US4252865A
Expired / Lapsed
US
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Highly solar-energy absorbing device and method of making the same
Assignee: National Patent Development Corp
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Filing: 1978-05-24
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Granted: 1981-02-24
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Expires: 1998-05-24
Abstract
Abstract The invention contemplates a highly solar-energy absorbing device wherein the surface exposed to incident solar energy is a particularly characterized roughness of an amorphous semiconductor material, the particular characterization being that of an array of outwardly projecting structural elements of relatively high aspect ratio and at effective lateral spacings which are or include those in the order of magnitude of wavelengths within the solar-energy spectrum.
Inventors
- 👤 Laurence R. Gilbert
- 👤 Russell F. Messier
- 👤 Rustum Roy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 18:19
CPC Classifications
H; H10; H10F; H10F71/00; H10F71/10; H10F71/103; F; F24; F24S; F24S70/00; F24S70/20; F24S70/225; F24S70/25; H10F77/00; H10F77/70; H10F77/703; Y; Y02; Y02E; Y02E10/00; Y02E10/40; Y02E10/50; Y02P; Y02P70/00; Y02P70/50; Y10; Y10S; Y10S126/00; Y10S126/907; Y10S126/908; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/12; Y10T428/12465; Y10T428/12493; Y10T428/12528; Y10T428/12674; Y10T428/12993; Y10T428/26; Y10T428/261
Claims Analysis
Total Claims: 40
Claim 1
Independent Claim
42 words
A highly solar-energy absorbing device comprising an amorphous semiconductor body having at least one etched surface characterized by an array of oriented acicular structures, wherein the distance between adjacent structures is within or near the solar-energy wavelength or wavelengths to be absorbed.
Claim 2
Dependent Claim
42 words
A highly solar-energy absorbing device comprising an amorphous semiconductor body having at least one etched surface characterized by an array of oriented acicular structures, wherein the distance between adjacent structures is within or near the solar-energy wavelength or wavelengths to be absorbed.
Claim 3
Dependent Claim
86 words
An energy-absorbing device that is highly absorbent of energy incident in a particular direction and in a particular and limited spectral range, comprising an amorphous semiconductor body having an etched surface adapted to be exposed to such energy incidence, said surface being characterized by an array of acicular structures having spaced axes such that at least a substantial fraction of said structures are at an axis-to-axis lateral offset between adjacent acicular structures which offset is in the order of magnitude of wavelengths within the solar-energy spectrum.
Claim 4
Dependent Claim
86 words
An energy-absorbing device that is highly absorbent of energy incident in a particular direction and in a particular and limited spectral range, comprising an amorphous semiconductor body having an etched surface adapted to be exposed to such energy incidence, said surface being characterized by an array of acicular structures having spaced axes such that at least a substantial fraction of said structures are at an axis-to-axis lateral offset between adjacent acicular structures which offset is in the order of magnitude of wavelengths within the solar-energy spectrum.
Claim 5
Dependent Claim
16 words
The device of claim 2, in which said acicular structures are of randomly distributed axial extent.
Claim 6
Dependent Claim
22 words
The device of claim 2, in which the aspect ratio of said acicular structures is in the range of 2:1 to 10:1.
Claim 7
Dependent Claim
18 words
The device of claim 2, in which the aspect ratio of said acicular structures is greater than 3:1.
Claim 8
Dependent Claim
82 words
A highly solar-energy absorbing device, comprising an amorphous semiconductor body having at least one etched surface characterized by an array of interpenetrating generally conical pits, wherein said pits are of randomly distributed depth and wherein the spacing between pits of greatest depth does not substantially exceed the wavelength of the infrared end of the solar-energy spectrum, whereby the axial spacing between pits of lesser depth within said random distribution necessarily includes a random distribution of spacings of smaller pits at solar-energy wavelengths.
Claim 9
Dependent Claim
82 words
A highly solar-energy absorbing device, comprising an amorphous semiconductor body having at least one etched surface characterized by an array of interpenetrating generally conical pits, wherein said pits are of randomly distributed depth and wherein the spacing between pits of greatest depth does not substantially exceed the wavelength of the infrared end of the solar-energy spectrum, whereby the axial spacing between pits of lesser depth within said random distribution necessarily includes a random distribution of spacings of smaller pits at solar-energy wavelengths.
Claim 10
Dependent Claim
77 words
A highly solar-energy absorbing device, comprising a substrate having a supporting surface, a sputtered amorphous semiconductor body united to and covering at least a portion of said surface, said body having an etched outer surface substantially characterized by an array of outwardly projecting structural elements of aspect ratio within the range 2:1 to 10:1 and at lateral spacings at least a substantial fraction of which are in the order of magnitude of wavelengths within the solar-energy spectrum.
Claim 11
Dependent Claim
77 words
A highly solar-energy absorbing device, comprising a substrate having a supporting surface, a sputtered amorphous semiconductor body united to and covering at least a portion of said surface, said body having an etched outer surface substantially characterized by an array of outwardly projecting structural elements of aspect ratio within the range 2:1 to 10:1 and at lateral spacings at least a substantial fraction of which are in the order of magnitude of wavelengths within the solar-energy spectrum.
Claim 12
Dependent Claim
13 words
The device of claim 7, in which said projecting structural elements are acicular.
Claim 13
Dependent Claim
30 words
The device of claim 7, in which said projecting structural elements are of randomly distributed peak elevation with respect to the unetched body material to which they are integrally connected.
Claim 14
Dependent Claim
24 words
The device of claim 7, in which said projecting structural elements are defined by intersecting walls of an array of interpenetrating generally conical pits.
Claim 15
Dependent Claim
18 words
The device of claim 7, in which said body includes tetrahedrally bonded amorphous material as an essential component.
Claim 16
Dependent Claim
25 words
The device of claim 7, in which said body is of tetrahedrally bonded amorphous material selected from the group including non-crystalline germanium and non-crystalline silicon.
Claim 17
Dependent Claim
18 words
The device of claim 7, in which said body comprises an alloy of non-crystalline germanium and non-crystalline silicon.
Claim 18
Dependent Claim
20 words
The device of claim 7, in which said surface is substantially flat, but for said array of projecting structural elements.
Claim 19
Dependent Claim
21 words
The device of claim 7, in which said surface is convex and curvilinear, but for said array of projecting structural elements.
Claim 20
Dependent Claim
11 words
The device of claim 15, in which said surface is cylindrical.
Claim 21
Dependent Claim
20 words
The device of claim 14, in which the projecting direction of said structural elements is substantially normal to said surface.
Claim 22
Dependent Claim
26 words
The device of claim 14, in which the projecting direction of said structural elements is at substantially the same inclination to a normal to said surface.
Claim 23
Dependent Claim
17 words
The device of claim 7, in which said semiconductor body is an element of a photothermal device.
Claim 24
Dependent Claim
17 words
The device of claim 7, in which said semiconductor body is an element of a photovoltaic cell.
Claim 25
Dependent Claim
14 words
The device of claim 7, in which said semiconductor body is a thin film.
Claim 26
Dependent Claim
22 words
The device of claim 7, in which said substrate is of metal, at least at or near interface with said semiconductor body.
Claim 27
Independent Claim
113 words
The method of making a highly solar-energy absorbing surface on a substrate body, which comprises the controlled sputtering application of a layer of amorphous semiconductor material to an exposed-surface area of said body, and then altering the exposed-surface morphology of said layer by etching the same to form an array of outwardly projecting structural elements, the etchant being selected for the particular semiconductor material and applied in such strength and for such exposure time and ambient conditions of temperature as to form said structural elements with an aspect ratio in the range 2:1 to 10:1 and at lateral spacings which are in the order of magnitude of a wavelength within the solar-energy spectrum.
Claim 28
Independent Claim
113 words
The method of making a highly solar-energy absorbing surface on a substrate body, which comprises the controlled sputtering application of a layer of amorphous semiconductor material to an exposed-surface area of said body, and then altering the exposed-surface morphology of said layer by etching the same to form an array of outwardly projecting structural elements, the etchant being selected for the particular semiconductor material and applied in such strength and for such exposure time and ambient conditions of temperature as to form said structural elements with an aspect ratio in the range 2:1 to 10:1 and at lateral spacings which are in the order of magnitude of a wavelength within the solar-energy spectrum.
Claim 29
Dependent Claim
22 words
The method of claim 23, in which said amorphous semiconductor material is non-crystalline germanium and the etchant consists essentially of hydrogen peroxide.
Claim 30
Dependent Claim
23 words
The method of claim 24, in which the hydrogenperoxide etchant is to the extent of a substantially 30 percent solution thereof in water.
Claim 31
Dependent Claim
25 words
The method of claim 23, in which said amorphous semiconductor material is non-crystalline silicon and the etchant consists essentially of hydrogen fluoride and nitric acid.
Claim 32
Dependent Claim
20 words
The method of claim 26, in which the proportion by volume of hydrogen fluoride to nitric acid is approximately 10:1.
Claim 33
Dependent Claim
29 words
The method of claim 27, in which said etchant further includes water dilution, to the extent that the volume proportions of nitric acid and water are substantially the same.
Claim 34
Dependent Claim
21 words
The method of claim 23, in which said etching step is one of a plurality of etching steps with different etchants.
Claim 35
Dependent Claim
23 words
The method of claim 23, in which said controlled sputtering step is one of a plurality of sputtering steps with different sputtered materials.
Claim 36
Dependent Claim
16 words
The method of claim 30, in which the etching step is performed between successive sputtering steps.
Claim 37
Dependent Claim
20 words
The method of claim 23, including the additional step of annealing at least to the extent of crystallizing said body.
Claim 38
Dependent Claim
8 words
The product of the method of claim 32.
Claim 39
Dependent Claim
117 words
The product of the method of making a highly solar-energy absorbing surface on a substrate body, which comprises the controlled sputtering application of a layer of amorphous semiconductor material to an exposed-surface area of said body, and then altering the exposed-surface morphology of said layer by etching the same to form an array of outwardly projecting structural elements, the etchant being selected for the particular semiconductor material and applied in such strength and for such exposure time and ambient conditions of temperature as to form at least a substantial fraction of said structural elements with an aspect ratio in the range 2:1 to 10:1 and at lateral spacings which are in the range of 0.2 to 2.0μ.
Claim 40
Dependent Claim
117 words
The product of the method of making a highly solar-energy absorbing surface on a substrate body, which comprises the controlled sputtering application of a layer of amorphous semiconductor material to an exposed-surface area of said body, and then altering the exposed-surface morphology of said layer by etching the same to form an array of outwardly projecting structural elements, the etchant being selected for the particular semiconductor material and applied in such strength and for such exposure time and ambient conditions of temperature as to form at least a substantial fraction of said structural elements with an aspect ratio in the range 2:1 to 10:1 and at lateral spacings which are in the range of 0.2 to 2.0μ.
References Cited (Backward Citations)
CA751084A
Cited
US4137123A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-02-24 | 1984-08-25 | 1985-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-24 | 1988-08-25 | 1989-02-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-02-24 | 1992-08-25 | 1993-02-24 | $7700.00 | Window Closed / Lapsed |