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US4121000A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating composition comprising a polysiloxane resin-forming precondensate, a fluorocarbon polymer, an epoxy resin, a silicone fluid, and an inorganic hardening agent

Assignee: EIDP Inc
•
Filing: 1978-01-23
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Granted: 1978-10-17
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Expires: 1998-01-23
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Abstract

Abstract A coating composition comprising (A) A BINDER CONTAINING A POLYSILOXANE RESIN-FORMING PRECONDENSATE AND AN EPOXY RESIN, (B) A DIMETHYLPOLYSILOXANE FLUID, (C) A FLUOROCARBON POLYMER, (D) AN INORGANIC HARDENING AGENT, AND (E) AN INERT LIQUID CARRIER.

Inventors

  • 👤 David K. Wald

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:25
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/70; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 228 words
A coating composition having a solids content of 25-80% by weight in an inert liquid carrier and comprised of: (a) a binder comprised of (1) 40-93%, based on the weight of the binder, of a polysiloxane resin-forming precondensate which has one or more of the units ##STR8## wherein X is a functional group which allows cross-linking at its site, and a, b, c, d and e are of a magnitude and in proportions which provide the resin with a degree of substitution, measured as the ratio of phenyl plus methyl groups to silicon atoms, of at least about 1.0, and a ratio of phenyl groups to silicon atoms of at least about 0.3, and which has a silanol content above 4%, based on the weight of the precondensate; (2) 5-50%, based on the weight of the binder, of a fluorocarbon polymer; and (3) 2-40%, based on the weight of the binder, of an epoxy resin having the formula ##STR9## wherein n is an integer from 0-42, and R is an alkylene group of 1-4 carbon atoms; (b) 0.2-10%, based on the weight of the binder, of a silicone fluid which is a dimethyl polysiloxane fluid having a viscosity of 50-5000 centistokes measured at 25° C.; (c) a finely divided inorganic hardening agent in a hardening agent-to-binder ratio of about 5/100 to 400/100; and (d) a inert liquid carrier.
Claim 2
Dependent Claim 228 words
A coating composition having a solids content of 25-80% by weight in an inert liquid carrier and comprised of: (a) a binder comprised of (1) 40-93%, based on the weight of the binder, of a polysiloxane resin-forming precondensate which has one or more of the units ##STR8## wherein X is a functional group which allows cross-linking at its site, and a, b, c, d and e are of a magnitude and in proportions which provide the resin with a degree of substitution, measured as the ratio of phenyl plus methyl groups to silicon atoms, of at least about 1.0, and a ratio of phenyl groups to silicon atoms of at least about 0.3, and which has a silanol content above 4%, based on the weight of the precondensate; (2) 5-50%, based on the weight of the binder, of a fluorocarbon polymer; and (3) 2-40%, based on the weight of the binder, of an epoxy resin having the formula ##STR9## wherein n is an integer from 0-42, and R is an alkylene group of 1-4 carbon atoms; (b) 0.2-10%, based on the weight of the binder, of a silicone fluid which is a dimethyl polysiloxane fluid having a viscosity of 50-5000 centistokes measured at 25° C.; (c) a finely divided inorganic hardening agent in a hardening agent-to-binder ratio of about 5/100 to 400/100; and (d) a inert liquid carrier.
Claim 3
Dependent Claim 39 words
The coating composition of claim 1 wherein the binder is comprised of (a) 65-85%, based on the weight of the binder, of said precondensate, (b) 10-20%, based on the weight of binder, fluorocarbon polymer; and (c) 5-15% epoxy resin.
Claim 4
Dependent Claim 32 words
The coating composition of claim 2 comprised of 1-3%, based on the weight of the binder, silicone fluid; and hardening agent is a hardening agent-to-binder ratio of about 10/100 to about 70/100.
Claim 5
Dependent Claim 35 words
The coating composition of claim 1 wherein the precondensate, when measured at 60% resin solids in xylene at 25° C., has a viscosity of 30-50 centipoises, specific gravity of 1.03-1.2, and refractive index of 1.45-1.57.
Claim 6
Dependent Claim 59 words
The coating composition of claim 4 wherein the precondensate has a silanol content above 5%, based on the weight of the resin, and a softening point of about 75°-88° C., and, when measured at 60% resin solids in xylene at 25° C., a viscosity of about 35-45 centipoises, specific gravity of about 1.05-1.12, and refractive index of about 1.50-1.53.
Claim 7
Dependent Claim 17 words
The coating composition of claim 1 wherein the fluorocarbon polymer is a copolymer of tetrafluoroethylene and hexafluoropropylene.
Claim 8
Dependent Claim 40 words
The coating composition of claim 1 wherein the epoxy resin is a liquid having a viscosity of 1.2-225 poises at 25° C., and an epoxy equivalent of 150-470; and wherein n is an integer from 0-3, and R is isopropylidene.
Claim 9
Dependent Claim 20 words
The coating composition of claim 1 wherein the silicone fluid has a viscosity at 25° C. of about 500-1500 centistokes.
Claim 10
Dependent Claim 13 words
The coating composition of claim 1 wherein the hardening agent is an alumina.
Claim 11
Dependent Claim 34 words
The coating composition of claim 1 containing pigment in a pigment-to-binder ratio of about 1/100 to about 400/100; and a wetting agent in a concentration of 0.2-10%, based on the weight of the binder.
Claim 12
Dependent Claim 203 words
The coating composition of claim 1 wherein (a) the binder is comprised of (1) 65-85%, based on the weight of the binder, of a polysiloxane resin-forming precondensate having (a) silanol content above 5%, based on the weight of the resin, (b) softening point of about 75°-85° C., and (c) when measured at 60% resin solids in xylene, viscosity of about 35-45 centipoises, specific gravity of about 1.05-1.112, and refractive index of about 1.50-1.53; (2) 10-20%, based on the weight of the binder, of fluorocarbon polymer which is a copolymer of tetrafluoroethylene and hexafluoropropylene; and (3) 5-15%, based on the weight of the binder, of liquid epoxy resin having a viscosity of 1.2-225 poise at 25° C., and an epoxy equivalent of 150-470; and wherein n is an integer from 0-3, and R is isopylidene; (b) 1-3%, based on the weight of the binder, of a silicone fluid having a viscosity of 500-1500 at 25° C.; (c) hardening agent which is alumina in a hardening agent-to-binder ratio of about 10/100 to 70/100; (d) pigment in a pigment-to-binder ratio of about 1/100 to about 400/100; (e) wetting agent in a concentration of 0.2-10%, based on the weight of the binder; and (f) inert liquid carrier.
Claim 13
Dependent Claim 16 words
A cooking vessel coated with a film produced by curing the coating composition of claim 1.

References Cited (Backward Citations)

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US3154597A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-16 1982-04-17 1982-10-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-16 1986-04-17 1986-10-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-16 1990-04-17 1990-10-17 $7700.00 Window Closed / Lapsed

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