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US4076622A Expired / Lapsed US ⏱️ 0.0 years remaining

Microbiocidal macroreticular ion exchange resins, their method of preparation and use

Assignee: Rohm and Haas Co
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Filing: 1976-06-22
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Granted: 1978-02-28
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Expires: 1996-06-22
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Abstract

Abstract This invention relates to large pore macroreticular ion exchange resins which contain chemically or physically bound microbiocides or combinations thereof. This invention also relates to methods of preparation of these microbiocidal compositions and their use in purifying aqueous solutions which are microbially contaminated.

Inventors

  • 👤 C. Richard Costin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:42
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/08; A01N25/10; C; C02; C02F; C02F1/00; C02F1/50; C02F1/505

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 50 words
A microbiocidal composition which comprises a large pore macroreticular strong base anion exchange resin containing quaternary ammonium groups, wherein the average critical dimension of the macroreticular anion exchange pore is in the range of from about 8,000 A to about 500,000 A which contains a physically bound silver chloride microbiocide.
Claim 2
Dependent Claim 50 words
A microbiocidal composition which comprises a large pore macroreticular strong base anion exchange resin containing quaternary ammonium groups, wherein the average critical dimension of the macroreticular anion exchange pore is in the range of from about 8,000 A to about 500,000 A which contains a physically bound silver chloride microbiocide.
Claim 3
Dependent Claim 21 words
A method of purifying microbially contaminated water which comprises passing said contaminated water through a microbiocidal composition according to claim 1.
Claim 4
Dependent Claim 21 words
A method according to claim 2 wherein the microbes are gram-negative and gram-positive bacteria, viruses, fungi, lichens, algae slime and molds.
Claim 5
Dependent Claim 14 words
A method according to claim 2 wherein the microbes are gram-negative and gram-positive bacteria.
Claim 6
Dependent Claim 23 words
A method of purifying microbially contaminated aqueous solutions which comprises passing said contaminated aqueous solution through a microbiocidal composition according to claim 1.
Claim 7
Dependent Claim 66 words
A process for the preparation of the microbiocidal composition according to claim 1 which comprises: a. stirring an aqueous mixture of a preconditioned large pore macroreticular anion exchange resin in the chloride anion form; b. adding a water soluble silver salt to said mixture at about room temperature and contacting for a period of about an hour; c. filtering the resin and washing it with water.
Claim 8
Dependent Claim 26 words
A process according to claim 6 which includes the additional step of drying the washed resin at temperatures from about 40° C to about 110° C.
Claim 9
Dependent Claim 32 words
A process according to claim 6 wherein the water soluble silver salt is selected from the group consisting of silver sulfate, silver nitrate, silver acetate, silver carbonate, silver oxide and silver tartarate.
Claim 10
Dependent Claim 15 words
A process according to claim 8 wherein said water soluble silver salt is silver sulfate.

References Cited (Backward Citations)

US2434190A Cited
US2396515A Cited
US2692855A Cited
US3454493A Cited
US3462363A Cited
US3817860A Cited
US3923665A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-27 1981-08-29 1982-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-27 1985-08-29 1986-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-27 1989-08-29 1990-02-28 $7700.00 Window Closed / Lapsed

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