Patent US4374517A successfully refreshed from Google Patents.
US4247449A
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Urea derivatives, process for their manufacture and their use as light protecting agents for polymers
Assignee: Hoechst AG
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Filing: 1979-07-31
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Granted: 1981-01-27
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Expires: 1999-07-31
Abstract
Abstract The amide nitrogen of 9,9-dimethyl-2-oxa-4-oxo-3,8-diazaspiro-(4,5)-decane reacts with isocyanates or diisocyanates to give novel urea derivatives which can be used as light stabilizers for plastic materials.
Inventors
- 👤 Hartmut Wiezer
- 👤 Norbert Mayer
- 👤 Harald Knorr
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 10:02
CPC Classifications
C; C07; C07D; C07D498/00; C07D498/02; C07D498/10; C07D498/12; C07D498/20; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
326 words
Urea derivatives of the formula (I) ##STR3## in which R 1 and R 2 denote identical or different straight chain or branched alkyl radicals having from 1 to 12 carbon atoms, or R 1 and R 2 together with the carbon atom to which they are linked denote a cyclopentane or cyclohexane ring which may be methylsubstituted or a 2,2,6,6-tetramethylpiperidine ring carbon atom 4 of which is identical with carbon atom 7 of the spirodecane system; R 3 denotes hydrogen, alkyl or isoalkyl having from 1 to 30 carbon atoms, or aralkyl having from 7 to 10 carbon atoms; R 4 denotes hydrogen, alkyl having from 1 to 30 carbon atoms, phenyl or naphthyl which may be substituted by a halogen atom, or alkyl having from 1 to 4 carbon atoms, or denotes aralkyl with 7 to 10 carbon atoms, or R 3 and R 4 may also be together with the carbon atom by which they are linked a cycloalkane ring having from 4 to 20 carbon atoms which may be substituted by C 1 to C 4 alkyl radicals; R 5 denotes hydrogen, oxygen or C 1 -C 4 alkyl; n is 1 or 2 depending on the valence of R 6 , R 6 , with n being 1, denotes alkyl having from 1 to 20 carbon atoms, alkenyl having from 2 to 18 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms which may be substituted by a C 1 -C 4 -alkyl radical; phenyl or naphthyl which may be substituted by a chlorine atom or alkyl having from 1 to 18 carbon atoms; or phenylalkyl having from 7 to 18 carbon atoms, or R 6 , with n being 2, denotes a straight chain or branched alkylene group having from 2 to 20 carbon atoms, or phenylene or naphthylene which may be substituted by C 1 -C 4 alkyl, or a diphenylenealkane radical having from 13 to 18 carbon atoms.
Claim 2
Dependent Claim
326 words
Urea derivatives of the formula (I) ##STR3## in which R 1 and R 2 denote identical or different straight chain or branched alkyl radicals having from 1 to 12 carbon atoms, or R 1 and R 2 together with the carbon atom to which they are linked denote a cyclopentane or cyclohexane ring which may be methylsubstituted or a 2,2,6,6-tetramethylpiperidine ring carbon atom 4 of which is identical with carbon atom 7 of the spirodecane system; R 3 denotes hydrogen, alkyl or isoalkyl having from 1 to 30 carbon atoms, or aralkyl having from 7 to 10 carbon atoms; R 4 denotes hydrogen, alkyl having from 1 to 30 carbon atoms, phenyl or naphthyl which may be substituted by a halogen atom, or alkyl having from 1 to 4 carbon atoms, or denotes aralkyl with 7 to 10 carbon atoms, or R 3 and R 4 may also be together with the carbon atom by which they are linked a cycloalkane ring having from 4 to 20 carbon atoms which may be substituted by C 1 to C 4 alkyl radicals; R 5 denotes hydrogen, oxygen or C 1 -C 4 alkyl; n is 1 or 2 depending on the valence of R 6 , R 6 , with n being 1, denotes alkyl having from 1 to 20 carbon atoms, alkenyl having from 2 to 18 carbon atoms, cycloalkyl having from 5 to 12 carbon atoms which may be substituted by a C 1 -C 4 -alkyl radical; phenyl or naphthyl which may be substituted by a chlorine atom or alkyl having from 1 to 18 carbon atoms; or phenylalkyl having from 7 to 18 carbon atoms, or R 6 , with n being 2, denotes a straight chain or branched alkylene group having from 2 to 20 carbon atoms, or phenylene or naphthylene which may be substituted by C 1 -C 4 alkyl, or a diphenylenealkane radical having from 13 to 18 carbon atoms.
Claim 3
Dependent Claim
20 words
Compounds as claimed in claim 1, in which R 1 and R 2 denote methyl and R 5 denotes hydrogen.
Claim 4
Dependent Claim
82 words
Process for the manufacture of compounds as claimed in claim 1, which comprises reacting a compound of the formula III ##STR4## in an inert organic solvent, at a temperature of 20° to 80° C. and with the addition of catalytic amount of a base, with an isocyanate of the formula II R.sub.6 (NCO).sub.n (II) in which formulae R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and n are as defined in claim 1.
Claim 5
Dependent Claim
46 words
Synthetic polymers stabilized against UV decomposition containing from 0.01 to 5 parts by weight, calculated on the polymer, of a compound as claimed in claim 1 or 2, either per se or in the form of a salt with a non oxidizing inorganic or organic acid.
Claim 6
Dependent Claim
58 words
Process for stabilizing synthetic polymers against the detrimental influence of light, which comprises adding to the polymer to be stabilized from 0.01 to 5 parts by weight, calculated on the polymer, of a compound as claimed in claim 1, per se or in the form of a salt with a non oxidizing inorganic acid or an organic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-27 | 1984-07-28 | 1985-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-27 | 1988-07-28 | 1989-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-27 | 1992-07-28 | 1993-01-27 | $7700.00 | Window Closed / Lapsed |