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US4194041A Expired / Lapsed US ⏱️ 0.0 years remaining

Waterproof laminate

Assignee: W.L. Gore and Associates Inc
•
Filing: 1978-06-29
•
Granted: 1980-03-18
•
Expires: 1998-06-29
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Abstract

Abstract A waterproof article for use in, for example, protective clothing. The article prevents liquid water from penetrating through to undergarments while at the same time permitting moisture vapor such as perspiration to pass out through the article. The article is thus both breathable and waterproof. The article is layered: a microporous hydrophobic outer layer which permits the passage of moisture vapor but resists penetration by liquid water at pressures up to about 345 Kn/m2; a hyrophilic inner layer permitting the transfer of moisture vapor but preventing surface tension lowering agents such as those contained in perspiration and/or body oils from reaching the hydrophobic layer.

Inventors

  • 👤 Robert W. Gore
  • 👤 Samuel B. Allen, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-22 15:54
CPC Classifications
B; B32; B32B; B32B5/00; B32B5/18; B32B3/00; B32B3/26; A; A41; A41D; A41D31/00; A41D31/04; A41D31/10; A41D31/102; B32B27/00; B32B27/06; B32B27/08; B32B27/28; B32B27/30; B32B27/32; B32B27/40; D; D06; D06N; D06N3/00; D06N3/12; D06N3/14; D06N3/18; D06N3/183; B32B2250/00; B32B2250/24; B32B2305/00; B32B2305/02; B32B2305/026; B32B2307/00; B32B2307/50; B32B2307/554; B32B2307/70; B32B2307/724; B32B2307/726; B32B2307/7265; B32B2307/728; B32B2307/73; B32B2323/00; B32B2323/10; B32B2375/00; B32B2437/00; B32B2571/00; Y; Y10; Y10S; Y10S2/00; Y10S2/01; Y10S2/05; Y10S5/00; Y10S5/939; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249953; Y10T428/249978; Y10T428/249981; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31551; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31899; Y10T428/31902; Y10T428/31909; Y10T428/31913; Y10T428/31938; Y10T442/00; Y10T442/30; Y10T442/3854; Y10T442/3878

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 146 words
A flexible layered article suitable for use in waterproof garments, or tents, which permits transfer of water vapor to prevent the build-up of moisture, the layered article retaining its resistance to transmission of liquid water even when the interior face of the article is exposed to a surface tension lowering agent, such as perspiration and body oils, comprising: (a) a flexible, first layer of hydrophobic material having a moisture vapor transmission rate exceeding 1000 gms./m 2 . day and an advancing water contact angle exceeding 90 degrees; and (b) a continuous hydrophilic layer attached to the inner face of said first layer, said hydrophilic layer having a moisture vapor transmission rate exceeding 1000 gms./m 2 . day and forming a barrier to passage of a surface tension lowering agent that would if present in said first layer tend to reduce the waterproofness of said first layer.
Claim 2
Dependent Claim 146 words
A flexible layered article suitable for use in waterproof garments, or tents, which permits transfer of water vapor to prevent the build-up of moisture, the layered article retaining its resistance to transmission of liquid water even when the interior face of the article is exposed to a surface tension lowering agent, such as perspiration and body oils, comprising: (a) a flexible, first layer of hydrophobic material having a moisture vapor transmission rate exceeding 1000 gms./m 2 . day and an advancing water contact angle exceeding 90 degrees; and (b) a continuous hydrophilic layer attached to the inner face of said first layer, said hydrophilic layer having a moisture vapor transmission rate exceeding 1000 gms./m 2 . day and forming a barrier to passage of a surface tension lowering agent that would if present in said first layer tend to reduce the waterproofness of said first layer.
Claim 3
Dependent Claim 34 words
The layered article of claim 1 in which said hydrophilic layer does not permit detectable passage of liquid water therethrough at a pressure of at least about 25 cm water head for 20 minutes.
Claim 4
Dependent Claim 37 words
The layered article of claim 1 in which said hydrophilic layer does not permit detectable passage of liquid water therethrough at pressures of between about 25 cm water head and about 172 kN/M 2 for 30 seconds.
Claim 5
Dependent Claim 31 words
The layered article of claim 1 in which said hydrophilic layer does not permit detectable passage of liquid water therethrough at a pressure of about 172 kN/M 2 for 30 seconds.
Claim 6
Dependent Claim 19 words
The layered article of claim 1 in which said hydrophobic layer is in laminar contact with said hydrophilic layer.
Claim 7
Dependent Claim 13 words
The layered article of claim 1 in which said hydrophobic layer is microporous.
Claim 8
Dependent Claim 14 words
The layered article of claim 1 in which said hydrophobic layer is porous polytetrafluoroethylene.
Claim 9
Dependent Claim 15 words
The layered article of claim 1 in which said hydrophilic layer is impermeable to air.
Claim 10
Dependent Claim 15 words
The layered article of claim 1 in which said hydrophilic layer is impermeable to air.
Claim 11
Dependent Claim 14 words
The layered article of claim 1 in which said hydrophilic layer is a polyether-polyurethane.
Claim 12
Dependent Claim 16 words
The layered article of claim 1 in which said hydrophilic layer is a perfluorosulphonic acid membrane.
Claim 13
Dependent Claim 45 words
The layered article of claim 1 in which said hydrophilic layer has a moisture vapor transmission rate above 2000 gms./m 2 . day and no detectable transmission rate for liquid water at hydrostatic pressures of at least about 25 cm water head for 20 minutes.
Claim 14
Dependent Claim 49 words
The layered article of claim 1 in which said hydrophilic layer has a moisture vapor transmission rate above 2000 gms./m 2 . day and no detectable transmission rate for liquid water at hydrostatic pressures of between about 25 cm water head and about 172 kN/M 2 for 30 seconds.
Claim 15
Dependent Claim 42 words
The layered article of claim 1 in which said hydrophilic layer has a moisture vapor transmission rate above 2000 gms./m 2 . day and no detectable transmission rate for liquid water at hydrostatic pressures of about 172 kN/M 2 for 30 seconds.
Claim 16
Dependent Claim 28 words
The layered article of claim 1 in which a wear-resistant textile layer is attached to the outer face of said hydrophobic layer and aligned in laminar relationship therewith.
Claim 17
Dependent Claim 27 words
The layered article of claim 15 in which a textile layer is attached to the inner face of said hydrophilic layer and aligned in laminar relationship therewith.
Claim 18
Dependent Claim 25 words
The layered article of claim 15 in which said hydrophobic layer is in laminar contact with both said hydrophilic layer and said wear-resistant textile layer.
Claim 19
Dependent Claim 19 words
The layered article of claim 17 in which a textile layer is in laminar contact with said hydrophilic layer.
Claim 20
Dependent Claim 23 words
The layered article of claim 1 in which said hydrophilic layer has a moisture vapor transmission rate above 2000 gms./m 2 . day.
Claim 21
Dependent Claim 19 words
The layered article of claim 19 in which said hydrophobic layer is in laminar contact with said hydrophilic layer.
Claim 22
Dependent Claim 27 words
The layered article of claim 19 in which a textile layer is attached to the inner face of said hydrophilic layer and aligned in laminar relationship therewith.
Claim 23
Dependent Claim 14 words
The layered article of claim 19 in which said hydrophilic layer is a polyether-polyurethane.
Claim 24
Dependent Claim 16 words
The layered article of claim 19 in which said hydrophilic layer is a perfluorosulphonic acid membrane.
Claim 25
Dependent Claim 13 words
The layered article of claim 19 in which said hydrophobic layer is microporous.
Claim 26
Dependent Claim 14 words
The layered article of claim 19 in which said hydrophobic layer is porous polytetrafluoroethylene.
Claim 27
Dependent Claim 28 words
The layered article of claim 19 in which a wear-resistant textile layer is attached to the outer face of said hydrophobic layer and aligned in laminar relationship therewith.
Claim 28
Dependent Claim 25 words
The layered article of claim 26 in which said hydrophobic layer is in laminar contact with both said hydrophilic layer and said wear-resistant textile layer.
Claim 29
Dependent Claim 19 words
The layered article of claim 27 in which a textile layer is in laminar contact with said hydrophilic layer.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-03-18 1983-09-17 1984-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-03-18 1987-09-17 1988-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-03-18 1991-09-17 1992-03-18 $7700.00 Window Closed / Lapsed

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