarboxy aryl moiety of the formula ##STR15## where Ar' is a divalent radical comprising at least one aromatic ring wherein at least one hydrogen atom present upon an aromatic ring optionally may be substituted with methyl, chloro, bromo, phenyl, alkoxy having 1 to 4 carbon atoms, and mixtures of the foregoing, and wherein said polyester comprises approximately 30 to 60 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, approximately 20 to 35 mole percent of moiety III, and approximately 10 to 25 mole percent of moiety IV.
Claim 3
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximatey 360° C.
Claim 4
Dependent Claim 25 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety III and said dicarboxyl aryl moiety IV are symmetrically disposed.
Claim 5
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 1 wherein each moiety is substantially free of ring substitution.
Claim 6
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety III is selected from the group consisting of: ##STR16## and mixtures of the foregoing.
Claim 7
Dependent Claim 18 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety III is ##STR17##
Claim 8
Dependent Claim 18 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety III is ##STR18##
Claim 9
Dependent Claim 29 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dicarboxy aryl moiety IV is selected from the group consisting of: ##STR19## and mixtures of the foregoing.
Claim 10
Dependent Claim 18 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dicarboxy aryl moiety IV is ##STR20##
Claim 11
Dependent Claim 49 words
A melt processable wholly aromatic polyester according to claim 1 which comprises approximately 35 to 50 mole percent of moiety I, approximately 10 to 25 mole percent of moiety II, approximately 25 to 30 mole percent of moiety III, and approximately 10 to 15 mole percent of moiety IV.
Claim 12
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 2.5 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorphenol at 60° C.
Claim 13
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 3.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 14
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of 3.0 to 5.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 15
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 1.
Claim 16
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 1.
Claim 17
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 1.
Claim 18
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 19
Dependent Claim 75 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 360° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR21## and wherein said polyester comprises approximately 30 to 60 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, approximately 20 to 35 mole percent of moiety III, and approximately 10 to 25 mole percent of moiety IV.
Claim 20
Dependent Claim 75 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 360° C. consisting essentially of the recurring moieties I, II, III, and IV wherein: ##STR21## and wherein said polyester comprises approximately 30 to 60 mole percent of moiety I, approximately 10 to 30 mole percent of moiety II, approximately 20 to 35 mole percent of moiety III, and approximately 10 to 25 mole percent of moiety IV.
Claim 21
Dependent Claim 49 words
A melt processable wholly aromatic polyester according to claim 18 which comprises approximately 35 to 50 mole percent of moiety I, approximately 10 to 25 mole percent of moiety II, approximately 25 to 30 mole percent of moiety III, and approximately 10 to 15 mole percent of moiety IV.
Claim 22
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 18 which exhibits an inherent viscosity of at least 2.5 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 23
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 18 which exhibits an inherent viscosity of at least 3.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 24
Dependent Claim 35 words
A melt processable wholly aromatic polyester according to claim 18 which exhibits an inherent viscosity of 3.0 to 5.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 25
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 18.
Claim 26
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 18.
Claim 27
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 18.
Claim 28
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 18 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

References Cited (Backward Citations)

US3884876A Cited
US4118372A Cited
US4066620A Cited
US4130545A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-04 1984-11-03 1985-05-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-04 1988-11-03 1989-05-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-04 1992-11-03 1993-05-05 $7700.00 Window Closed / Lapsed

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