← Back to Patent Explorer
US4218283A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for fabricating semiconductor device and etchant for polymer resin

Assignee: Hitachi Ltd
•
Filing: 1978-07-12
•
Granted: 1980-08-19
•
Expires: 1998-07-12
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A semiconductor device fabricated by forming a layer of cured polyimide resin on a semiconductor body, forming a photoresist layer having a prescribed pattern on said cured layer, immersing in an etchant consisting of hydrazine and ethylenediamine to said cured layer through said prescribed pattern, whereby said cured layer is precisely etched according to said prescribed pattern and prescribed surfaces of said semiconductor body are exposed, forming a metal layer on the surface of said polyimide and the prescribed surfaces of said body, and selectively etching said metal layer so as to form a prescribed pattern.

Inventors

  • 👤 Atsushi Saiki
  • 👤 Toshio Okubo
  • 👤 Seiki Harada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:17
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/68; H10P14/683; H10P14/65; H10P14/6516; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081; H10W20/082; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/032; H05K1/0346; H05K3/00; H05K3/0011; H05K3/0017

Claims Analysis

Total Claims: 57
Claim 1
Independent Claim 102 words
A method for fabricating a semiconductor device comprising the steps of: forming, on a body, a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C.; and contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to a prescribed portion of said cured layer so as to form an opening at said prescribed portion.
Claim 2
Independent Claim 102 words
A method for fabricating a semiconductor device comprising the steps of: forming, on a body, a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C.; and contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to a prescribed portion of said cured layer so as to form an opening at said prescribed portion.
Claim 3
Dependent Claim 29 words
A method for fabricating a semiconductor device according to claim 1, wherein the volume % of said at least one polyamine in said etchant is between 30% and 50%.
Claim 4
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 1, wherein the cured polymer resin layer is a cured polyimide resin layer.
Claim 5
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 1, wherein the cured polymer resin layer is a cured polyimide-iso-indroquinazolinedione resin layer.
Claim 6
Dependent Claim 38 words
A method for fabricating a semiconductor device according to claim 1, wherein said etchant consists essentially of hydrazine and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms.
Claim 7
Dependent Claim 26 words
A method for fabricating a semiconductor device according to claim 5, wherein the volume % of said polyamine in said etchant is between 30% and 50%.
Claim 8
Dependent Claim 16 words
A method for fabricating a semiconductor device according to claim 6, wherein said polyamine is ethylenediamine.
Claim 9
Dependent Claim 27 words
A method for fabricating a semiconductor device according to claim 5, wherein said polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine and hexamethylenediamine.
Claim 10
Dependent Claim 16 words
A method for fabricating a semiconductor device according to claim 8, wherein said polyamine is ethylenediamine.
Claim 11
Dependent Claim 55 words
A method for fabricating a semiconductor device according to claim 5, wherein said etchant consists of an aqueous solution of hydrazine and polyamine shown by a chemical formula of: NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine and polyamine, balance water.
Claim 12
Dependent Claim 27 words
A method for fabricating a semiconductor device according to claim 10, wherein said polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine and hexamethylenediamine.
Claim 13
Dependent Claim 16 words
A method for fabricating a semiconductor device according to claim 11, wherein said polaymine is ethylenediamine.
Claim 14
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 10, wherein the volume % of said polyamine is between 30% and 50%.
Claim 15
Dependent Claim 26 words
A method for fabricating a semiconductor device according to claim 10, wherein said solution contains more than 95 volume % of hydrazine and polyamine, balance water.
Claim 16
Dependent Claim 58 words
A method for fabricating a semiconductor device according to claim 1, wherein said etchant consists of an aqueous solution of hydrazine and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine and polyamine, balance water.
Claim 17
Dependent Claim 26 words
A method for fabricating a semiconductor device according to claim 15, wherein said solution contains more than 95 volume % of hydrazine and polyamine, balance water.
Claim 18
Dependent Claim 26 words
A method for fabricating a semiconductor device according to claim 15, wherein the volume % of said at least one polyamine is between 30% and 50%.
Claim 19
Dependent Claim 30 words
A method for fabricating a semiconductor device according to claim 15, wherein said at least one polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, petamethylenediamine and hexamethylenediamine.
Claim 20
Dependent Claim 19 words
A method for fabricating a semiconductor device according to claim 18, wherein said at least one polaymine is ethylenediamine.
Claim 21
Independent Claim 275 words
A method for fabricating a semiconductor device comprising the steps of: forming at least one circuit element in a semiconductor body; forming an insulating layer on the surface of said body; forming at least one opening at prescribed portions of said insulating layer for exposing at least one prescribed surface of said circuit element forming a metal layer on the surface of said at least one surface and on said exposed at least one surface of said circuit element; selectively etching said metal layer for forming a prescribed pattern of said metal layer, whereby prescribed surfaces of said insulating layer are exposed; forming a layer of cured polymer resin selected from the group consisting of polymimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surfaces of said metal layer and exposed surfaces of said insulating layer; forming a photoresist layer on the surface of said cured polymer resin layer; forming a prescribed pattern on said photoresist layer, so that prescribed surfaces of said cured polymer layer are exposed; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to the exposed surface of said polymer layer, so as to etch said polymer layer and to expose prescribed surfaces of said metal layer; removing said photoresist layer; forming another metal layer on the surface of said cured polymer resin layer and exposed surface of said metal layer; and etching said another metal layer so as to form a prescribed pattern.
Claim 22
Independent Claim 275 words
A method for fabricating a semiconductor device comprising the steps of: forming at least one circuit element in a semiconductor body; forming an insulating layer on the surface of said body; forming at least one opening at prescribed portions of said insulating layer for exposing at least one prescribed surface of said circuit element forming a metal layer on the surface of said at least one surface and on said exposed at least one surface of said circuit element; selectively etching said metal layer for forming a prescribed pattern of said metal layer, whereby prescribed surfaces of said insulating layer are exposed; forming a layer of cured polymer resin selected from the group consisting of polymimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surfaces of said metal layer and exposed surfaces of said insulating layer; forming a photoresist layer on the surface of said cured polymer resin layer; forming a prescribed pattern on said photoresist layer, so that prescribed surfaces of said cured polymer layer are exposed; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to the exposed surface of said polymer layer, so as to etch said polymer layer and to expose prescribed surfaces of said metal layer; removing said photoresist layer; forming another metal layer on the surface of said cured polymer resin layer and exposed surface of said metal layer; and etching said another metal layer so as to form a prescribed pattern.
Claim 23
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 20, wherein the cured polymer resin layer is a cured polyimide-iso-indroquinazolinedione resin layer.
Claim 24
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 20, wherein the cured polymer resin layer is a cured polyimide resin layer.
Claim 25
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 20, wherein the volume % of said polyamine is between 30% and 50%.
Claim 26
Independent Claim 179 words
A method for fabricating a semiconductor device comprising the steps of: forming an insulating layer on a surface of a body; forming a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surface of said insulating layer; forming a photoresist layer on the surface of said cured polymer layer; forming a prescribed pattern on said photoresist layer, so that prescribed surfaces of said cured polymer layer are exposed; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to the exposed surface of said polymer layer, so as to etch said polymer layer and to expose prescribed surfaces of said insulating layer; removing said photoresist layer; etching said insulating layer; forming a metal layer on said cured polymer resin layer; and etching said metal layer so as to form a prescribed pattern.
Claim 27
Independent Claim 179 words
A method for fabricating a semiconductor device comprising the steps of: forming an insulating layer on a surface of a body; forming a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surface of said insulating layer; forming a photoresist layer on the surface of said cured polymer layer; forming a prescribed pattern on said photoresist layer, so that prescribed surfaces of said cured polymer layer are exposed; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C., to the exposed surface of said polymer layer, so as to etch said polymer layer and to expose prescribed surfaces of said insulating layer; removing said photoresist layer; etching said insulating layer; forming a metal layer on said cured polymer resin layer; and etching said metal layer so as to form a prescribed pattern.
Claim 28
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 24, wherein the volume % of said polyamine is between 30% and 50%.
Claim 29
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 24, wherein the cured polymer resin layer is a cured polyimide-iso-indroquinazolinedione resin layer.
Claim 30
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 24, wherein the cured polymer resin layer is a cured polyimide resin layer.
Claim 31
Independent Claim 173 words
A method for fabricating a semiconductor device comprising the steps of: forming a first metal layer on an insulating layer; etching said metal layer so as to form a prescribed pattern; forming a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surface of said prescribed pattern and on exposed surfaces of said insulating layer; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C. at prescribed portions of said cured polymer layer, so as to etch said prescribed portions of said cured polymer layer and to expose surfaces of the first metal layer; forming a second metal layer on said cured polymer resin layer and exposed surfaces of said first metal layer; and etching said second metal layer so as to form a prescribed pattern.
Claim 32
Independent Claim 173 words
A method for fabricating a semiconductor device comprising the steps of: forming a first metal layer on an insulating layer; etching said metal layer so as to form a prescribed pattern; forming a layer of cured polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., on the surface of said prescribed pattern and on exposed surfaces of said insulating layer; contacting an etchant consisting essentially of hydrazine or hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, the temperature of said etchant being in a range from 25° C. to 35° C. at prescribed portions of said cured polymer layer, so as to etch said prescribed portions of said cured polymer layer and to expose surfaces of the first metal layer; forming a second metal layer on said cured polymer resin layer and exposed surfaces of said first metal layer; and etching said second metal layer so as to form a prescribed pattern.
Claim 33
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 28, wherein the volume % of said polyamine is between 30% and 50%.
Claim 34
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 28, wherein the cured polymer resin layer is a cured polyimide-iso-indroquinazolinedione resin layer.
Claim 35
Dependent Claim 23 words
A method for fabricating a semiconductor device according to claim 28, wherein the cured polymer resin layer is a cured polyimide resin layer.
Claim 36
Dependent Claim 62 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of hydrazine and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, with the volume % of said at least one polyamine being between 30% and 50%.
Claim 37
Dependent Claim 62 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of hydrazine and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, with the volume % of said at least one polyamine being between 30% and 50%.
Claim 38
Dependent Claim 25 words
An etchant according to claim 32, wherein said at least one polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine and hexamethylenediamine.
Claim 39
Dependent Claim 14 words
An etchant according to claim 33, wherein said at least one polyamine is ethylenediamine.
Claim 40
Dependent Claim 56 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of hydrazine and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, with the volume % of said polyamine being between 30% and 50%.
Claim 41
Dependent Claim 56 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of hydrazine and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, with the volume % of said polyamine being between 30% and 50%.
Claim 42
Dependent Claim 22 words
An etchant according to claim 35, wherein said polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine and hexamethylenediamine.
Claim 43
Dependent Claim 11 words
An etchant according to claim 36, wherein said polyamine is ethylenediamine.
Claim 44
Dependent Claim 67 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of an aqueous solution of hydrazine hydrate and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine hydrate and polyamine, balance water.
Claim 45
Dependent Claim 67 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of an aqueous solution of hydrazine hydrate and at least one polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine hydrate and polyamine, balance water.
Claim 46
Dependent Claim 22 words
An etchant according to claim 38, wherein said solution contains more than 95 volume % of hydrazine hydrate and polyamine, balance water.
Claim 47
Dependent Claim 24 words
An etchant according to claim 38, wherein said at least one polyamine is selected from the group of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine, and hexamethylenediamine.
Claim 48
Dependent Claim 21 words
An etchant according to claim 38, wherein the volume % of said at least one polyamine is between 30% and 50%.
Claim 49
Dependent Claim 14 words
An etchant according to claim 38, wherein said at least one polyamine is ethylenediamine.
Claim 50
Dependent Claim 21 words
An etchant according to claim 42, wherein the volume % of said at least one polyamine is between 30% and 50%.
Claim 51
Dependent Claim 64 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of an aqueous solution of hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine hydrate and polyamine, balance water.
Claim 52
Dependent Claim 64 words
An etchant for a polymer resin selected from the group consisting of polyimide and polyimide-iso-indroquinazolinedione and cured at 260°-450° C., consisting essentially of an aqueous solution of hydrazine hydrate and polyamine shown by a chemical formula of NH.sub.2.R.NH.sub.2 wherein R is selected from divalent radicals having 2-6 carbon atoms, said solution containing more than 90 volume % of hydrazine hydrate and polyamine, balance water.
Claim 53
Dependent Claim 22 words
An etchant according to claim 44, wherein said solution contains more than 95 volume % of hydrazine hydrate and polyamine, balance water.
Claim 54
Dependent Claim 22 words
An etchant according to claim 44, wherein said polyamine is selected from the group consisting of ethylenediamine, trimethylenediamine, tetramethylenediamine, pentamethylenediamine and hexamethylenediamine.
Claim 55
Dependent Claim 18 words
An etchant according to claim 46, wherein the volume % of said polyamine is between 30% and 50%.
Claim 56
Dependent Claim 11 words
An etchant according to claim 46, wherein said polyamine is ethylenediamine.
Claim 57
Dependent Claim 18 words
An etchant according to claim 48, wherein the volume % of said ethylenediamine is between 30% and 50%.

References Cited (Backward Citations)

US3395057A Cited
US3700497A Cited
US4113550A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-19 1984-02-18 1984-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-19 1988-02-18 1988-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-19 1992-02-18 1992-08-19 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag