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US4184099A Expired / Lapsed US ⏱️ 0.0 years remaining

Composition for slow release of volatile ingredients at _high temperature; and article comprising same

Assignee: International Flavors and Fragrances Inc
•
Filing: 1978-06-08
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Granted: 1980-01-15
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Expires: 1998-06-08
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Abstract

Abstract Bodies which are formed compositions of Versalon® type polyamide resin containing from about 35% up to about 70% by weight of highly volatile materials such as perfumes, odorants, insecticides, bactericides, and animal repellents which are able to act in a very diluted vapor state in the air for relatively long periods of time, are described. The highly volatile substances are released in a controlled manner over a long period of time. The molecular weight of the resin is between 9,000 and 12,000, and its softening point varies from 120° C. up to 400° C. In addition, articles are described incorporating said composition and, as part of the instant invention, a light bulb coated with a toroidal article which consists essentially of said composition, is included. The method of our invention comprises heating Versalon® polyamide resin (Note 1) having a molecular weight of from 9,000 up to 12,000 until it is pourable and stirrable, e.g., to a temperature of between 120° C. and 400° C., and then blending from 35 up to 70% of a highly volatile ingredient such as a perfume oil, an insecticide composition, a bactericide composition, or an animal repellent composition, into the melt until a uniform mixture is obtained, and cooling the mixture to solidify it as such or in a toroidal state, preferably rapidly as by quenching in cold water. The product so obtained is then formed into an article such as a coating on a substrate such as an electric light bulb. Alternatively, one or more volatile ingredients are blended into the resin in the feed line of a molding machine in which the resin bodies containing said volatile ingredients are fashioned directly. Minneapolis, Minnesota.

Inventors

  • 👤 Jerome I. Lindauer
  • 👤 Marina Munteanu
  • 👤 Sharon Reich
  • 👤 Enrique Pelliza

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:20
CPC Classifications
A; A01; A01M; A01M1/00; A01M1/20; A01M1/2022; A01M1/2061; A01M1/2083; A01N; A01N25/00; A01N25/08; A01N25/10; A01N25/18; A61; A61L; A61L9/00; A61L9/015; A61L9/02; A61L9/03; A61L9/04; A61L9/042; A61L2209/00; A61L2209/10; A61L2209/12

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 189 words
A co-solvent free, alcohol free thermoplastic polyamide resin body consisting essentially of from 35% up to 70% by weight of said polyamide resin body of a volatile substance selected from the group consisting of perfume oils, insecticides, odorants, bactericides and animal repellents, the remainder of said thermoplastic polyamide resin body being a fatty polyamide which is a reaction product of ethylene diamine and polymeric fat acids at temperatures in the range of 150°-300° C. employing essentially 1 molar equivalent of amine per molar equivalent of carboxyl group, said polymeric fat acids being polymerized monocarboxylic aliphatic acids having from 8 to 24 carbon atoms, and said polymeric fat acids having a dimeric fat acid content and a ratio of trimeric: monomeric fat acids defined substantially within the area ABC of FIG. 5, said fatty polyamide softening in the range of 10°-15° C. on being heated within the range of 120° C. up to 400° C. and having a sharp decrease in viscosity at temperatures above its softening range, said fatty polyamide having a molecular weight within the range between about 9,000 and 12,000, said resin body being a solid solution.
Claim 2
Dependent Claim 189 words
A co-solvent free, alcohol free thermoplastic polyamide resin body consisting essentially of from 35% up to 70% by weight of said polyamide resin body of a volatile substance selected from the group consisting of perfume oils, insecticides, odorants, bactericides and animal repellents, the remainder of said thermoplastic polyamide resin body being a fatty polyamide which is a reaction product of ethylene diamine and polymeric fat acids at temperatures in the range of 150°-300° C. employing essentially 1 molar equivalent of amine per molar equivalent of carboxyl group, said polymeric fat acids being polymerized monocarboxylic aliphatic acids having from 8 to 24 carbon atoms, and said polymeric fat acids having a dimeric fat acid content and a ratio of trimeric: monomeric fat acids defined substantially within the area ABC of FIG. 5, said fatty polyamide softening in the range of 10°-15° C. on being heated within the range of 120° C. up to 400° C. and having a sharp decrease in viscosity at temperatures above its softening range, said fatty polyamide having a molecular weight within the range between about 9,000 and 12,000, said resin body being a solid solution.
Claim 3
Dependent Claim 15 words
The polyamide resin body of claim 1 wherein the volatile substance is a perfume oil.
Claim 4
Dependent Claim 15 words
The polyamide resin body of claim 1 wherein the volatile substance is an animal repellent.
Claim 5
Dependent Claim 14 words
The polyamide resin body of claim 1 wherein the volatile substance is an insecticide.
Claim 6
Dependent Claim 17 words
The polyamide resin body of claim 1 in which the resin is a coating on a substrate.
Claim 7
Dependent Claim 20 words
The polyamide resin body of claim 5 in which the substrate is in the form of an electric light bulb.
Claim 8
Dependent Claim 15 words
The polyamide resin body of claim 6 wherein the volatile substance is a perfume oil.
Claim 9
Dependent Claim 15 words
The polyamide resin body of claim 6 wherein the volatile substance is an animal repellent.
Claim 10
Dependent Claim 19 words
The polyamide resin body of claim 6 wherein the volatile substance is a mixture of insecticide and perfume oil.
Claim 11
Dependent Claim 19 words
The polyamide resin body of claim 1 wherein the volatile substance is a mixture of insecticide and perfume oil.
Claim 12
Dependent Claim 20 words
The spherical light bulb having fixedly coated thereon a toroid consisting of the thermoplastic polyamide resin body of claim 1.
Claim 13
Dependent Claim 25 words
A spherical light bulb having fixedly coated thereon a toroid consisting of the thermoplastic resin body of any of claims 2, 3, 4 or 10.

References Cited (Backward Citations)

FR1176992A Cited
US3148125A Cited
US3303046A Cited
US3396180A Cited
US3474176A Cited
US3763347A Cited
US3725311A Cited
US3926655A Cited
US4051159A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-01-14 1983-07-16 1984-01-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-01-14 1987-07-16 1988-01-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-01-14 1991-07-16 1992-01-15 $7700.00 Window Closed / Lapsed

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