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US4129423A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable liquid abrasive composition suitable for removing manganese-ion derived discolorations from hard surfaces

Assignee: Lever Brothers Co
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Filing: 1977-04-22
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Granted: 1978-12-12
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Expires: 1997-04-22
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Abstract

Abstract Pourable, stable, liquid, abrasive compositions capable of removing manganese-ion derived discolorations from hard surfaces comprising a solid phase homogeneously dispersed and stabilized within an aqueous liquid phase are disclosed. Said solid phase comprises a water insoluble abrasive material. Said liquid phase comprises a stabilizing mixture, of a tertiary mixture of synthetic anionic surfactant, soap, and a nonionic surfactant, and an electrolyte system, said system comprising a stain removing amount of at least one electrolyte selected from the group consisting of an alkali metal salt of dihydroxy maleic acid, an alkali metal salt of dihydroxy tartaric acid, and mixtures thereof.

Inventors

  • 👤 Fred K. Rubin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 10:28
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086; C11D17/00; C11D17/0008; C11D17/0013

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 249 words
A pourable liquid, abrasive, stain removing composition, comprising: (A) a solid phase, comprising about 5 to about 65 percent, by weight of said composition, of a substantially water insoluble, abrasive material selected from the group consisting of calcite, dolomite, feldspar, silica flour, quartz, pumice, polishing clays and mixtures thereof, dispersed and suspended in; (b) a stabilizing aqueous liquid phase, comprising (i) about 1 to about 20 percent of a tertiary surfactant mixture, said mixture consisting essentially of: (a) about 0.25 to about 10 percent, by weight of said composition, of an alkylaryl sulphonate synthetic anionic surfactant; (b) about 0.25 to about 10 percent, by weight of said composition, of a soap wherein said soap is an alkali metal salt of a ten to twenty-two carbon fatty acid; and (c) about 0.50 to about 10 percent by weight of said composition, of a fatty acid alkanolamide, nonionic surfactant wherein the fatty acid moiety of said amide contains about 8 to about 18 carbon atoms; wherein the ratio of said soap to said synthetic anionic in said mixture is about 1:3.2 to about 1:0.8, and wherein the ratio of said synthetic anionic surfactant plus said soap to said nonionic surfactant is about 0.6:1 to about 1:0.9; and (ii) about 3 to about 20 percent of an electrolyte system comprising at least one electrolyte selected from the group consisting of dihydroxymaleic acid, of an alkali metal salt of dihydroxymaleic acid, dihydroxytartaric acid, an alkali metal salt of tartaric acid, and mixtures thereof.
Claim 2
Dependent Claim 249 words
A pourable liquid, abrasive, stain removing composition, comprising: (A) a solid phase, comprising about 5 to about 65 percent, by weight of said composition, of a substantially water insoluble, abrasive material selected from the group consisting of calcite, dolomite, feldspar, silica flour, quartz, pumice, polishing clays and mixtures thereof, dispersed and suspended in; (b) a stabilizing aqueous liquid phase, comprising (i) about 1 to about 20 percent of a tertiary surfactant mixture, said mixture consisting essentially of: (a) about 0.25 to about 10 percent, by weight of said composition, of an alkylaryl sulphonate synthetic anionic surfactant; (b) about 0.25 to about 10 percent, by weight of said composition, of a soap wherein said soap is an alkali metal salt of a ten to twenty-two carbon fatty acid; and (c) about 0.50 to about 10 percent by weight of said composition, of a fatty acid alkanolamide, nonionic surfactant wherein the fatty acid moiety of said amide contains about 8 to about 18 carbon atoms; wherein the ratio of said soap to said synthetic anionic in said mixture is about 1:3.2 to about 1:0.8, and wherein the ratio of said synthetic anionic surfactant plus said soap to said nonionic surfactant is about 0.6:1 to about 1:0.9; and (ii) about 3 to about 20 percent of an electrolyte system comprising at least one electrolyte selected from the group consisting of dihydroxymaleic acid, of an alkali metal salt of dihydroxymaleic acid, dihydroxytartaric acid, an alkali metal salt of tartaric acid, and mixtures thereof.
Claim 3
Dependent Claim 34 words
The composition according to claim 1 wherein said solid phase further comprises a colloid forming clay wherein said clay is present in said composition in an amount up to about 5 percent by weight.
Claim 4
Dependent Claim 37 words
The composition according to claim 2 wherein, (a) said soap is a sodium salt of a blend of tallow and coconut fatty acids; (b) said abrasive is calcite; and (c) said colloid forming clay is attapulgite clay.
Claim 5
Dependent Claim 18 words
The composition according to claim 3 wherein said blend of tallow and coconut fatty acids is about 85:15.
Claim 6
Dependent Claim 108 words
A pourable liquid, abrasive, stain removing composition comprising: (A) A solid phase, comprising: (i) about 48 percent of a water insoluble calcite abrasive; and (ii) about 0.50 percentof attapulgite clay dispersed and suspended in (B) a liquid phase, comprising: (i) a tertiary soap mixture consisting essentially of: (a) about 2 percent of a sodium alkylbenzene sulphonate; (b) about 0.6 percent of a soap wherein said soap is an alkali metal salt of an 85:15 blend of tallow and coconut fatty acids; (c) about 2.4 percent of nonionic surfactant said nonionic being a blend of lauric and myristic diethanolamide; and (ii) about 5 to about 10 percent dihydroxymaleic acid.
Claim 7
Dependent Claim 108 words
A pourable liquid, abrasive, stain removing composition comprising: (A) A solid phase, comprising: (i) about 48 percent of a water insoluble calcite abrasive; and (ii) about 0.50 percentof attapulgite clay dispersed and suspended in (B) a liquid phase, comprising: (i) a tertiary soap mixture consisting essentially of: (a) about 2 percent of a sodium alkylbenzene sulphonate; (b) about 0.6 percent of a soap wherein said soap is an alkali metal salt of an 85:15 blend of tallow and coconut fatty acids; (c) about 2.4 percent of nonionic surfactant said nonionic being a blend of lauric and myristic diethanolamide; and (ii) about 5 to about 10 percent dihydroxymaleic acid.

References Cited (Backward Citations)

US3607161A Cited
US3653931A Cited
US3754941A Cited
US3966432A Cited
US4049467A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-12-11 1982-06-12 1982-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-12-11 1986-06-12 1986-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-12-11 1990-06-12 1990-12-12 $7700.00 Window Closed / Lapsed

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