Polymeric light stabilizers for plastics

Claim 2

A polyester, the recurrent molecular unit of which contains a polyalkylpiperidine radical of the formula ##STR61## or is substituted by a polyalkylpiperidine side group of the formula ##STR62## in which R denotes hydrogen or alkyl with 1-5 C atoms and R' denotes hydrogen, alkyl with 1-12 C atoms, alkenyl with 3-8 C atoms, alkinyl with 3-6 C atoms, aralkyl with 7-12 C atoms, alkanoyl with 1-8 C atoms or alkenoyl with 3-5 C atoms, and copolymers thereof with polyalkylpiperidine-free components.

Claim 3

A polyester, the recurrent molecular unit of which contains a polyalkylpiperidine radical of the formula ##STR63## or is substituted by a polyalkylpiperidine side group of the formula ##STR64## in which R denotes hydrogen or an alkyl radical with 1-5 C atoms and R' denotes hydrogen, alkyl with 1-12 C atoms, allyl, benzyl, acetyl, acryloyl or crotonyl.

Claim 4

A polyester, the recurrent molecular unit of which contains a polyalkylpiperidine radical of the formula ##STR63## or is substituted by a polyalkylpiperidine side group of the formula ##STR64## in which R denotes hydrogen or an alkyl radical with 1-5 C atoms and R' denotes hydrogen, alkyl with 1-12 C atoms, allyl, benzyl, acetyl, acryloyl or crotonyl.

Claim 5

A polyester according to claim 1 of the general formula I or II ##STR65## wherein A, B and D denote divalent organic radicals, n has a value of from 2 to about 50, and, in each of the formulae I and II at least one polyalkylpiperidine radical is present in the main chain or as a side group.

Claim 6

A polyester according to claim 3 of the general formula I, in which X and X' denote oxygen and A denotes one of the radicals of the formulae IX to XVII ##STR66## in which R denotes hydrogen or alkyl with 1-5 C atoms, R' denotes hydrogen, alkyl with 1-12 C atoms, allyl, benzyl, acetyl, acryloyl or crotonyl, m is 1, 2 or 3, p is zero or 1, preferably zero, R 4 denotes hydrogen, alkyl with 1-12 C atoms, allyl, benzyl or 3,5-di-tert.butyl-4-hydroxybenzyl, X" is oxygen or preferably NH, Z denotes a direct bond or --CH 2 CH 2 -- or --OCH 2 CH 2 CH 2 --, Z 1 denotes --CH 2 --, --CH 2 CH 2 -- or --CO--Z 12 -- and Z 12 denotes one of the radicals --CH 2 CH 2 --, --(CH 2 ) 3 --, --CH═CH--, ##STR67## Z 2 denotes one of the radicals --N(R")--, --NR 3 --CO--NR 3 --, --NR 3 --CO--CO--NR 3 --, --NR 3 --CO--Z 3 --CO--NR 3 --, alkylene with 4-10 C atoms, p-xylylene ##STR68## -O-alkylene-O- with 1-10 C atoms, -O-alkenylene-O- with 4-8 C atoms or --O--xylylene--O--, in which R 3 denotes hydrogen, alkyl with 1-12 C atoms, cyclohexyl, benzyl or aryl with 6-14 C atoms, but preferably H, R" denotes alkanoyl with 1-8 C atoms or alkenoyl with 3-5 C atoms and Z 3 denotes alkylene with 1-10 C atoms or phenylene, and B' represents an alkylene radical with 2-12 C atoms, a xylylene or hexahydroxylylene radical, a cyclohexylene or 4,4'-dicyclohexylmethane radical, an arylene radical with 6-12 C atoms or a -phenylene-Z 4 -phenylene- radical, in which Z 4 denotes --CH 2 --, C(CH 3 ) 2 . --O-- or --SO 2 --, and in which B denotes an alkylene radical with 2-12 C atoms, an alkenylene radical with 4-8 C atoms, a xylylene or hexahydroxylylene radical, a cyclohexylene radical or a radical of the formula --CH 2 CH 2 OCH 2 CH 2 -- or --CH 2 CH 2 O-phenylene-OCH 2 CH 2 --.

Claim 7

A polyester according to claim 3 of the formula I, in which X and X' are oxygen, A denotes a direct bond, alkylene or phenyl-substituted, benzyl-substituted or hydroxydialkylbenzyl-substituted alkylene with 1-12 C atoms, arylene with 6-12 C atoms, cycloalkylene with 6-12 C atoms or a radical of the formula IX to XVII defined in claim 4 and B represents one of the radicals of the formulae XVIII to XXX ##STR69## in which R, R', X", R 3 , Z, Z 2 and B' have the meanings indicated in claim 4, R 5 is hydrogen, methyl or phenyl, Z 5 represents alkylene or alkenylene with 4-8 C atoms, p-xylylene or a group of the formula ##STR70## Z 6 represents one of the groups --CH 2 CH 2 --, --OCH 2 CH(R 5 )--N(R 3 )--CH 2 --CH(R 5 )--, --CH 2 CH 2 --N(R 3 )--CH 2 CH(R 5 )-- or --O--(CH 2 ) 3 --N(R 3 )--CH 2 CH(R 5 )--, Z 7 is alkylene with 2-12 C atoms, arylene with 6-12 C atoms, 4,4'-dicyclohexylenemethane or a radical -phenylene-Z 4 -phenylene- in which Z 4 has the meaning indicated in claim 4, Z 7' denotes alkylene or alkenylene with 4-8 C atoms or p-xylylene and B" has the same meaning as B in claim 4.

Claim 8

A polyester according to claim 3 of the general formula II, in which X is oxygen and -X-D-CO- represents one of the radicals of the formulae L to LIX ##STR71## in which m, X", Z, R, R' and Z 12 have the same meaning as in claim 4 and R 5 has the same meaning as in claim 5.

Claim 9

A copolymer according to claim 1, which consists of one of the structural units listed in claims 4, 5 or 6 and a polyalkylpiperidine-free structural unit.

Claim 10

A copolymer according to claim 7 in which the proportion of the polyalkylpiperidine-free component is at most 50 mol %.

Claim 11

A polyester according to claim 1 in which R is hydrogen or methyl.

Claim 12

A polyester according to claim 1 in which R is hydrogen.

Claim 13

A polyester according to one of claims 4, 5 or 6 in which R' denotes hydrogen or methyl.

Claim 14

A polyester according to claim 11 in which R' is hydrogen.

Claim 15

A polyester according to one of claims 4 or 6 in which R 3 is hydrogen.

Claim 16

A polyester according to claim 4 of the general formula I, in which X and X' are oxygen, B denotes an alkylene radical with 2-12 C atoms, an alkenylene radical with 4-8 C atoms, a xylylene or hexahydroxylylene radical, a cyclohexylene radical or a radical of the formula --CH 2 CH 2 OCH 2 CH 2 -- or --CH 2 CH 2 O-phenylene--OCH 2 CH 2 -- and A denotes one of the radicals of the formulae XIV, XV or XVI, in which R and R' denote hydrogen or methyl, Z is a direct bond, M is 1 or 2 and Z 1 , Z 2 and B' have the meaning given in claim 4.

Claim 17

A polyester according to claim 5 of the general formula I, in which X and X' are oxygen, A represents alkylene or phenyl-substituted or benzyl-substituted alkylene with 1-15 C atoms or arylene with 6-12 C atoms and B represents one of the radicals of the formulae XVIII, XXI, XXV or XXX in which R, R' and R 5 are hydrogen or methyl, B" denotes an alkylene radical with 2-12 C atoms, an alkenylene radical with 4-8 C atoms, a xylylene or hexahydroxylylene radical, a cyclohexylene radical or a radical of the formula --CH 2 CH 2 OCH 2 CH 2 -- or --CH 2 CH 2 O--phenylene-OCH 2 CH 2 -- and Z 2 , Z 5 and Z 6 have the meaning given in claim 5.

Claim 18

A polyester according to claim 6 of the general formula II, in which -X-D-CO- represents a radical of the formula L, LV, LVI or LVII, in which R, R 3 and R 5 are hydrogen or methyl, m is 1 or 2, Z denotes a direct bond and Z 12 represents, 1,2-ethylene, 1,3-propylene, vinylene or o-phenylene.

Claim 19

A plastic stabilised against photodegradation which contains 0.005 to 5% by weight of at least one polyester of claim 1.

Claim 20

A stabilised plastic according to claim 17 which contains 0.01 to 1% by weight of the polymeric stabilizer.

Claim 21

A plastic according to claim 17 or 18 in which the plastic is selected from the group consisting of polyolefine, styrene polymer, polyurethane or polyamide.

Claim 22

A stabilised plastic according to claim 18 which contains 0.02 to 0.5% by weight of the polymeric stabiliser.