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US4250072A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiopaque polyurethane resin compositions

Assignee: Becton Dickinson and Co
•
Filing: 1979-05-18
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Granted: 1981-02-10
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Expires: 1999-05-18
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Abstract

Abstract Radiopaque compositions are provided by formulating polyurethane resins, alone, or combined with vinyl resins, with alkyl or alkoxyalkyl 2,5-diiodobenzoates, 2,3,4,6-tetraiodobenzoates or mixtures thereof. The compositions are useful in the manufacture of X-ray opaque medical devices, particularly medical surgical tubing. Surgical tubing with excellent plastic memory is provided, well adapted to forming flares and curved tips necessary for selective renal and celial arteriography. Multi-wall and co-tapered multiwall tubing contructions are also disclosed.

Inventors

  • 👤 Vincent J. Flynn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-22 20:18
CPC Classifications
A; A61; A61L; A61L29/00; A61L29/04; A61L29/06; A61L29/049; A61L29/14; A61L29/18; A61M; A61M25/00; A61M25/0009; A61M25/0021; A61M25/0041; A61M25/0043; A61M25/0045; A61M25/01; A61M25/0105; A61M25/0108; B; B29; B29C; B29C48/00; B29C48/16; B29C48/18; B29C48/21; B29C48/25; B29C48/30; B29C48/32; B29C48/335; B29C48/336; C; C08; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/101; C08L; C08L27/00; C08L75/00; C08L75/04; A61B; A61B90/00; A61B90/39; A61F; A61F2210/00; A61F2210/0014; A61F2210/0019; B29C48/03; B29C48/09; B29L; B29L2031/00; B29L2031/753; B29L2031/7542

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 89 words
A radiopaque composition comprising (a) a resin which includes from 100 to 33 parts by weight of a thermoplastic polyurethane and from 0 to 67 parts of a polymer of a halogenated vinyl monomer; and (b) a radiopacifier therefor consisting of a diiodobenzoate or a tetraiodobenzoate compound of the formula ##STR2## wherein R 1 is hydrogen or iodo, and R is alkyl or alkoxyalkyl or a mixture of said compounds, said radiopacifier or comprising 10 to 40 parts by weight per 100 parts by weight of (a) and (b).
Claim 2
Dependent Claim 89 words
A radiopaque composition comprising (a) a resin which includes from 100 to 33 parts by weight of a thermoplastic polyurethane and from 0 to 67 parts of a polymer of a halogenated vinyl monomer; and (b) a radiopacifier therefor consisting of a diiodobenzoate or a tetraiodobenzoate compound of the formula ##STR2## wherein R 1 is hydrogen or iodo, and R is alkyl or alkoxyalkyl or a mixture of said compounds, said radiopacifier or comprising 10 to 40 parts by weight per 100 parts by weight of (a) and (b).
Claim 3
Dependent Claim 23 words
A composition as defined in claim 1 wherein, in said radiopacifier, each R 1 is iodo and R is (lower)alkyl or (lower)alkoxy (lower)alkyl.
Claim 4
Dependent Claim 13 words
A composition as defined in claim 1 wherein said radiopacifier is n-butyl 2,3,4,6-tetraiodobenzoate.
Claim 5
Dependent Claim 13 words
A composition as defined in claim 1 wherein compound (b) is 2-ethoxyethyl 2,5-diiodobenzoate.
Claim 6
Dependent Claim 19 words
A composition as defined in claim 1 wherein compound (b) is a mixture of n-butyl 2,3,4,6-tetraiodobenzoate and 2-ethoxyethyl 2,5-diiodobenzoate.

References Cited (Backward Citations)

US3356650A Cited
US3361700A Cited
US3489723A Cited
US3752617A Cited
US3645955A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-10 1984-08-11 1985-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-10 1988-08-11 1989-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-10 1992-08-11 1993-02-10 $7700.00 Window Closed / Lapsed

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