US4143218A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymeric materials
Assignee: UK Secretary of State for Defence
•
Filing: 1977-09-12
•
Granted: 1979-03-06
•
Expires: 1997-09-12
Abstract
Abstract A method of treating a hydrophilic polymer film is described in which the film is immersed at a temperature greater than 80° C., and preferably greater than the crystalline melting point of the polymer, in a liquid capable of swelling the polymer. Polymers to which this method can be applied include graft copolymers of for example polyethylene, polypropylene, polytetrafluoroethylene, and nylon with acrylic or methacrylic acid. The films when treated have decreased electrical resistance and increased hydroxyl ion permeability and are then useful as battery separators and in other semi permeable membrane applications.
Inventors
- 👤 Lionel B. Adams
- 👤 Keith V. Lovell
- 👤 Gordon Partridge
- 👤 Barbara J. Ringrose
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 12:13
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0083; B01D67/0088; C; C08; C08J; C08J7/00; C08J7/02; C08J2351/00
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
119 words
A method of treating a film of hydrophilic polymeric material selected from graft copolymers in which a hydrophilic comonomer is grafted on to a hydrophobic base polymer, sulphonated polymers, and polymers containing a quaternary ammonium group, which includes the steps of a. immersing, at a temperature in excess of 80° C., said film of polymeric material in a liquid treatment material consisting of a liquid which is mainly organic and contains hydroxyl groups or ions and is capable of swelling the said hydrophilic polymeric material, and b. removing the liquid treatment medium by quenching the said film to about room temperature and washing the said polymeric film in a wash liquid selected from cold water or dilute alkaline solution.
Claim 2
Independent Claim
119 words
A method of treating a film of hydrophilic polymeric material selected from graft copolymers in which a hydrophilic comonomer is grafted on to a hydrophobic base polymer, sulphonated polymers, and polymers containing a quaternary ammonium group, which includes the steps of a. immersing, at a temperature in excess of 80° C., said film of polymeric material in a liquid treatment material consisting of a liquid which is mainly organic and contains hydroxyl groups or ions and is capable of swelling the said hydrophilic polymeric material, and b. removing the liquid treatment medium by quenching the said film to about room temperature and washing the said polymeric film in a wash liquid selected from cold water or dilute alkaline solution.
Claim 3
Dependent Claim
28 words
A method as claimed in claim 1 and wherein the temperature of the liquid treatment material is above the crystalline melting point of the said hydrophilic polymeric material.
Claim 4
Dependent Claim
24 words
A method as claimed in claim 1 and wherein the liquid treatment material is selected from alkanols, polyhydric alcohols, ethylene glycols and polyethylene glycols.
Claim 5
Dependent Claim
22 words
A method as claimed in claim 3 and wherein the heat treatment material is selected from glycerol, diethylene glycol and polyethylene glycol.
Claim 6
Dependent Claim
28 words
A method as claimed in claim 3 and wherein the liquid treatment material also contains up to 5% molar of an alkali metal or alkaline earth metal hydroxide.
Claim 7
Dependent Claim
16 words
A method as claimed in claim 5 and wherein the alkali metal hydroxide is potassium hydroxide.
Claim 8
Dependent Claim
12 words
A battery separator comprising the product of the process of claim 1.
Claim 9
Independent Claim
154 words
A method of treating a film of hydrophilic polymeric material which includes the steps of a. immersing, at a temperature in excess of 80° C., the said film of polymeric material in a liquid treatment material consisting of a liquid which is mainly organic and contains hydroxyl groups or ions and is capable of swelling the said hydrophilic polymeric material, and b. removing the liquid treatment medium by quenching the said film to about room temperature and washing the said polymeric film in a wash liquid selected from cold water or dilute alkaline solution, wherein the hydrophilic polymeric material is graft copolymer in which a hydrophilic comonomer is grafted on to a hydrophobic base polymer, and the said base polymer being selected from polyolefins, copolyolefins, condensation polymers, and mixtures thereof, and the hydrophilic comonomer is selected from ethylenic carboxylic acids, ethylenic carboxylic acid amides, ethylenic carboxylic acid amines, and organic bases capable of quaternization.
Claim 10
Independent Claim
154 words
A method of treating a film of hydrophilic polymeric material which includes the steps of a. immersing, at a temperature in excess of 80° C., the said film of polymeric material in a liquid treatment material consisting of a liquid which is mainly organic and contains hydroxyl groups or ions and is capable of swelling the said hydrophilic polymeric material, and b. removing the liquid treatment medium by quenching the said film to about room temperature and washing the said polymeric film in a wash liquid selected from cold water or dilute alkaline solution, wherein the hydrophilic polymeric material is graft copolymer in which a hydrophilic comonomer is grafted on to a hydrophobic base polymer, and the said base polymer being selected from polyolefins, copolyolefins, condensation polymers, and mixtures thereof, and the hydrophilic comonomer is selected from ethylenic carboxylic acids, ethylenic carboxylic acid amides, ethylenic carboxylic acid amines, and organic bases capable of quaternization.
Claim 11
Dependent Claim
42 words
A method as claimed in claim 8 and wherein the said base polymer is selected from low, medium and high density polyethylene, polypropylene, poly-4-methylpentene-1, polyvinylacetate, polyvinylalcohol, polyvinylchloride, chlorinated rubber, polytetrafluoroethylene, polychlorofluoroethylene, polyamides, copolyamides, saturated and unsaturated polyesters, and mixtures and copolymers thereof.
Claim 12
Dependent Claim
31 words
A method as claimed in claim 8 and wherein the said hydrophilic copolymer is selected from acrylic acid, metacrylic acid, itaconic acid, acrylamide methacrylamide, butylamine acrylate, vinyl pyridine and vinyl pyrrolidone.
Claim 13
Dependent Claim
39 words
A method as claimed in claim 8 and wherein the said base polymer is selected from low, medium and high density polyethylene, polypropylene, polytetrafluoroethylene and polyamides and the said hydrophilic comonomer is selected from acrylic acid and methyacrylic acid.
Claim 14
Dependent Claim
28 words
A method as claimed in claim 8 and wherein the temperature of the liquid treatment material is above the crystalline melting point of the said hydrophilic polymeric material.
Claim 15
Dependent Claim
24 words
A method as claimed in claim 8 and wherein the liquid treatment material is selected from alkanols, polyhydric alcohols, ethylene glycols and polyethylene glycols.
Claim 16
Dependent Claim
22 words
A method as claimed in claim 13 and wherein the heat treatment material is selected from glycerol, diethylene glycol and polyethylene glycol.
Claim 17
Dependent Claim
28 words
A method as claimed in claim 13 and wherein the liquid treatment material also contains up to 5% molar of an alkali metal or alkaline earth metal hydroxide.
Claim 18
Dependent Claim
94 words
A process for decreasing the electrical resistance, increasing the hydroxyl ion permeability, increasing the rate of wetting out and increasing the equilibrium water content of a cross-linked polymer film which comprises immersing a graft copolymer film in which the graft copolymer has been prepared by grafting a hydrophilic comonomer onto a hydrophobic base polymer, sulfonated polymer or a polymer containing a quaternary ammonium group at a temperature above 80° C. in a polyhydric alcohol, cooling the film to about room temperature and washing the film with cold water or a dilute aqueous alkaline solution.
Claim 19
Dependent Claim
94 words
A process for decreasing the electrical resistance, increasing the hydroxyl ion permeability, increasing the rate of wetting out and increasing the equilibrium water content of a cross-linked polymer film which comprises immersing a graft copolymer film in which the graft copolymer has been prepared by grafting a hydrophilic comonomer onto a hydrophobic base polymer, sulfonated polymer or a polymer containing a quaternary ammonium group at a temperature above 80° C. in a polyhydric alcohol, cooling the film to about room temperature and washing the film with cold water or a dilute aqueous alkaline solution.
References Cited (Backward Citations)
US3035110A
Cited
US3427206A
Cited
US3497072A
Cited
US3536796A
Cited
US3892594A
Cited
US3720321A
Cited
US3912834A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-03-05 | 1982-09-04 | 1983-03-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-05 | 1986-09-04 | 1987-03-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-05 | 1990-09-04 | 1991-03-06 | $7700.00 | Window Closed / Lapsed |