US4198331A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Resinous coating compositions curable by Michael adduct exchange
Assignee: PPG Industries Inc
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Filing: 1978-08-28
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Granted: 1980-04-15
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Expires: 1998-08-28
Abstract
Abstract Curable resinous compositions containing primary and/or secondary amine groups which are non-volatile under curing conditions and containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties which are reacted with a primary and/or secondary amine which are volatile under curing conditions are disclosed. The compositions are depositable on a substrate to form films.
Inventors
- 👤 Stephen L. Buchwalter
- 👤 Robert D. Jerabek
- 👤 Lee-Pei H. Chou
- 👤 Roger M. Christenson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 19:06
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/14; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/50; C09D133/24; C09D133/26; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4453; C08L; C08L63/00
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
74 words
A curable resinous composition comprising: (A) a polyamine resin containing primary and/or secondary amino groups, said resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous composition being depositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 2
Dependent Claim
74 words
A curable resinous composition comprising: (A) a polyamine resin containing primary and/or secondary amino groups, said resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous composition being depositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 3
Dependent Claim
20 words
The resinous composition of claim 1 in which a portion of the amine groups are converted to cationic salt groups.
Claim 4
Dependent Claim
12 words
The resinous composition of claim 2 which is dispersed in aqueous medium.
Claim 5
Dependent Claim
101 words
A curable resinous coating composition dispersible in aqueous medium with the aid of cationic salt groups comprising as the resinous binder: (A) a polyamine resin containing primary and/or secondary amino groups, said resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous binder being neutralized with acid to provide said cationic salt groups and being electrodepositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 6
Dependent Claim
101 words
A curable resinous coating composition dispersible in aqueous medium with the aid of cationic salt groups comprising as the resinous binder: (A) a polyamine resin containing primary and/or secondary amino groups, said resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous binder being neutralized with acid to provide said cationic salt groups and being electrodepositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 7
Dependent Claim
22 words
The resinous compositions of claims 1 or 4 in which the polyamine resin is a poly(amine-amide) having a terminal primary amine group.
Claim 8
Dependent Claim
26 words
The resinous compositions of claims 1 or 4 in which the polyamine resin is the reaction product of an epoxy-containing resinous material and a primary amine.
Claim 9
Dependent Claim
30 words
The resinous composition of claims 1 or 4 in which the polyamine resin is the reaction product of an epoxy-containing resinous material and a polyamine containing ketimine-blocked primary amine groups.
Claim 10
Dependent Claim
32 words
The resinous compositions of claims 1 or 4 in which (B) is formed from reacting an organic polyol with acrylic or methacrylic acid followed by reaction with a primary and/or secondary amine.
Claim 11
Dependent Claim
33 words
The resinous composition of claims 1 or 4 in which (B) is formed from reacting an epoxy-containing resinous material with acrylic or methacrylic acid followed by reaction with a primary and/or secondary amine.
Claim 12
Dependent Claim
33 words
The resinous compositions of claims 1 or 4 in which (B) is formed from reacting a polymeric polyol with an N-alkoxymethyl-containing acrylamide or methacrylamide followed by reaction with a primary and/or secondary amine.
Claim 13
Dependent Claim
69 words
A curable resinous composition comprising a polyamine resin containing: (A) primary and/or secondary amino groups which are non-volatile under curing conditions; and (B) amine groups which are formed by reacting alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties with primary and/or secondary amines which are volatile under curing conditions; said resinous composition being depositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 14
Dependent Claim
69 words
A curable resinous composition comprising a polyamine resin containing: (A) primary and/or secondary amino groups which are non-volatile under curing conditions; and (B) amine groups which are formed by reacting alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties with primary and/or secondary amines which are volatile under curing conditions; said resinous composition being depositable on a substrate to form a film thereon which is curable at elevated temperatures.
Claim 15
Dependent Claim
20 words
The resinous composition of claim 11 in which a portion of the amine groups are converted to cationic salt groups.
Claim 16
Dependent Claim
12 words
The resinous composition of claim 12 which is dispersed in aqueous medium.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-15 | 1983-10-15 | 1984-04-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-15 | 1987-10-15 | 1988-04-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-15 | 1991-10-15 | 1992-04-15 | $7700.00 | Window Closed / Lapsed |