Diethylene glycol bis(allyl carbonate) compositions containing crosslinkable copolymers

Claim 2

A composition consisting essentially of 25 to 99 percent by weight of diethylene glycol bis(allyl carbonate) monomer, and 1 to 75 percent by weight of a copolymer having a molecular weight of 1,000 to 100,000 prepared by reacting (i) at least one allyl ester, substituted allyl ester, N-allyl substituted amide or N-N-diallyl substituted amide of an α-B unsaturated carboxylic or dicarboxylic lic acid; or an allyl substituted monovinyl aromatic compound. (ii) at least one lower alkyl methacrylate, optionally together with a minor amount of one or more vinyl or vinylidene monomers which are polymerizable by a free radical mechanism.

Claim 3

A composition consisting essentially of 25 to 99 percent by weight of diethylene glycol bis-(allyl carbonate) monomer, 1 to 75 percent by weight of a copolymer having a molecular weight of 1,000 to 100,000 prepared by reacting (i) at least one compound having the formula ##STR11## Z is ##STR12## or A-R 4 where R 4 is aryl of 6 to 15 carbons; When Z is A-R 4 , Y is hydrogen and R is hydrogen or CH 3 --; When Z is ##STR13## Y is hydrogen or ##STR14## and R is hydrogen, CH 3 --, or ##STR15## where A is ##STR16## R 2 is hydrogen or CH 3 ; X is --O-- or ##STR17## R 3 is A, hydrogen, alkyl of 1 to 10 carbons, aryl of 6 to 12 carbons, cycloalkyl of 3 to 12 carbons or aralkyl of 7 to 15 carbons; R 1 is A or R 3 with the proviso that when Y is ##STR18## R is hydrogen and when R is ##STR19## Y is hydrogen; and (ii) at least one lower alkyl methacrylate, optionally together with a minor amount of one or more monomers selected from: α-β unsaturated carboxylic or dicarboxylic acids, their esters or anhydrides, vinyl aromatics, dienes, vinyl esters, vinyl chloride, vinylidene chloride, acrylonitrile or methacrylonitrile.

Claim 4

A composition consisting essentially of 25 to 99 percent by weight of diethylene glycol bis-(allyl carbonate) monomer, 1 to 75 percent by weight of a copolymer having a molecular weight of 1,000 to 100,000 prepared by reacting (i) at least one compound having the formula ##STR11## Z is ##STR12## or A-R 4 where R 4 is aryl of 6 to 15 carbons; When Z is A-R 4 , Y is hydrogen and R is hydrogen or CH 3 --; When Z is ##STR13## Y is hydrogen or ##STR14## and R is hydrogen, CH 3 --, or ##STR15## where A is ##STR16## R 2 is hydrogen or CH 3 ; X is --O-- or ##STR17## R 3 is A, hydrogen, alkyl of 1 to 10 carbons, aryl of 6 to 12 carbons, cycloalkyl of 3 to 12 carbons or aralkyl of 7 to 15 carbons; R 1 is A or R 3 with the proviso that when Y is ##STR18## R is hydrogen and when R is ##STR19## Y is hydrogen; and (ii) at least one lower alkyl methacrylate, optionally together with a minor amount of one or more monomers selected from: α-β unsaturated carboxylic or dicarboxylic acids, their esters or anhydrides, vinyl aromatics, dienes, vinyl esters, vinyl chloride, vinylidene chloride, acrylonitrile or methacrylonitrile.

Claim 5

The composition of claim 2 wherein the copolymer is methyl methacrylate-allyl methacrylate copolymer.

Claim 6

The composition of claim 2 wherein the copolymer is methyl methacrylate-allyl methacrylate-maleic anhydride terpolymer.

Claim 7

The composition of claim 2 wherein the copolymer is methyl methacrylate-allyl methacrylate-styrene terpolymer.

Claim 8

The composition of claim 2 wherein (i) is at least one of the members selected from the group consisting of allyl methacrylate, allyl itaconate, diallyl itaconate, allyl acrylamide, diallyl acrylamide, allyl maleate, diallyl maleate, allyl fumarate and diallyl fumarate.

Claim 9

The composition of claim 2 wherein (ii) is a lower alkyl methacrylate, optionally together with a minor amount of one of the members selected from the group consisting of styrene, vinyl toluene, p-methoxystyrene, vinyl cyclohexane, chloro-, fluoro- or bromo styrene, vinyl chloride, vinylidene chloride, tetrafluoroethylene, acrylic acid, methacrylic acid, vinyl acetate, vinyl propionate, vinyl stearate, isoprene, butadiene, chloroprene, maleic anhydride, acrylonitrile and methacrylonitrile.

Claim 10

A process for the preparation of a casting comprising curing the composition of claim 2.

Claim 11

The optical clear, reduced shrinkage, product prepared by the process of claim 8.