US4123380A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Waste disposal
Assignee: Saab Bofors AB
•
Filing: 1977-04-04
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Granted: 1978-10-31
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Expires: 1997-04-04
Abstract
Abstract Transferring solids constituents from aqueous waste containing low and/or medium radioactive solids into solid units for long-term depositing which includes adding an organic compound which forms an azeotrope with water, distilling off the azeotrope, adding a substance which is transformable into a solid state, and distilling off the organic compound.
Inventors
- 👤 Karl T. Norell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 19:33
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/28; G21F9/30; G21F9/301; G21F9/307; G21F9/008; G21F9/04; G21F9/06; G21F9/08
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
152 words
A method of transferring the solid constituents from aqueous waste containing low and/or medium active radioactive solid constituents into solid units intended for longtime depositing wherein said solid constituents contain ion-exchange masses which comprises: (A) conveying said aqueous waste to a container provided with a stirrer; (B) adding an organic compound which forms an azeotrope with water to said aqueous waste; (C) distilling off said azeotrope and continuing the distilling until most or all of the water has been removed; (D) during the distillation returning said organic compound to said aqueous waste after the water portion of said azeotrope has been removed; (E) adding while stirring a substance which subsequently either through hardening or reaction with another substance is transformable into a solid state; (F) distilling off most or all of said organic compound; (G) pouring the waste from said container into a vessel for transformation into solid units for subsequent deposition.
Claim 2
Independent Claim
152 words
A method of transferring the solid constituents from aqueous waste containing low and/or medium active radioactive solid constituents into solid units intended for longtime depositing wherein said solid constituents contain ion-exchange masses which comprises: (A) conveying said aqueous waste to a container provided with a stirrer; (B) adding an organic compound which forms an azeotrope with water to said aqueous waste; (C) distilling off said azeotrope and continuing the distilling until most or all of the water has been removed; (D) during the distillation returning said organic compound to said aqueous waste after the water portion of said azeotrope has been removed; (E) adding while stirring a substance which subsequently either through hardening or reaction with another substance is transformable into a solid state; (F) distilling off most or all of said organic compound; (G) pouring the waste from said container into a vessel for transformation into solid units for subsequent deposition.
Claim 3
Dependent Claim
35 words
A method according to claim 1, characterized in that the organic compound consists of benzene, alkyl benzene, butyl ether, cyclohexane, diisobutylene, 2,5-dimethyl furan, ethyl butyl ether, heptane, hexyl chloride, carbon disulphide, carbon tetrachloride or tetrachloroethylene.
Claim 4
Dependent Claim
15 words
A method according to claim 2, characterized in that the organic compound consists of toluene.
Claim 5
Dependent Claim
20 words
A method according to claim 1, characterized in that the azeotropic distillation is continued until less than 0.5% water remains.
Claim 6
Dependent Claim
21 words
A method according to claim 1, characterized in that the azeotropic distillation is carried out at a temperature below 150° C.
Claim 7
Dependent Claim
23 words
A method according to claim 1, characterized in that the distillation of the organic compound continues until less than 10% organic compound remains.
Claim 8
Dependent Claim
24 words
A method according to claim 1, characterized in that the distillation of the organic compound is carried out at a temperature below 150° C.
Claim 9
Dependent Claim
16 words
A method according to claim 1, characterized in that the substance added consists of melted bituman.
Claim 10
Dependent Claim
15 words
The method of claim 1 wherein said solid constituents consist substantially entirely of ion-exchange masses.
Claim 11
Dependent Claim
24 words
The method of claim 1 which includes heating said aqueous waste in said container to partially evaporate water before said organic compound is added.
Claim 12
Dependent Claim
55 words
The method of claim 10 wherein aqueous waste is continuously conveyed to the container so that during the evaporation the volume of liquid in said container is substantially constant, and after the continuous addition of aqueous waste the evaporation continues up to approximately a 40 percent dry substance content before said organic compound is added.
Claim 13
Dependent Claim
22 words
The method of claim 1 wherein the substance added includes at least one polyol and isocyanate which react together to form polyurethane
Claim 14
Dependent Claim
34 words
The method of claim 12 wherein said polyol is added continuously at the same time said organic compound is distilled off so that a substantially constant volume of liquid is obtained in said container.
Claim 15
Dependent Claim
11 words
The method of claim 12 wherein said isocyanate is 4,4'-diphenyl-methane diisocyanate.
Claim 16
Dependent Claim
27 words
The method of claim 12 wherein a catalyst for hastening the formation of polyurethane is added at about the same time as when the isocyanate is added.
Claim 17
Dependent Claim
12 words
The method of claim 15 wherein said catalyst is dibutyl tin dilaurate.
Claim 18
Dependent Claim
32 words
The method of claim 12 wherein the polyol and waste mixture is poured from said container into said vessel intended for depositing, and wherein the isocyanate is added to said vessel thereafter.
Claim 19
Dependent Claim
49 words
A method according to claim 17, characterized in that the polyol-waste mixture and the isocyanate are mixed in the depositing vessel with the aid of a stirrer, which during the formation of polyurethane is disconnected from its driving motor and is thereafter allowed to remain in the depositing vessel.
Claim 20
Dependent Claim
37 words
The method of claim 12 wherein the polyol-waste mixture and the isocyanate are mixed in a mechanical mixing device placed in a drain pipe from said container, and is thereafter poured into said vessel intended for depositing.
Claim 21
Dependent Claim
11 words
The method of claim 1 wherein a flame retarder is added.
Claim 22
Dependent Claim
13 words
The method of claim 20 wherein said flame retarder is a phosphorous compound.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-30 | 1982-05-01 | 1982-10-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-30 | 1986-05-01 | 1986-10-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-30 | 1990-05-01 | 1990-10-31 | $7700.00 | Window Closed / Lapsed |